Abstract
Nanocrystalline powders of <TEX>$MnFeP_{1-x}As_x$</TEX>(x=0.45-0.6) have been synthesized by mechanochemical reaction at room temperature using high-energy ball milling from mixtures of Mn, Fe, P, and As Powders. It has been found that a mechanically induced self-propagating reaction (MSR) occurs within 2 hours of milling and it produces very fine polycrystalline powder having a hexagonal <TEX>$Fe_2P$</TEX> structure. Further milling up to 24 hours did not change the crystalline and average particle sizes or the phase composition of the milling product. When x is 0.65, no reaction among the reactants has been observed even after 24 hours of milling. As the P content decreases in <TEX>$MnFeP_{1-x}As_x$</TEX>, the incubation time for the MSR has increased and the lattice constants in both a and c axes have changed.
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