Abstract
Abstractα,α‐Dibromotoluene 1 was found to be polymerized by the reaction with excess Mg to give poly(phenylmethylene)s 2, whose main chains were partially dehydrogenated to carbon–carbon double bonds (CC). The CCs in 2 can be brominated by treatment with Br2. The polymerization mechanism was presumed to include the formation of Grignard reagents of various species with benzylic CBr bonds and the nucleophilic attacks of the Grignard reagents to various compounds with benzylic CBr bonds. Copolymerization of 1 with dichlorodimethylsilane successfully proceeded. Mg/Cu‐mediated copolycondensation of 1 with 1,6‐dibromohexane proceeded to give polymers that have similar compositions to those of random copolymers of ethylene and styrene. © 2006Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5661–5671, 2006
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More From: Journal of Polymer Science Part A: Polymer Chemistry
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