Abstract
본 연구는 supercapacitor에 사용되는 전해액인 이온성 액체 EMI-<TEX>$BF_4$</TEX> (1-ethyl-3-methyl imidazolium tetrafluoroborate)를 제조 한 다음 산화알루미늄과 활성탄 그리고 액체/액체 연속 추출방법을 이용하여 고순도의 이온성 액체를 얻기 위한 정제방법을 연구하였다. 산화알루미늄과 활성탄을 이용한 정제는 고순도 이온성 액체를 얻기에는 부적합 하였고 액체/액체 연속 추출을 통한 정제과정에서 용매제의 변화에 따른 전기적 용량을 비교한 결과 이온성 액체 대비 증류수 비율을 높게 할수록 불순물제거율이 높으며 또한 supercapacitor의 전기적 성능이 좋게 나왔다. 그리고 추출용매는 1,2-dichloroethane을 이용할 경우 methylene chloride으로 추출할 때 보다 고순도의 이온성 액체를 얻었으며 또한 전기적 용량이 높게 나왔다. This work is on the synthesis of EMI-<TEX>$BF_4$</TEX> (1-ethyl-3-methylimidazolium tetrafluoroborate) and purification of spectroscopic grade using aluminium oxide method, activated charcoal method, and liquid/liquid fractional extraction method in order to make supercapacitor finally. But the aluminum oxide method and the activated charcoal method were not suitable for obtaining high-purity ionic liquids. The liquid/liquid fractional distillation method turned out that as the concentration of solvent (<TEX>$H_2O$</TEX>) was increased, the higher purity of EMI-<TEX>$BF_4$</TEX> was obtained and the electrical capacity of this compound was increased to higher value. When the solvent was changed to from methylene chloride to 1,2-dichloroethane, the higher purity of EMI-<TEX>$BF_4$</TEX> was obtained.
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