Abstract
In the present study particle powders of copper coated with thin films of organometallic complexes were pressed and then heat treated. The complex compounds were thermally decomposed to carbide particles of uniform dimension or to fine oxide particles; these particles were homogeneously dispersed in the alloys, thus permitting the production of the conductive materials having fairly low or negative temperature gradient of resistance to keep high conductivity at higher temperature. It may be said that this type of new conductive materials overthrows the Matthissen's rule. Thus deviation from the Matthissen's rule is particularly re-markable in the samples added with Ni(AA)2, Ti(AA)3, 1Mn4Ni(AA)2 and SmCo5(AA)2. This deviation may be attributed to s-d interaction of the dispersed amorphous transition metal compounds and matrix copper atoms.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Japan Society of Powder and Powder Metallurgy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.