Abstract
The dechlorination reaction of an aqueous solution of trichloroethylene (TCE) with α-Fe·Fe3O4 composite particles which included 500-4500 ppm sulfur was carried out using shaking and stationary methods. As a result, the following reaction mechanism was obtained. cis-1,2-dichloroethylene (DCE) was produced as the intermediate product at the first step of the dechlorination of TCE, and cis-1,2-DCE was converted into four types of sulfonated hydrocarbon through the reaction. Such a substitution of Cl in cis-1,2-DCE to S proceeded catalytically at the surface of magnetite including in composite particles and S atoms only acted as the promoter of dechlorination without the formation of hydrogen sulfide. These sulfonated hydrocarbons converted to seven types of hydrocarbon as the main products by the successive reactions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
