Abstract

Electrodes modified using aggregated cobalt-porphyrin/polymer ligand systems were prepared and electrocatalytic activity for oxygen (0) reduction was investigated physicochemically. The maximum value of water yield due to 0 four-electron reduction was 56%. The apparent number of electrons involved in 0 reduction was 2.7 to 3.1. Two reactions due to 0 two- and four-electron reduction occurred on modified electrodes. Modification (adsorption) stability of the electrocatalyst system was over a few hours under hydrodynamic conditions,

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