Abstract

이 논문에서는 미세한 통로를 흐르는 고분자 블렌드의 유변학적 특성에 관하여 연구하였다. 우선 두께가 각각 0.1, 0.2 0.5 mm 인 세 종류의 슬릿 다이를 제작하였고 특수 제작한 피스톤을 부착한 모세관 점도계로 고분자 블렌드의 점도 거동을 관찰하였다. 관찰 결과 상구조가 해도 구조를 가지는 경우 고분자 블렌드의 점도는 다이의 크기에 의존하지 않음을 알 수 있었다. 그러나 상구조가 co-continuous 구조를 가지는 경우에는 점도가 다이의 크기에 의존함을 관찰하였는데, 몇몇 부가 실험 결과 이는 각 상 간의 미끄러짐이 원인임을 알 수 있었다. In this paper, rheological property of polymer blends in a confined geometry was investigated. The shear viscosity was measured in a capillary rheometer incorporated with a specially designed piston and three slit dies having 0.1, 0.2 and 0.5 mm in thickness. It was observed that the viscosity of polymer blends does not depend on the die size when the phase of polymer blends is a sea-island structure. However, when the phase of polymer blends is a co-continuous structure, the viscosity of the blends was dependent on the die size. By additional investigations, this result is attributed to the slip phenomenon between polymer phases in the blends.

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