리튬용액 침투방법에 의한 Li2TiO3페블 제조

Abstract

To fabricate spherical lithium titanate (Li₂TiO₃) pebbles which are used for a breeder material in fusion reactor, titanium oxide (TiO₂) granules were used as a starting material. The granules were pre-sintered, and then aqueous lithium nitrate solution infiltrated into the granules at vacuum condition. The granules were crystallized to Li₂TiO₃ after sintering under the control of process parameters. In this study, the concentration of lithium in the solution, as well as the number of penetration times and sintering temperature affected the final crystallite phase and the microstructure of the pebbles. In particular, the sphericity and size of the pebbles were effectively controlled by a technical rolling process. The useful spherical Li₂TiO₃ pebbles which have 10 ~ 20% porosity and 60 ~ 120 N compressive strength were obtained through the sintering at 1000 ~ 1100℃ in the multi-times infiltration process with 50 wt% solution. The physical properties of pebbles such as density, porosity and strength, can be controlled by a selection of TiO₂ powders and control of processing parameters. It can be thought that the lithium penetration method is a useful method for the fabrication of mass product of spherical Li₂TiO₃ pebbles.