Abstract

The article uses the thermodynamic method to study the effect of temperature on the Gibbs free energy, the determination of its coefficient and the dependence of the melting temperature of phases on pressure. Nerns's thermal theorem was revised by the method of quantum statistics, and it was discussed in detail and proved that isothermal processes occur without a change in entropy as the temperature approaches T→0, and that changes in free energy (∆G), enthalpy (∆H) are characterized by a tangent parallel to abscissa axis.

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