Abstract
Измерением ЭДС концентрационных цепей с твердым электролитом Cu4RbCl3I2 в интервале температур 300÷380 К изучена система Cu8GeS6-Ag8GeS6. Показано образование широких областей твердых растворов на основе исходных соединений. Из данных измерений ЭДС вычислены парциальные молярные функции меди в сплавах.
Highlights
Abstract.The system Cu GeS - Ag GeS was studied by electromotive force measurements of the concentration chains w(–it)hCinu3(0s0o÷l.3) 8| 0CuɄ4RtebmCpl3eIr2a(tsuorle.)in| t(eCrvuainl
(1) superionic conductor Cu4RbCl3I2 was used as the electrolyte
The metallic copper was used as a left electrodeand equilibrium alloys of the studied system were served as right electrodes
Summary
Ƚ. Ⱦɠɚɜɢɞɚ 113, AZ 1143 Ȼɚɤɭ, Ⱥɡɟɪɛɚɣɞɠɚɧ e-mail: babanlymb@gmail.com ɉɨɫɬɭɩɢɥɚ ɜ ɪɟɞɚɤɰɢɸ 23.01.2017 ɝ. ꞫȺɲɢɧɢɧɧɪɬɨɨɟɤɬɪɢɚɜɯɰɚɢɨɥɹɛɟɥ.ɬɚɂɟɫɦɡɬɦɩɟɟɣɟɪɪɬɚɟɜɬɧɟɭɢɪɪɟɞɦ3ɵ0ɯɗ0Ⱦɪ÷ɚ3ɋɫ8ɬɤ0ɜɨɨKɧɪɰɢɨɟɜɡɧɭɧɬɱɪɚɟɚɧɨɰɚɫɢɧɫɨɨɢɧɜɫɧɟɬɵɟɢɦɯɫɚɯɰɨCɟɞɩuɧɟ8ɵGɣɯeɫSɫɬɨ6ɜ–ɟɟAɞɪɢgɞɧ8ɵGɟɦɧeɢSɷɣ6ɥ..ɟɉɂɤɨɬɡɪɤɞɚɨɚɡɥɧɚɢɧɧɬɨɵɨɦɯɨɛɢCɪɡuɚɦ4ɡRɟɨɪɜbɟɚCɧɧlɢɢ3Iɣɟ2 ɗȾɋ ɜɵɱɢɫɥɟɧɵ ɩɚɪɰɢɚɥɶɧɵɟ ɦɨɥɹɪɧɵɟ ɮɭɧɤɰɢɢ ɦɟɞɢɜ ɫɩɥɚɜɚɯ. Ɋɩɥɚɜɥɟɧɢɟɦ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɫɨɟɞɢɧɟɧɢɣ ɜ ɪɚɡɥɢɱɧɵɯ ɫɨɨɬɧɨɲɟɧɢɹɯ ɜ ɜɚɤɭɭɦɢɪɨɜɚɧɧɵɯ ɤɜɚɪɰɟɜɵɯ ɚɦɩɭɥɚɯ ɝɨɬɨɜɢɥɢ ɫɩɥɚɜɵ ɫɢɫɬɟɦɵ Ⱦɥɹ ɩɪɨɜɟɞɟɧɢɹ ɢɡɦɟɪɟɧɢɣ ɗȾɋ ɛɵɥɢ ɫɨɫɬɚɜɥɟɧɵ ɤɨɧɰɟɧɬɪɚɰɢɨɧɧɵɟ ɰɟɩɢ ɬɢɩɚ: (–) Cu (ɬɜ.) | Cu4RbCl3I2 (ɬɜ.) | (Cu ɜ ɫɩɥɚɜɟ) (ɬɜ.) (+), (1) Ɇɟɬɨɞɢɤɢ ɫɨɫɬɚɜɥɟɧɢɹ ɷɥɟɤɬɪɨɯɢɦɢɱɟɫɤɢɯ ɰɟɩɟɣ ɢ ɢɡɦɟɪɟɧɢɣ ɗȾɋ ɩɨɞɪɨɛɧɨ ɨɩɢɫɚɧɵ ɜ [12].
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