Анализ причин образования дефектов заготовок из стали 12x18h10t и разработка рекомендаций по их устранению

Abstract

Introdution. Austenitic steel (e.g., AISI 304, AISI 321, AISI 316, AISI 403, 12-Cr18-Ni10-Ti, etc.) is widespread, which is caused by high corrosion resistance and the corresponding possibility of use in aggressive media. The following most common types of 12-Cr18-Ni10-Ti steel defects can be distinguished: integranular corrosion, martensitic orientation of the α-phase and ferrite δ-phase. The purpose of work: to analyze the defects formation reasons of the 12-Cr18-Ni10-Ti steel grade billets and to develop recommendations for their elimination. The methods of investigation. Tests of 12-Cr18-Ni10-Ti steel samples for resistance to integranular corrosion, metallographic analysis of defects were carried out in this work. Hardness measurements were carried out for various degrees of billets reduction. Thermodynamic calculations of phase equilibrium in multicomponent steel for different temperatures were performed by the Thermo-Calc software. Results and Discussion. It is determined that in order to prevent integranular corrosion, it is necessary to reduce the nitrogen and carbon content in steel at the stage of ladle refining to 0.05%, and also to ensure the concentration of titanium in steel is not less than the permissible value — 0.3%. These measures contribute to the reduction of Cr23C6 chromium carbides responsible for integranular corrosion. It is necessary to reduce the degree of compression of the billets to a level of no more than 50% to prevent the appearance of a ferromagnetic martensitic α-phase, since the formation of this defect is associated with a high degree of compression during drawing. The high-temperature phase of δ-ferrite exists in the metal structure in a wide temperature range. Reducing this range to 100 degrees or less by optimizing the composition of the carbon and chromium alloy in accordance with GOST 5632-2014 leads to a significant reduction of the amount of ferrite. However, it is not possible to completely eliminate it from the structure of steel. For all cases, it is necessary to assign austenization of billets in the temperature range of 1,050…1,100 °C.