Abstract

Cd or Zn doped CuInSe2 and undoped CuGaSe2 crystals have been grown using synthesis solute diffusion method with controlling the growth rate. The CuGaSe2 crystals having a single phase were obtained under the same growth condition as CuInSe2 for the first time. The Cd or Zn doped CuInSe2 crystals have p-type conduction, in contrast to that of doping Cd or Zn using Brigeman method (n-type conduction).

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