Abstract
The article presents the results of a kinetic study of the synthesis of a new fullerene derivative containing a diterpene fragment, obtained using the HPLC method and subsequent mathematical modeling. The kinetic and activation parameters of fullerene cyclopropanation by the Bingel method were determined, and the reaction mechanism was proposed. Optimal synthesis conditions were found: it is preferable to use a small excess of a chlorine-containing cyclopropanation agent and carry outthe reaction at room temperature.
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