Исследование свойств водонабухающей резины, содержащей камеди и экстэлинт

Abstract

It is known that the main role in water-swellable sealing elements belongs to rubber, the properties of which depend on the nature of the rubbers and functional ingredients used. Water-swellable sealing elements are mainly made from rubbers based on acrylate, chloroprene and nitrile butadiene rubbers using various hydrophilic additives: starch derivatives, cellulose, polyvinyl alcohol and various oligomeric resins. However, after sufficiently long contact with water, some additives are washed out and the sealing properties of the sealing elements are lost. Among the promising insoluble and limited water-swellable additives, sodium polyacrylate should be distinguished. Using it as part of rubbers together with soluble water-swellable additives will allow preserving the sealing properties of the sealing elements by filling it with the pores formed when washing water-soluble swellable additives from rubbers. In this regard, in this work, the effect of guar and xanthan gums together with extelint fiber on the properties of water-swelling rubber based on a combination of nitrile butadiene BNKS-18AMN, chloroprene neoprene W, acrylate nipole AR22 and butadiene SKD caoutchoucs with sulfuric vulcanizing system, was studied. The rubber mixture was prepared by mixing rubbers with ingredients on laboratory rolls LB 320 160/160. The rheological characteristics of the rubber composition were studied on an MDR 3000 Basic rheometer at 150 °C. Standard samples of the rubber mixture were vulcanized at a temperature of 150 ° C for 30 minutes in a curing press type P-V-100-3RT-2-PCD. The main properties of the vulcanizates were determined according to the standards applicable in the rubber industry. It is shown that the introduction of gums with extelite into the rubber mixture leads to a change in its rheological parameters. Vulcanizates that contain gums are characterized by lower values of conditional tensile strength and rebound elasticity, but larger elongation at break and degree of swelling in distilled and formation water compared to the vulcanizate of the base rubber mixture.