Abstract

The results of a thermodynamic study of a group of inorganic compounds of the general formula Ln2M2O7, where M = Sn, Ti, are presented. Single-phase samples were obtained by reverse precipitation followed by high-temperature synthesis. Crystallographic parameters were calculated and their dependence on the radius of the element is shown. The temperature dependences of the heat capacity are experimentally studied in a wide temperature range. The thermodynamic properties of samarium compounds with a pyrochlore-type structure are compared.

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