게 껍질을 이용한 수중의 복합 중금속 제거에 관한 연구

Abstract

In order to examine the inhibition effect of other heavy metal ions on the removal of heavy metal ions by crab shell in aqueous solution, 10 heavy metal ions <TEX>$(Cr^{3+},\;Cd^{2+},\;Ni^{2+},\;Zn^{2+},\;Hg^{2+},\;Cu^{2+},\;Mn^{2+],\;Fe^{2+},\;Fe^{3+},\;Pb^{2+})$</TEX> were used as single heavy metal ions and mixed heavy metal ions, respectively. In single heavy metal ions, <TEX>$Pb^{2+},\;Cr^{3+},\;Cu^{2+}$</TEX> were well removed by crab shell, however, <TEX>$Cd^{2+},\;Ni^{2+},\;Zn^{2+},\;Mn^{2+}$</TEX> were not. The heavy metal removal increased as the increase of covalent index (Xm<TEX>$^2$</TEX>r), and the relationship classified heavy metal ions as 2 heavy metal groups <TEX>$(Fe^{3+},\;Fe^{2+},\;Cu^{2+},\; Cr^{3+},\;Mn^{2+},\;Ni^{2+},\;Zn^{2+}\;group\;and\;Pb^{2+},\;Hg^{2+},\;Cd^{2+}\;group)$</TEX>. In mixed heavy metal ions, the removals of <TEX>$Fe^{2+},\;Fe^{3+},\;Pb^{2+},\;Cu^{2+}$</TEX> as 0.49 m㏖/g, regardless of the existence of other heavy metal ions, were similar to the result of single heavy metal ions experiment. The removals of <TEX>$Mn^{2+},\;Cd^{2+},\;Ni^{2+}$</TEX> decreased as the existence of other heavy metal ions, however, the removal of <TEX>$Zn^{2+},\;Cr^{3+},\;Hg^{2+}$</TEX> increased.