Abstract

본 논문에서는 이소 옥탄을 연료로 사용하는 층류 확산 화염에서 불완전 연소의 결과로 발생하는 그을음 입자의 성장 및 산화과정을 조사하였다. 또한, 철 연료첨가제의 그을음 발생 억제 효과를 평가하였다. 광 계측 기술을 이용하여 화염 안 그을음 입자의 탄성 산란 광을 화염의 높이에 따라 계측하고, 미광 보정 과정을 통하여 그을음 입자의 미분 산란 계수를 구하였다. 이 미분 산란 계수를 비교하여, 화염에서 그을음 입자의 성장 및 산화과정을 조사하였는데, 산화과정을 통하여 화염 내의 그을음 양이 감소하는 것을 관찰하였다. 철 연료 첨가제를 첨가한 화염에 대해서 동일한 연구 방법으로 구한 미분 산란 계수가 연료 첨가제가 첨가되지 않은 화염보다 더 작은 값을 보였다. 또한, 화염의 높이에 따라 반경방향으로 투과율을 측정하였는데, 연료 첨가제를 첨가한 연료의 화염은 투과율이 산화영역에서 약 5% 증가하는 것을 관찰하였고, 이는 미분 산란 계수와 동일한 경향을 보였다. 이것은 연료첨가제의 성분이 촉매 역할을 하여 그을음이 산화를 촉진해 화염 안의 그을음 양이 감소한 것으로 사료된다. This paper presents an experimental analysis of the growth and oxidation processes of soot particles generated in an isooctane diffusive laminar flame due to incomplete combustion. The effects of iron-based diagnostics were employed to measure the elastic scattering light from soot particles in a flame at different flame heights, and the differential scattering coefficients were calculated through a calibration process. The growth and oxidation of soot particles in flame was investigated by comparing differential scattering coefficients, and the soot volume fraction was seen to decrease in the soot oxidation process. In the same manner, the differential scattering coefficients were calculated for iron-based fuel-additive seeded flame, and these coefficients were revealed to be smaller than those obtained in the fuel-additive unseeded flame. In addition, transmission through the radial direction of the flame was measured, and transmission in the soot oxidation regime was approximately 5% higher for the seeded flame. The propensity of the data coincided well with the differential scattering coefficients, and it can be concluded that the iron component of the fuel additive plays a crucial role as a catalyst, which eventually enhanced soot particle oxidation.

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