Abstract
The Debye-Waller factors determined by diffraction and XAFS experiments provide important information about the thermal vibration and disordered structure. The statistical distribution of Ag in α-AgI and supersonic conduction mechanism have been discussed based on the effective one-particle potential, probability density function and effective pair potential. The disordered nature of α-AgI is due to the thermal motion and the probability of finding mobile Ag ions at saddle point is a few percent in α-AgI.
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