Abstract
Конформационные переходы поли (С) и поли(сІС): исследование методом протонной буферной емкости
Highlights
These dependencies are expanded into basic functions corresponding to ionized groups of equal pK
It is found that the buffer capacity curve of poly(C) has four peaks: two narrow and two wide ones
The first narrow peak reflects the process of cooperative formation of double helices, which is induced by the protonation of the N3 atom of the nucleotide bases partly exposed in the solution
Summary
On the basis of the literature data the j>H-dependencies of proton buffer capacity of poly(C) (at 0,1 M Na ) and poly(dC) These dependencies are expanded into basic functions corresponding to ionized groups of equal pK.
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