Abstract
Within the framework of the quantum-mechanical theory of elementary acts of non-adiabatic electrochemical reactions and using the model of isotropic spherically symmetric band, the calculation of the discharge current of ions at the “solid–electrolyte” interface has been carried out. It is shown that our results generalize the analogical formulae, which are available in the literature. The average densities of states in the valence band and in the conduction band of the solid electrode under the heterogeneous charge transfer are found.
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