Abstract

Experimental evidence for the possibility of controllably transforming the habit of copper microcrystals formed by electrodeposition has been presented. Selective evolution of microcrystal facets with a specific crystallographic orientation has been performed by a premeditated change in the chemical composition of a standard sulfuric electrolyte. The experiments have demonstrated elastic energy relaxation channel associated with disclination type defect in pentagonal small particles specifically an open sector instead of a twin boundary.

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