Решение обратной задачи для сложного вибронного аналога резонанса Ферми на основе плоских вращений Якоби

Abstract

Based on algebraic methods, we have found an accurate solution for the inverse task for the vibronic analogue of the complex Fermi resonance, i.e. the determination from the spectral data (energies Ek and transition intensities Ik of the observed conglomerate of lines, k = 1, 2, ..., n; n > 2) energies of the «dark» states Am and the matrix elements of their coupling Bm with the «bright» state. The algorithm consists of two stages. At the first stage, the Jacobi plane rotations are used to construct an orthogonal similarity transformation matrix X, for which the elements of the first row obey the requirement (X1k)^2 = Ik, which corresponds to that fact that there is only one non-perturbed «bright» state. At the second stage, the quantities Am and Bm are obtained after solving the eigenvalue problem for block of «dark» states of the matrix Xdiag({Ek})X-1.