Abstract
First described the noble metal (platinum group elements (PGE) and Au) geochemical specialization of magmatic rocks of Bashkirian meganticlinorium and the adjacent part of the East European Platform (EEP). Identity graphs of normalized PGE and Au contents in igneous rocks of the western slope of the Southern Urals and east EEP indicates the proximity of their formation and common mechanisms of formation of noble metal geochemical specialization during the formation of these bodies. It was found that the specific precious metal geochemical specialization (“rhodium anomaly”) magmatic complexes Bashkirian meganticlinorium and east EEP, due to the content of precious metals in sulphide minerals (pentlandite) has a “primary” nature. Variations contents Pt, Pd and Au, which are characteristic for different varieties of common species within the region, are the result of their redistribution during the formation of magmatic bodies and/or transformation by secondary processes. It is shown that the noble metal geochemical specialization of clastic rocks of Bashkirian meganticlinorium tectonic zones (presence of increased amounts of platinum and most importantly - “rhodium anomaly”) formed under the influence of magmatism with further redistribution and concentration of precious metals as a result of a later time metamorphism and local metasomatism.
Highlights
Впервые охарактеризована благороднометалльная (элементы платиновой группы (ЭПГ) и Au) геохимическая специализация магматических пород Башкирского мегантиклинория и прилегающей части Восточно-Европейской платформы (ВЕП)
Identity graphs of normalized PGE and Au contents in igneous rocks of the western slope of the Southern Urals and east European Platform (EEP) indicates the proximity of their formation and common mechanisms of formation of noble metal geochemical specialization during the formation of these bodies
It was found that the specific precious metal geochemical specialization (“rhodium anomaly”) magmatic complexes Bashkirian meganticlinorium and east EEP, due to the content of precious metals in sulphide minerals has a “primary” nature
Summary
Определения платиноидов (Pt, Pd, Rh, Ru, Ir) и Au были выполнены нанотехнологическим способом определения содержания редких и рассеянных химических элементов в горных породах (ВСЕГЕИ). Методика определения заключается в том, что химическому анализу подвергают коллоидносолевой раствор, приготовленный из пробы исследуемых объектов горных пород и деионизированной воды, взятых в соотношении 1:10. Методом масс-спектрометрии с индуктивно-связанной плазмой (ICP MS) в коллоидно-солевом растворе, содержащем частицы фракции исследуемой пробы с размерами 1–1000 нм, определяется наличие и количественное содержание редких и рассеянных элементов. Мкг/л: 0.01 (Au), 0.02 (Pt), 0.03 (Pd), 0.005 (Ag), 0.005 (Rh), 0.02 (Ru), 0.006 (Ir) [Олейникова и др., RU 2370764]. Содержания благородных (Pt, Pd, Rh, Ru, Ir и Au) элементов определялись на массспектрометрической системе высокого разрешения HR ICP-MS ELEMENT2 (ThermoFinnigan) для мультиэлементного анализа геологического материала
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