РЕШЕНИЕ ЗАДАЧИ В РАБОЧЕЙ ЗОНЕ. ЧИСЛЕННЫЙ РАСЧЕТ МОДЕЛИ НИЖНЕКАМСКОГО РЕАКТОРА ДЛЯ ПОЛУЧЕНИЯ СТИРОЛА (ЧАСТЬ 3)

Abstract

Heterogeneous catalytic processes conducted in axial or radial type reactors with a still catalytic layer are some of the most important elements of the chemical technology. The attention of scientists and manufacturers to the investigation and application of these contact units deals with the following advantages: a highly developed surface of a phase separation, a possibility to provide a high flow velocity and hence to decrease sizes and a material consumption, a construction simplicity and a reliability of an exploit. Improving an operation of contact units may be achieved by refining present technologies, catalysts, disperse system structures and by creating new ones. Nevertheless, in some cases large scale hydrodynamic heterogeneities in a working zone of the unit cancel out efforts to increase an efficiency of chemical, heat/mass transfer and other processes. The exploration of reasons of the hydrodynamic heterogeneities formation requires an investigation of liquid and gas motion physics features in granular layers. A practice of a chemical reactors exploitation reveals that technical and economical indicators of an industrial process are as a rule lower than the calculated ones, derived on a stage of the process design. Now it can be considered proven that one of the reasons affecting the reactor output is the heterogeneity of a reagents flow in a granular catalyst layer. The article deals with a mathematical modeling of an incompressible liquid flow in flat and radial contact units with the still granular layer and a creation of numerical realization methods for the model We propose a cycle of articles dealt with a model of a real reactor that consists of three parts: a distributing manifold, a collecting manifold and a working zone, where the still layer of a granular catalyst is loaded. An input and an output are made with a Z-shaped scheme. We consider processes and their equations in each reactor zone in detail.