Organochlorine Pesticide Residues Research Articles

Ecological risk assessment of organochlorine pesticide residues in sediment samples from Lake Tana and Hayqe in Northwest Ethiopia

In most developing countries, including Ethiopia, the excessive use of toxic and persistent pesticides for agricultural and malaria control purposes poses a significant challenge. This study focuses on evaluating the concentration and ecological risks associated with organochlorine pesticides (OCPs) in the sediments of Lake Tana and Hayqe. Employing a laboratory-based cross-sectional approach, the residues of OCPs in sediment samples were extracted using the Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method, followed by dispersive solid phase extraction cleanup (d-SPE) techniques and analyzed for 18 OCPs by gas chromatography coupled to tandem mass spectrometry (GC-MS). The risk Quotient (RQ) method was adopted for ecological risk assessments by using fish, daphnia, and algae as indicators. The concentration of OCPs ranged from 10.11 to 125.65 μg/kg and 10.96–45.17 μg/kg in Lake Tana and Hayqe, respectively. There was a statistically significant difference in the mean concentration of OCPs across the sampling sites in Lake Tana. Deltamethrin and lindane exhibit comparatively lower concentrations among the OCPs, whereas endrin, DDT, and their metabolites were the predominant pesticides in the study area, exceeding WHO and USEPA residue limits, except for endosulfan. Risk Quotient values ranged from 0.006 to 865.4 in Lake Tana and 0.005 to 729.9 in Lake Hayqe, indicating potential low to high ecological risks for aquatic organisms. High ecological risks are particularly evident in fish, daphnia, and algae species exposed to α and β-Endosulfan, DDT, and their metabolites, while specifically in daphnia, endrin poses high ecological risks. The ANOVA test revealed there were statistically significant differences (p-value <0.05) among sampling sites in Lake Tana and the mean values between Lake Tana and Lake Hayqe, underscoring the importance of addressing pesticide-related ecological concerns in the region.

Post-synthetic modification of covalent organic framework for efficient adsorption of organochlorine pesticides from cattle's milk

Analysis of organochlorine pesticides (OCPs) residues in milk faces a significant challenge. Herein, a sea urchin structured covalent organic framework bearing boric acid groups named COF-B(OH)2 was synthesized and applied as a coating material for solid-phase microextraction (SPME) of the OCPs in cattle’s milk. Its performance was superior to that of three commonly used commercial SPME fibers, which could be due to the coexistence of hydrogen bonding, halogen bonding, π-stacking and electrostatic interactions. Besides, the fiber coating displayed good stability and reusability. After optimization, a COF-B(OH)2 based SPME coupled with gas chromatography-electron capture detection was established for the sensitive detection of the OCPs from milk samples. The limits of detection (S/N = 3) were between 0.04 and 1.0 μg kg−1. Satisfactory accuracy was achieved with the method recoveries in the range of 87.5 % to 112.5 %. These results manifest the feasibility of the COF-B(OH)2 coated fiber for the enrichment of the trace OCPs from milk samples.

Health Risk Assessment of Organochlorine Pesticide Residues in Selected Herbal Medicines Sold in Lagos State, Nigeria

The use of herbal medicines has a very long history for therapeutic purposes. However, cases of toxicological effects have been reported. The present study aims to assess the safety level of herbal medicines by monitoring the organochlorine pesticide (OCP) residues content. This study assessed the presence of seventeen organochlorine pesticide residues in twenty-seven (27) herbal medicine samples (14 liquid and 13 solid) collected from seven Local Government Area of Lagos state, Nigeria. The residues were analyzed using Gas Chromatography-Mass Spectrometry (GC-MS) with solid phase extraction. Results showed the presence of banned OCP residues in all the selected samples at concentrations greater than the Maximum Residue limit, MRL. The Estimated Daily Intake, EDI measures the level of exposure to the pesticide residues for all the samples were found to be lower than the Acceptable Daily Intake, ADI. Health Risk Index (HRI) of all the selected samples was generally lesser than one (1) which indicates that long term exposure may not be of immediate concern to the consumers. The solid herbal medicines were found to have higher mean concentration, EDI and HRI when compared to the liquid herbal samples, suggesting that processing and preparation techniques for solid herbal medicines should be improved. The presence of the banned OCP residues in herbal medicine is, however, of public health interest and should be regularly monitored.

Seasonal Dynamics and Ecological Risks of Organochlorine Pesticides in Kafrelsheikh-Egypt: Implications for Aquatic Ecosystems and Public Health

Kafrelsheikh, situated in the middle of the Nile Delta, significantly contributes to Egypt's aquaculture and agriculture sectors. However, the local use of organochlorine pesticides (OCPs) in agriculture is often a source of OCP residues in associated drainage waters, which may threaten aquatic ecosystems. These pesticides persist in local water bodies, jeopardizing aquatic ecosystems and potentially impacting human health. This comprehensive study assessed the seasonal variations of 17 OCPs in both water sources and Nile tilapia across eight fish farming locations in Kafrelsheikh. Using gas chromatography coupled with mass spectrometry (GC-MS), we detected OCP concentrations in water that varied seasonally: winter recorded the highest levels at 22.5 ng/mL. In comparison, summer showed the lowest levels at 6.2 ng/mL. Despite water samples occasionally showing risk quotients (RQs) greater than 1, indicating a potential threat to aquatic life, the OCP levels in Nile tilapia were sufficiently low, with target hazard quotients (THQ) below 1, suggesting no significant risk to human consumers. The research highlights a pressing need for regular environmental monitoring and stricter regulatory control over pesticide use to protect aquatic life and ensure the safety of aquaculture products. These findings provide a critical basis for policy-making, aimed at balancing agricultural productivity with environmental sustainability in regions heavily dependent on both.

Vortex-assisted dispersive micro-solid-phase extraction using silica-supported Fe2O3-modified khat (Catha edulis) biochar nanocomposite followed by GC-MS for the determination of organochlorine pesticides in juice samples

In this paper, dispersive micro-solid phase extraction technique was developed for the purpose of extracting and preconcentrating organochlorine pesticide residues in juice samples before their separation and quantitative analysis by gas chromatography-mass spectrometry. A sorbent composed of a silica-supported Fe2O3-modified khat leftover biochar nanocomposite (SiO2-Fe2O3-KLBNC) was implemented in the process. To improve the dispersion of the sorbent in the solution, vortex mixer was employed. Experimental parameters influencing the performance of the method were optimized, and the optimal conditions were established. With these conditions, linear dynamic ranges ranged from 0.003 to 100.0 ng/mL were achieved, with a correlation coefficient (r2) ≥ 0.9981. The limits of detection and quantification, determined by signal-to-noise ratios of 3 and 10, respectively, were found to be in the ranges of 0.001–0.006 ng/mL and 0.003–0.020 ng/mL. Intra- and inter-day precision, values ranging from 0.3–4.8% and 1.7–5.2% were obtained, respectively. The matrix-matched extraction recoveries demonstrated favorable outcomes, falling within the range of 83.4–108.3%. The utilization of khat leftover as an adsorbent in contemporary sample preparation methodologies offers a cost-effective alternative to the currently available, yet expensive, adsorbents. This renders it economically viable, particularly in resource-constrained regions, and is anticipated to witness widespread adoption in the coming future.

Occurrence and seasonal variation of organochlorine pesticides in selected vegetable farmlands in Lagos State, Nigeria

Pest infestation in crop production have increased farmers' interest in pesticides use with short and long term consequences. This study investigated the occurrence and seasonal variations of organochlorine pesticide residues in vegetable farms in selected areas of Lagos State. Non carcinogenic and carcinogenic risk assessment was also evaluated. Soil samples were collected during the wet and dry seasons at soil depth of 0-30 cm. Gas chromatography coupled with an Agilent mass spectrometer was used to analyse organochlorine residues (alpha-lindane,lindane, delta.-lindane, aldrin, heptachlor epoxide, alpha.-endosulfan, p,p'-dichlorodiphenyldichloroethylene (p,p'-DDE), endrin, endosulfan, m,p'-dichlorodiphenyldichloroethane (m,p'-DDD), endosulfan sulfate, o,p'-dichlorodiphenyltrichloroethane (o,p'-DDT) and endrin ketone) in soil. Heptachlor epoxide showed maximum concentration of 43.03 mg/kg in Station 19 in Western zone during the dry season while m,p'-DDD and endosulfan had minimum value of 0.004 mg/kg in Station 2 and Station 5 respectively during the wet season in the Far eastern zone. The concentrations of organochlorine residues were intermediate in the Eastern zone in both seasons. There was significant (p &lt; 0.05) increase in dry season concentrations when compared to wet season. The risk assessment indicated Hazard Quotient (HQ) &gt; 1 for non-cancer risk and cancer risk &gt; 10-6. Thus a need for stringent monitoring programs for pesticides.

Correction: Development of temperature-assisted solidification of floating organic droplet-based dispersive liquid–liquid microextraction performed during centrifugation for extraction of organochlorine pesticide residues in cocoa powder prior to GC-ECD

Correction: Development of temperature-assisted solidification of floating organic droplet-based dispersive liquid–liquid microextraction performed during centrifugation for extraction of organochlorine pesticide residues in cocoa powder prior to GC-ECD

Organochlorine, organophosphorus, and carbamate pesticide residues in an Ethiopian Rift Valley Lake Hawassa: occurrences and possible ecological risks.

Currently, pesticide production and use are on the rise globally. This trend is certain to continue in the coming decades with residues posing risks to the environment and human health even at low levels. Although various aspects of pesticides and their possible implications have widely been studied, such studies have mostly been carried out in developed countries leaving the rest of the world with little scientific information. We present here the results of a study on the occurrences, concentrations, and ecological risks of 30 pesticide residues (PRs) in water and sediment samples from a tropical freshwater Lake Hawassa in the Ethiopian Rift Valley. A total of 54 composite samples of water and sediment were collected from three sampling sites on three occasions. The samples were prepared by quick, easy, cheap, effective, rugged, and safe (QuEChERS) technique, and analyzed using GC-MS at Bless Agri Food Laboratory Service located in Addis Ababa, Ethiopia. The study applied the risk quotient (RQ) method to scrutinize the risks posed to aquatic biota by the detected PRs. The results showed occurrences of 18 and 20 PRs in the water and sediment samples, respectively. The majority, 78 and 75% of the detected PRs in water and sediment samples, respectively represent the organochlorine chemical class. Concentrations of heptachlor epoxide were significantly (p ≤ 0.001) higher than those of the remaining pesticides in both matrices. Of the pesticides detected, 77% were present in water and 83% in sediment samples and pose a serious risk (RQ ≥ 1) to the Lake Hawassa biota. This calls for further research to investigate the risks to human health posed by the PRs. The findings of this study can contribute to the development of global protocols, as they support the concerns raised about the ecological and public health impacts of PRs on a global level.

Diffusion of organochlorine (OCPs) and cypermethrin pesticides from rohu (Labeo rohita) internal organs to edible tissues during ice storage: a threat to human health.

The migration of organochlorine pesticides (OCPs) and cypermethrin residues from internal organs to edible tissues of ice-held Labeo rohita (rohu) was investigated in this study. The liver (246µg/kg) had the highest level of ∑OCP residues, followed by the gills (226µg/kg), intestine (167µg/kg), and muscle tissue (54µg/kg). The predominant OCPs in the liver and gut were endosulfan (53-66µg/kg), endrin (45-53µg/kg), and dichloro-diphenyl-trichloroethane (DDT; 26-35µg/kg). The ∑OCP residues in muscle increased to 152µg/kg when the entire rohu was stored in ice, but they decreased to 129µg/kg in gill tissues. On days 5 and 9, the total OCPs in the liver increased to 317µg/kg and 933µg/kg, respectively. Beyond day 5 of storage, total internal organ disintegration had led to an abnormal increase in OCP residues of liver-like mass. Despite a threefold increase in overall OCP residues by day 9, accumulation of benzene hexachloride (BHC) and heptachlor was sixfold, endrin and DDT were fourfold, aldrin was threefold, and endosulfan and cypermethrin were both twofold. Endosulfan, DDT, endrin, and heptachlor were similarly lost in the gills at a rate of 40%, while aldrin and BHC were also lost at 60 and 30%, respectively. The accumulation of OCP residues in tissues has been attributed to particular types of fatty acid derivatives. The study concluded that while pesticide diffusion to edible tissues can occur during ice storage, the levels observed were well below the allowable limit for endosulfan, endrin, and DDT.

Residual levels, phase distributions, and human health risks of OCPs in the middle reach of the Huai River, China.

Are the residues of organochlorine pesticides (OCPs) in freshwater in China still of concern after prohibition and restriction for decades? The scarcity of monitoring data on OCPs in freshwater in China over the past few years has hampered understanding of this issue. In this study, water and suspended particulate matter (SPM) samples were collected from the middle reach of the Huai River for OCP analyses. Residues of ∑OCPs in water and SPM ranged from ND to 8.6ng L-1 and 0.50 to 179ng L-1, with mean concentrations of 1.7 ± 1.3ng L-1 and 6.1 ± 31ng L-1, respectively. ∑HCHs (α-, β-, γ-, and δ-HCH) and ∑HEPTs (heptachlor and heptachlor epoxide) were the most predominant pesticides in the dissolved phase and SPM, respectively, accounting for 43 ± 35% and 27 ± 29% of ∑OCPs. HCHs and heptachlor epoxide mainly existed in the dissolved phase, while heptachlor mainly existed in SPM. The isomeric composition pattern of HCHs in water differed from that in SPM. Briefly, β-HCH dominated in water, while δ-HCH dominated in SPM. However, the composition pattern of DDT and its metabolites in water was similar to that in SPM. o,p'-DDD and p,p'-DDE dominated in both water and SPM. The ratios of α-/γ-HCH and (DDD + DDE)/DDTs indicated that HCHs and DDTs were mainly derived from historical residues. Risk assessments indicated that OCPs may not pose carcinogenic and non-carcinogenic risks to residents.

Biochemical Response of the Endogeic Earthworm (Balanteodrilus extremus) Exposed to Tropical Soils

This work evaluated the biochemical responses of the endogeic earthworm Balanteodrilus extremus exposed for 14 and 48 days (d) to soils collected from two tropical agricultural systems: maize-sorghum (MS) and soybean-sorghum (SS). A soil without agricultural management (WAM) and the use of pesticides was selected as a reference. The presence of organochlorine (OC) and organophosphate (OP) pesticide residues was quantified in MS and SS soils. Biomarkers of detoxification [glutathione S transferase (GST)], neurotoxicity [acetylcholinesterase (AChE)] and oxidative stress [superoxide dismutase (SOD), catalase (CAT) and lipoperoxidation (LPO)] were evaluated in B. extremus. The concentration of OP pesticide residues was higher in SS than in MS. Activity of AChE in B. extremus exposed to SS soil for 14 d was significantly more inhibited (78%) than in MS soil (68%). B. extremus has been shown to be a good bioindicator of contaminated soils in tropical regions.

Polyaniline-coated kapok fibers for convenient in-syringe solid-phase microextraction and determination of organochlorine and pyrethroid pesticide residues in aqueous samples

Pesticides used in agriculture have low polarity and a tendency to accumulate in fatty tissues, posing potential risks to human health. Effective pre-treatment is crucial due to complex sample matrices and low concentrations of pesticide residues typically encountered in instrument analysis. In this study, polyaniline-coated kapok fiber (PANI-KF) was synthesized successfully using in-situ oxidative polymerization for use as sorbents in in-syringe SPME of pyrethroid pesticides (PYRs) and organochlorine pesticides (OCPs) from aqueous samples. Coating the natural KF with PANI maintained the hollow microtubular structure and fiber morphology while significantly enhancing the extraction efficiency. The extraction process was easily conducted by simply pulling and pushing the syringe plunger. The entire extraction process, utilizing 3 mg of PANI-KF, could be completed in approximately 3 min. Density functional theory results indicated that the adsorption mechanism of PANI-KF towards OCPs and PYRs mainly involved van der Waals interactions, π-π interactions, and weak hydrogen bonding interactions. With the coupling of gas chromatography-mass spectrometry, a quantification method was established that exhibited good linearities (R2 > 0.990), and relative recoveries (87.2–108.5 %). The limits of detection ranged from 0.4 to 2.0 ng mL−1 and the matrix effects were negligible (−12.3–16.4 %). The validated in-syringe SPME-GC-MS method was successfully applied to determine pesticide residues in fruit juices, oral liquids and herbal extract granules with satisfactory accuracy and precision. PANI-KF exhibits remarkable promise as a sorbent for the extraction and enrichment of pesticide residues in aqueous samples, thereby contributing to the advancement of pesticide residue determination methodologies.

Organochlorine pesticide residues in water and sediments in river Kibos-Nyamasaria in Kisumu County: An inlet river of Lake Victoria, Kenya

The misuse of organochlorine pesticides (OCPs) and the lack of adequate regulations have led to contamination of rivers and lakes. In this study, we determined the concentrations of OCPs that have either been banned or restricted for use in the Kibos-Nyamasaria River during two seasons: wet (April-May) and dry (February-March). OCPs were analyzed using GC–MS. Nineteen pesticide residues were detected in the river (water) and sediments. In water, aldrin had the highest concentration of 8.33 ± 0.58 μg/L, dieldrin (8.67 ± 0.5 μg/L), endosulfan sulphate (0.23 ± 0.00 μg/L), α-endosulfan (0.19 ± 0.00 μg/L), methoxychlor (4.57 ± 0.03 μg/L) and α-HCH (3.47 ± 0.00 μg/L) during the wet season, while dieldrin (6.03 ± 5.1 μg/L), methoxychlor (3.43 ± 0.06 μg/L), and α-HCH (8.27 ± 0.06 μg/L) were above 0.1 μg/L detection limit during the dry season. In sediments, aldrin, methoxychlor, and δ-HCH were not detected in either season; however, dieldrin and β-endosulfan were detected only during the dry season. Additionally, OCPs were above 0.2 μg/kg (maximum residue level (MRLs). The concentration of OCPs increased downstream as the river approached Lake Victoria. Because some pesticides were present at levels beyond the recommended limits, strategies must be developed to reduce them and identify potential sources of banned pesticides.

Persistent pesticides: Accumulation, health risk assessment, management and remediation: An overview

Pesticides are being employed for large-scale agricultural purposes, leading to global environmental issues. Organochlorine pesticides (dieldrin, DDT, and aldrin) are persistent due to their stable nature. Organochlorine pesticide (OCPs) residues present in various foodstuffs, blood serum, air, water, soil and sediments have generated a global surge due to their severe health as well as environmental ill effects. It pollutes air, soil, water resources and gets transferred into the tropic level through food chains and food webs. Studies reveal that incecticides (pesticides) may harm pulmonary, fertility, circulatory, neuronal, hormonal and endocrine functions leading to severe health ailments. In the present article, the fate of persistent pesticides in different ecosystems has been reviewed. Challenges and policies of pest management have been critically discussed.

Research progress on remediation of organochlorine pesticide contamination in soil.

Deteriorated soil pollution has grown into a worldwide environmental concern over the years. Organochlorine pesticide (OCP) residues, featured with ubiquity, persistence and refractoriness, are one of the main pollution sources, causing soil degradation, fertility decline and nutritional imbalance, and severely impacting soil ecology. Furthermore, residual OCPs in soil may enter the human body along with food chain accumulation and pose a serious health threat. To date, many remediation technologies including physicochemical and biological ways for organochlorine pollution have been developed at home and abroad, but none of them is a panacea suitable for all occasions. Rational selection and scientific decision-making are grounded in in-depth knowledge of various restoration techniques. However, soil pollution treatment often encounters the interference of multiple factors (climate, soil properties, cost, restoration efficiency, etc.) in complex environments, and there is still a lack of systematic summary and comparative analysis of different soil OCP removal methods. Thus, to better guide the remediation of contaminated soil, this review summarized the most commonly used strategies for OCP removal, evaluated their merits and limitations and discussed the application scenarios of different methods. It will facilitate the development of efficient, inexpensive and environmentally friendly soil remediation strategies for sustainable agricultural and ecological development.

Organochlorine and pyrethroid residue in fish and sediment of Lake Singkarak, a tropical deep lake

Agricultural activities still involve the use of synthetic pesticides to support the increase of their products. On the other hand, the use of synthetic pesticides such as organochlorines and pyrethroids may contribute to the decline of aquatic ecosystem health due to the accumulation of their residues in sediments and organisms. The current study aimed to assess the levels of organochlorine and pyrethroids pesticide residue in endemic fish and sediment from Lake Singkarak. Bilih fish and sediment samples were taken in June 2021 at ten (10) sampling sites in Lake Singkarak. The samples were extracted and analyzed by gas chromatography. Seven organochlorine compounds were measured, including aldrin, endrin, dieldrin, DDT, heptachlor, lindan, and endosulfan. Meanwhile, three compounds chosen from the pyrethroid group, cypermethrin, permethrin, and α-cypermethrin, were also measured. Four organochlorine compounds, aldrin, dieldrin, DDT, and endrin, were detected in bilih fish in three different sites. Dieldrin had the highest concentration at nd-0.007 mg/kg, followed by DDT, endrin, and aldrin. Meanwhile, in the sediments, no organochlorine compounds were detected from all observed sites. Pyrethroid compounds were detected in bilih fish at six sites. The compound with the highest concentration was permethrin (nd-0.02 mg/kg), followed by cypermethrin and α-cypermethrin. The surface sediment from three sites contained two pyrethroid residues, permethrin and α-cypermethrin, at nd-0.002 and nd-0.001 mg/kg, respectively. Our findings show that the residual levels of organochlorine and pyrethroid in bilih fish still meet the standards set by the Codex Alimentarius Commission (CAC). Nevertheless, Bilih fish accumulate more pesticide than surface sediment, so it is essential to be aware of their potential accumulation in the human body as the final consumer. Restriction on synthetic pesticide application is necessary to reduce its residue input into the lake waters for ecological and human health.

Pollution Assessment with Persistent Organic Pollutants in Upper Soil of a Series of Rural Roma Communities in Transylvania, Romania, Its Sources Apportionment, and the Associated Risk on Human Health

This paper aims to assess the pollution by determining the sources of persistent organic pollutants (POPs) in 22 rural Roma communities in Transylvania in order to assess the human health risk associated with this exposure. For this, 16 polycyclic aromatic hydrocarbons (PAHs), 20 organochlorine pesticides (OCPs) and 12 polychlorinated biphenyls (PCBs) were determined in 22 soil samples collected from selected areas by gas chromatography coupled with mass spectrometry for PAHs and with electron capture detector for all halogenated compounds. Target compounds were isolated from soil by ultrasound-assisted extraction. We found that POP concentrations in soil ranged from 4.86 to 451.85 ng/g dw for PAHs, from 25.62 to 139.30 ng/g dw for OCPs, and from 0.22 to 49.12 ng/g dw for PCBs. The diagnostic ratios ƩLMW/ƩHMW, ANT/(ANT + PHE), and FLT/(FLT + PYR) strongly suggest a pyrogenic model of PAHs, such as biomass, coal, and petroleum combustion, while the isomer ratios ƩDDT/ƩHCH, α-HCH/γ-HCH and (DDE + DDD)/ƩDDT suggest that OCP residues originate from their ancient uses. Non-carcinogenic (HI) and carcinogenic (CR) risks of these organic compounds present in the soil through non-dietary pathways were in the very low-risk category (ranging from 10−8 to 10−4), indicating an absence of these risks from the investigated POPs in the studied area.

Distribution, Transfer, and Health Risk of Organochlorine Pesticides in Soil and Water of the Huangshui River Basin.

The potential negative impacts of organochlorine pesticides on the environment and human health continue to receive attention. In order to study the spatial distribution characteristics of organochlorine pesticides in the inland alpine region, researchers collected soil and water samples in the Huangshui River Basin of the Qinghai-Tibetan Plateau and tested them for organochlorine pesticide residues represented by dichlorodiphenyltrichloroethane (DDT) and hexachlorohexane (HCH). The study identified the sources of OCPs by component analysis. We also constructed the LEVEL III model, applicable to the Huangshui River Basin, and used it to study the migration patterns of OCPs in various environmental media. OCPs were detected at low levels in the study area environment. The results of the OCPs source analysis show that there are both historical residuals and new sources in the region. Residual DDTs may originate from the mixture of technical DDTs and dicofol, and HCHs may originate from lindane or technical HCH. DDTs are mainly stored in soil, the input and output pathways are mainly atmospheric advection input and output, and its transport behavior in the environment is mainly air-soil exchange. Carcinogens in the study area pose little threat to people exposed to contaminated soil and contaminated water, but the cancer risk to children is greater than to adults. This study is helpful to managers of regional pesticide management and control.

Occurrences, Possible Sources, and Risk Impacts of Organochlorine Pesticides in Soil of Changchun Central Urban Area, Northeast China

Eighteen organochlorine pesticides (OCPs) in soil samples from the Changchun central urban area, Northeast China were analyzed using accelerated solvent extraction combined with gas chromatography/mass spectrometry (ASE-GC/MS) for the purpose of elucidating their contamination status, distribution characteristics, influencing factors, and feasible dangers in this city region. The complete concentrations of OCPs ranged from 15.63 to 92.79 ng/g, with a geomean of 36.46 ng/g. Hexachlorocyclohexane(HCHs), dichlorodiphenyltrichoroethane (DDTs), and chlordanes were the most dominant OCPs, with γ-HCH and p,p′-DDT being the predominant isomers. Higher concentrations of OCPs often centered to the northeast and southwest of the Changchun metropolis, and these artificial influences contributed to the destiny of OCPs in the soils. The residues of OCPs were derived from the historic utility of the technological DDT, dicofol, and lindane. A Pearson’s correlation evaluation indicated that TOC was once a key factor controlling OCP accumulation. The ecological risk evaluation based on the soil quality guidelines (SQGs) advises that the presence of DDTs, lindane, and heptachlor may additionally pose a poisonous ecological danger to soil organisms. The contrast outcomes of the incremental lifetime cancer risk (ILCR) confirmed that the highest cancer risk of OCPs to the posed populace was once low, whilst some unique areas with excessive OCP residues ought to be given attention. The research results provide basic information for evaluating the extent of OCP pollution in the soil of major cities in Northeast China and can help authorities establish environmental protection regulations and soil remediation techniques.

Levels and Health Risks of Heavy Metals and Organochlorine Pesticide Residues in Soil and Drinking Water of Flood-Prone Residential Area of Lagos, Nigeria

Levels and Health Risks of Heavy Metals and Organochlorine Pesticide Residues in Soil and Drinking Water of Flood-Prone Residential Area of Lagos, Nigeria