Mineralogical Composition Research Articles

Effect of Ultrasonic Pre-Treatment on the Reverse Flotation of Kaolinite From Bauxite

ABSTRACT Cationic reverse flotation of kaolinite from bauxite is an alternative to adequate high silica bauxites to the specifications of the Bayer process. However, the presence of clay minerals influences the slurries rheology decreasing the flotation performance. The objective of this work was to investigate the use of ultrasonic pre-treatment on kaolinite flotation and contrast it with the traditionally used chemical dispersant. Two bauxite samples were characterized in terms of chemical and mineralogical composition, as well as particle size distribution. Flotation was accomplished after conditioning with sodium polyacrylate and/or pre-treatment in ultrasound. Determinations of viscosity, sedimentation yield, and screening followed by the analysis of available alumina and reactive silica were also conducted. By increasing the concentration of solids to more than 20 wt.%, the slurry behavior changed from a Newtonian to a non-Newtonian behavior, the viscosity increased, and the flotation performance decreased. The use of chemical dispersant and ultrasonic pre-treatment increased the flotation performance. The ultrasound had a more marked effect in slurries with higher concentrations of solids. This result is related to the synergic effect of particle dispersion and reduction of the slime coating promoted by kaolinite onto gibbsite particles.

The depositional evolution and associated controls on reservoir property in the Permian Upper Urho Formation, Southern Zhongguai Rise, Junggar Basin, NW China

The Permian strata in southern Zhongguai Rise are famous for their abundant petroleum reservoirs. The depositional evolution of the Upper Urho Formation has been studied analyzing the interactions between the sedimentary environments and the diagenetic evolution based on the comprehensive analysis of geological and geophysical datasets. The obtained results have shown that fan delta deposits, overlain by lacustrine deposits, were deposited. Proceeding upwards, the fan delta succession is characterized by retrogradational patterns, including both sandstone facies and conglomeratic facies. These facies have shown different clay mineralogic composition, porosity and physical properties. The sandstone facies shows well-sorted and well-rounded sedimentological textures, with good physical properties. In contrast, the conglomeratic facies shows poorly-sorted and poorly-rounded sedimentological textures, with poor physical properties. All these characteristics leading to reservoir heterogeneity result from sedimentary facies and diagenesis.

Magmatic–hydrothermal stage recorded by mica zonation and Nb–Ta–W–Sn mineralization: New insight into the genesis of highly evolved Songshugang Nb–Ta deposit (Jiangxi, SE China)

The role of magmatic and hydrothermal processes in niobium-tantalum mineralization is still controversial and has been limited by a lack of mineralogical records in the evolving magmatic–hydrothermal system. Micas as essential rock-forming minerals and comprise the amount of elements (especially rare-metal elements), become one of the ideal indicator. The Songshugang rare-metal granite (RMG) located in the southern part of Jiangxi Province, China, is renowned as the largest tantalum reservoir in South China. The albite–topaz–K-feldspar granite is the major granite, with layers of pegmatite, topaz-K-feldspar granite, and greisen overlay on it. It is the typical highly evolved peraluminous with low phosphorous RMGs (PLP-type) according to geochemistry. The Songshugang pluton preserves analogical characters in topaz-albite-K feldspar granites and topaz-K feldspar granite, and partly reserves in greisen. Detailed petrographic, mineralogy, and chemical composition study of zoned mica and accessory Nb–Ta minerals suggest that zinnwaldite and Nb-Ta oxides have experienced magmatic fractionation with gradually decrease of K/Rb and Nb/Ta ratio in prismatic zinnwaldite and columbite-(Fe). The leap of Rb (Rb2O up to 4.08 wt%) and Ta (Ta# up to 0.29) at the rim of zinnwaldite and columbite is likely attributed to supersaturation. Afterwards the overgrowth of Rb-deficit zinnwaldite (0.56–0.72 wt% Rb2O) is coeval with the Ta-highest wodginite, taking place during the magmatic-hydrothermal transition associated with a fluid-melt interaction in hydrosaline melt. The ascent of fluxing elements contributes to the formation of hydrothermal zinnwaldite and cassiterite through greisenization. The systemic coupling mineralization of zinnwaldite and Nb–Ta oxides altogether record the both the melt-driven and fluid-driven processes in highly evolved Songshugang deposit that is critical for rare-metal mineralization. The Songshugang displays a great similarity to the typical PLP RMGs Cínovec cupola in geochemistry, which are metaluminous to peraluminous, containing low phosphorous, intermediate REE, Zr, Hf, and Th content. But Songshugang has experienced strong supersaturation; the latter is more akin to highly evolved melts alike Yichun or Beauvoir. The strong supersaturation and crystallization demonstrate its discrepant mineralization mechanism in Songshugang RMGs.

Evaluating the fresh and mechanical properties of steel slag aggregate concrete reinforced with steel fiber

In this study, steel slag (SS) and steel fiber (SF) were used to make environment-friendly high-strength concrete. Natural coarse aggregate (NCA) was initially substituted partially with SS at various substitution levels, i.e., 25 %, 50 %, 75 %, and 100 %, respectively, for getting the optimum substitution levels of SS in concrete. Afterward, SF, having an aspect ratio of 60, was considered with volume fractions of 0.15 %, 0.3 %,0.45 %, 0.6 %, 0.75 %, 0.90 %, 1.05 %, and 1.2 % in concrete. The water-to-binder ratio was taken as 0.35 for all the concrete mixes. For the fresh property, slump and compaction factor of concrete were determined. Similarly, for the mechanical property compressive strength (CS), split-tensile strength (STS), and flexural strength (FS) have been tested after the curing age of 28 and 56 days. Additionally ultrasonic pulse velocity (UPV) test was conducted to measure the quality of concrete. X-ray diffraction (XRD) was also performed to analyze crystalline phases and identify mineralogical composition within the concrete matrix. All the tests were compared with the standard concrete made with NCA. It has been found that the addition of steel slag aggregate (SSA) and SF enhances the mechanical properties of concrete, whereas it reduces workability. Substituting 50 % of SSA for NCA alongside 1.05 % of SF results in the highest CS, while employing 1.2 % SF achieves maximum STS, FS, and UPV.

Advances in Limnogeology: The lake‐basin‐type model revisited 25 years after…anomalies, conundrums and upgrades

AbstractThe lake‐basin‐type model classified the stratigraphic record of ancient lake systems according to rates of potential accommodation relative to sediment + water supply. The model convolved all modes and paths of water supply (direct fall, surficial, subsurface) with amounts and types of sediment supply (clastic, biogenic, chemical) into a single basin‐filling volume term (sediment + water); its major strength was its widespread applicability. This was supported by subsequent investigations confirming the utility of this approach, but it also revealed some important limitations due to simplifications in the original model. The model has been expanded here to address all inland waters (lakes, ponds, wetlands, playas) as well as adding two major subdivisions of the sediment + water term: (1) water supply paths and (2) the volume of water supply relative to sediment supply. Water supply flow paths in the subsurface are subdivided into ‘throughflow’, ‘recharge’ and ‘discharge’. Each of these groundwater hydrology states can be defined quite precisely by the ratio of net outflow to inflow, from persistently open to consistently closed. These paths can be deciphered using stable carbonate and oxygen isotope composition of primary lacustrine limestones, detailed sedimentology, stratigraphy, palaeontology and mineralogy. Distinguishing water supply paths provides additional insights into playa systems and the occurrence and character of evaporites and carbonates. The volume ratio of water to sediment supply most directly influences the water depths of lakes, ponds and wetlands, which affect water body hydrodynamics and ecosystem behaviour as well as the details of stratal stacking and depositional sequences. It helps fine‐tune estimates of the distribution of sediment texture, bedding, composition and organic matter content. The aim of this contribution is to address questions about the fundamental types of inland water bodies and to explain the new lake‐basin subtypes and provide examples that illustrate their potential to enable higher‐resolution, robust analysis of inland water systems and their stratigraphic records.

Low-Salinity Waterflooding for EOR in Field A of Western Offshore Basin: A Pilot Study Analysis with Laboratory and Simulation Studies—Early Observations

Carbonate reservoirs hold vast oil reserves, but their complex properties make traditional enhanced oil recovery (EOR) methods challenging. This study explores the application of low-salinity water flooding (LSWF) as a novel EOR method for India’s largest offshore carbonate oil field. Conventional EOR techniques were deemed unsuitable due to reservoir heterogeneity, pressure decline, high temperature, and the offshore location. Favorable factors for LSWF included successful seawater flooding history, medium-weight crude oil, and existing infrastructure. Following core flooding experiments demonstrating a 6–16% increase in oil recovery, a multi-pronged evaluation process was implemented. Single-well chemical tracer tests (SWCTT) and reservoir simulations confirmed the potential of LSWF. A specific target area was chosen based on reservoir characteristics, production data, and available facilities. Simulations predicted a 1.5% incremental oil recovery using diluted seawater (25% salinity) at 30% pore volume injection. After a positive techno-economic analysis, the first offshore LSWF project in India was completed within 3 years. Initial monitoring results are encouraging. This study highlights the successful journey of LSWF from concept to field deployment in a challenging carbonate reservoir, showcasing its potential for revitalizing such fields. Furthermore, this work provides valuable data relevant to Indian offshore environments, where factors like salinity, mineralogy, and crude oil composition pose unique challenges compared to other LSWF applications. These detailed data fill a critical gap in the existing literature.

Nephrite from Xinjiang Qiemo Margou Deposit: Gemological and Geochemical Insights

The nephrite belt in the Altun Mountain–Western Kunlun Mountain region, which extends about 1300 km in Xinjiang, NW China, is the largest nephrite deposit in the world. The Qiemo region in the Altun Mountains is a crucial nephrite-producing area in China, with demonstrated substantial prospects for future exploration. While existing research has extensively investigated secondary nephrite deposits in the Karakash River and native black nephrite deposits in Guangxi Dahua, a comprehensive investigation of black nephrite from original deposits in Xinjiang is lacking. Margou black-toned nephrite was recently found in primary deposits in Qiemo County, Xinjiang; this makes in-depth research on the characteristics of this mine necessary. A number of technical analytical methods such as polarizing microscopy, Ultra-Deep Three-Dimensional Microscope, electron microprobe, back-scattered electron image analysis, X-ray fluorescence, and inductively coupled plasma mass spectrometry were employed for this research. An experimental test was conducted to elucidate the chemical and mineralogical composition, further clarifying the genetic types of the black and black cyan nephrite from the Margou deposit in Qiemo, Xinjiang. The results reveal that the nephrite is mainly composed of tremolite–actinolite, characterized by Mg/(Mg + Fe2+) ratios ranging from 0.86 to 1.0. Minor minerals include diopside, epidote, pargasite, apatite, zircon, pyrite, and magnetite. Bulk-rock rare earth element (REE) patterns exhibit distinctive features, such as negative Eu anomalies (δEu = 0.00–0.17), decreasing light REEs, a relatively flat distribution of heavy REEs, and low total REE concentrations (1.6–38.9 μg/g); furthermore, the Cr (6–21 μg/g) and Ni (2.5–4.5 μg/g) contents are remarkably low. The magmatic influence of granite appears to be a fundamental factor in the genesis of the magnesian skarn hosting Margou nephrite. The distinctive black and black cyan colors are attributed to heightened iron content, mainly associated with FeO (0.08~6.29 wt.%). Analyses of the chemical composition allow Margou nephrite to be classified as typical of magnesian skarn deposits.

Performance of compressed earth bricks reinforced with sugar industrial by-products bagasse and molasse: Mechanical, physical and durability properties

Because sustainable development is a major concern, many studies focus on reducing greenhouse gas emissions during the manufacturing of building materials. Therefore, in this study, we aim to produce lightweight eco-friendly compressed earth bricks (CEB) using industrial sugar by-products, sugarcane bagasse fibers (SCB) and molasse (SCM), as soil stabilizers to diminish the employment of cement. First, we investigated the physical, chemical, and mineralogical composition of the sugar by-products and the used soil. Then, we produced three types of CEB: bricks with soil and SCM (5 wt% and 10 wt%), bricks with soil and SCB (0.5 wt%, 0.75 wt%, and 1 wt%), and bricks with soil, SCB and SCM (this mixture considered two variable parameters: 5 wt% and 10 wt% of SCM, with varying SCB concentrations at three distinct levels: 0,5 wt%, 0.75 wt% and 1 wt%).The results showed that the incorporation of SCM as a stabilizer instead of cement in CEB enhanced both the dry and wet compressive strength, reaching 11.128 MPa and 9.897 MPa, respectively, which represent more than three times the results for the reference soil brick. As to the soil-SCB matrix, the incorporation of SCB decreased the compressive strength by about 36 % (from 3.338 MPa corresponding to reference brick composed only with soil to 2,142 MPa related to bricks stabilized with 1 wt% of SCB). Finally, for the composite soil-SCB-SCM, the highest value obtained was 9.309 MPa related to 10 wt% of SCM and 0.5 wt% of SCB. Moreover, the durability properties including dry abrasion, erosion, and capillarity tests were investigated and compared. The results indicated that SCM has satisfactory durability criteria while bricks stabilized with only SCB showed low resistance, especially to the capillarity test.

Microfacies and mineralogical analyses of the late cretaceous carbonate rocks from The Central Benue Trough, Nigeria

The Cretaceous limestone facies from Yandev section in the central Benue Trough, Nigeria constitutes parts of the potential reservoirs  and sources rocks for petroleum prospects in the basin. The central Benue Trough is the least studied basin among its contemporaries  due to lack of subsurface data. Detailed mineralogical, facies analysis and diagenesis of these carbonate rocks in the basin have not  received significant study. The aim of this study was to employed multifaceted methodology such as sedimentological, facies analysis  petrographic and geochemical approaches which was lacking in previous research in the trough. The sedimentological analysis was done  to evaluate fabrics grain sizes, and lithology types. For petrographic analysis, thin sections were prepared and examined under a  petrographic microscope and categorized according to Dunham's classification. Geochemical analysis involved X-ray fluorescence (XRF),  X-ray diffraction (XRD), and scanning electron microscope - energy dispersive X-ray spectroscopy (SEM-EDX) techniques to unveil  mineralogical, oxide, and elemental compositions. The sedimentological results revealed light to dark grey medium to fine-grained limestone facies with intercalation of dark grey shales and siltstones. The XRD mineralogy data, revealed calcite (60.00 - 64.10%), quartz  (14.30 - 51.00%), albite (12.30 - 19.00%), and chlorite (6.30 - 8.10%). Microfacies results revealed distinct sandy bioclastic wackstone and  sparitic intraclastic packstone, as well as micritic intraclastic wackestone and sparitic bioclastic packstone. SEM images highlighted the  intricate composition, including elongated structures, whites and dark spots suggesting varying conditions of deposition. Elemental  analysis through EDX emphasized significant proportions of carbon, oxygen, sodium, potassium, calcium, silicon, aluminum, iron, and  magnesium. Based on sedimentological, biofacies, lithofacies and geochemical evidence we infer that the carbonate sediments were  mainly deposited in a shallow marine depositional environment (inner to outer neritic).

An Archaeometric Study of Lead-Glazed Medieval Ceramics (13th–14th Century) from Santarém, Portugal

Ceramic sherds from approximately 20 samples of lead-glazed tableware, recovered from diverse archaeological sites, including three repurposed storage pits transformed into dumpsters within the medieval city of Santarém (13th–14th century), underwent a meticulous examination. This investigation utilised techniques such as micro-Raman, ground-state diffuse reflectance absorption, and X-ray fluorescence spectroscopies, in addition to X-ray diffraction and stereomicroscopy. A parallel study was conducted on contemporaneous European ceramics (glazed sherds) sourced from archaeological sites dating back to the 13th–15th centuries in Saintonge (France), Ardenne, Zomergem, and Bruges (Belgium), as well as Surrey–Hampshire, Kingston, and Cheam (England). The first premise for comparing the Santarem samples with European production locations was their frequent commercial relations with Portugal and the frequency of these productions being found in Portugal. The colour of the ceramic bodies is predominantly white or whitish, with a few exhibiting a vivid red hue. Analyses of the fabric, mineralogical, and elemental composition of the sherds suggest that the majority of Santarém’s glazed ceramics were locally or regionally produced, potentially derived from a Pliocene kaolin-rich sand formation. However, this conclusion is not supported by the absence of discovered lead glaze kilns or workshops in Santarém for the late Middle Ages.

An Archaeometric Study of the Iron Age Ceramics from Quinta do Almaraz Archaeologic Site (8th to 5th Centuries BC)—Colour and Mineralogical Characterization

The ceramic pastes of ca. 31 samples recovered from the Almaraz archaeological site, located in the south bench of Tagus River, were studied in detail using XRF, micro-Raman and GSDR spectroscopies, as well as the XRD technique. The ceramic sherds could be grouped into six categories, red slip tableware, decorated tableware, yellow slip tableware, grey tableware, common tableware, and handmade pottery. Our studies of the mineralogic composition of the sherds’ body indicate all ceramics were produced locally, using siliceous clays in most cases and calcareous clays in a few ones. Micro-Raman and ground state diffuse reflectance absorption spectroscopy provided useful information regarding the materials used to produce the coloured ceramics: hematite and brookite for the red slip and decorated ceramics, jacobsite or carbon black for the black decoration or grey ceramics. For the yellow slip tableware, a simple engobe rich in yellow clay was used. XRF spectroscopic studies provided the elemental composition of all samples, and biplots of the potassium (K) versus calcium (Ca) contents, normalized to the silicon content of each ceramic paste, clearly show Pliocene and Miocene local clays sources were used to produce most ceramics. Only one sherd can be considered a Lisbon production.

Durability of Ternary Blended Concrete Incorporating Rice Husk Ash and Calcined Clay

Research on the combined substitution of supplementary cementitious materials (SCMs) has already demonstrated that it might be one of the few viable options to produce low-carbon concrete at scale. This paper presents an experimental investigation on the performance and durability of rice husk ash (RHA) and calcined clay (CC) in ternary blended concrete exposed to chloride attacks under wet/dry cycles. Portland cement (PC) was replaced by RHA and CC up to 50% by weight to produce low-carbon concrete. Samples were subjected to wet/dry cycles in 3.5% NaCl water, with mineralogical composition and microstructure development before and after exposure analysed by TGA-DSC, MIP, XRD, and SEM. The durability of the concrete against wet/dry cycles was investigated in terms of compressive strength, water absorption, open porosity, density, thermal conductivity, and electrical resistivity. The results showed that concrete mixes with CC and RHA up to 60% exhibited an increase of 33% in compressive strength, followed by minimal changes in water absorption. While a decrease in electrical resistivity was measured in all samples with RHA and CC, increasing the CC content to 50% resulted in improved resistance to chloride penetration. Increasing the CC content resulted in a more refined microstructure, with an overall decrease in porosity of up to 32% compared to the control series. While RHA alone did not contribute to significant improvements after wet/dry cycles, the combined substitution of RHA and CC at SCM replacement levels of 60% showed an overall improvement in hardened properties and durability. This investigation provides valuable insights into the long-term performance and strength of innovative low-carbon concrete.

Geochemistry of the Winneba-Mankoadze pegmatites in Southern Ghana: A clue to the petrogenesis of the pegmatites

The Birimian Supergroup (2195–2135 Ma) of Ghana was affected by the Eburnean Tectono-thermal Event at approximately 2195 Ma. The latest stage of this event resulted in pegmatitic veining in the Birimian Supergroup of Ghana at 2072 Ma. Deposits of pegmatites have been reported by many researchers in the south-western coast of Ghana. However, their mineralogy and economic potential remain fully unexplored. This study determined the geochemical characteristics and mineralogical composition of the pegmatites in the Winneba-Mankoadze area using field observations, petrographic studies, and major and trace element data. From the field work and petrographic data, the pegmatites can be classified as rare-element type, LCT family. The modal composition of the major minerals are spodumene (0.0–30.0 %), muscovite (0.0–20.0 %), garnet (0.0–5.0 %), microcline (0.0–20.0 %), plagioclase (6.0–70.0 %), and quartz (20.0–85.0 %). The geochemical data indicates that the pegmatites are enriched in Rb (2.8–3465 ppm), Cr (22–1803 ppm), Sr (1.2–314 ppm), Ba (13–501 ppm) and the light rare-earth elements (LREE). The pegmatites are highly fractionated accounting for the enrichment in the LREE than the MREE and HREE. They are also depleted in K and Ti. The pegmatites are peraluminous with calc-alkaline trend and are late-orogenic to post-orogenic. Therefore, the source of the pegmatites is the Birimian meta-sedimentary rocks, and the source lithology is upper-to-middle crust supracrustal rocks.

Response of the Soil Organic Matter to Clear-cutting in the Face of Climate Change – a Report from the East Sudety Mountains, South-West Poland

Abstract Clear-cutting induces biogeochemical, ecological, and hydrological changes in the soil environment, especially in the conditions of climate change effect. This type of management affects soil carbon sequestration. In this paper, we generalize the effect of clear-cutting in mountainous mixed coniferous forests on the direction of organic matter transformation and the properties of humic substances. Soil samples of dystric Cambisols were taken two and ten years after clear-cutting (CC). Soil profiles located at the same elevation under forest cover without any harvesting were used as references. The contents of total organic carbon, total nitrogen, qualitative and quantitative characteristics of humic substances, as well as the mineralogical composition and the clay-associated C fraction, were analysed. Under mountainous conditions, clear-cutting in the mixed coniferous forest enhanced organic matter decomposition and decreased the low-molecular weight humic fraction. It also caused the accumulation of more stable humic acids, particularly in the upper soil horizons, and resulted in accumulation of humic substances with higher contents of C and O and lower H content in the first years after CC. Clear-cutting in the first two years reduced the aliphacity of humic acids in the topsoil. Ten years after harvesting, a significant increase in aliphacity in the Oa horizon confirmed organic matter recovery. Mixed coniferous forests are more resistant to biotic and abiotic disturbances, which is particularly important in the face of violent weather phenomena related to climate change. Thus, forest management plans should consider the conversion of spruce monocultures to mixed coniferous forests.

Chemistry in Retrieved Ryugu Asteroid Samples Revealed by Non-Invasive X-ray Microanalyses: Pink-Beam Fluorescence CT and Tender-Energy Absorption Spectroscopy

The Hayabusa2 space mission recently retrieved 5.4 g of material from asteroid Ryugu, providing the first direct access to pristine material from a carbonaceous asteroid. This study employs a novel combination of non-invasive synchrotron X-ray techniques to examine microscale chemistry (elemental distributions and element-specific chemical speciation and local structure) inside Ryugu grains without physically cutting the samples. Manganese primarily occurs in carbonate: Mn-bearing dolomite with minor earlier ankerite. Iron sulfides present as large single grains and as smaller particles in the finer-grained matrix are both predominantly pyrrhotite. At the 5 μm scale, Fe sulfides do not show the mineralogical heterogeneity seen in many carbonaceous meteorites but exhibit some heterogeneous localized oxidation. Iron is present often as intergrowths of oxide and sulfide, indicating incomplete replacement. Trace selenium substitutes for S in pyrrhotite. Copper is present as Fe-poor Cu sulfide. These results demonstrate multiple episodes of fluid alteration on the parent body, including partial oxidation, and help constrain the sequence or evolution of fluids and processes that resulted in the current grain-scale mineralogical composition of Ryugu materials.

Production technique and multi-analytical characterization of a paint-plastered ceiling from the Late Antique villa of Negrar (Verona, Italy)

The research focuses on analyzing the production techniques and materials of a Roman paint-plastered ceiling from a Late Antique Roman villa near Negrar (Verona, Italy), recently uncovered. Stylistic features of the decoration, found in reworked collapse debris during the villa’s excavation, date the ceiling to the original construction phase in the 4th century CE. The paper presents the protocol we adopted for recovering and analyzing the painted decoration of the villa, which was in-laboratory recomposed in its original layout after a meticulous and systematic retrieval of fragmented materials. Microsamples of mortar and pigment were then taken to fully reconstruct the execution technique and raw materials used in the paint-plastered ceiling, detailing the application of the tectorium and pigment preparation. Mortar samples were analyzed to define preparatory layer properties, using various analytical techniques including Transmitted-Light Polarized Optical Microscopy (TL-OM) and Scanning Electron Microscopy with Energy Dispersive X-Ray Analysis (SEM-EDS). Optical reflected-light microscopy detected guide incisions on the preparatory mortar, while Reflected-Light Optical Microscopy (RL-OM) revealed the microstratigraphy of pictorial micro-layers. Micro-samplings of painted decorations were conducted to define pigment palettes, determining their mineralogical composition through X-Ray Powder Diffraction (XRPD) analysis coupled with micro-Raman analyses for the determination of carbon-based compounds. The research aims to establish a comprehensive protocol for future endeavors, integrating archaeological reassembly with precise micro-analyses of pigments and mortars, deciphering the intricate layout of ancient, fragmented decorations. This study is the first of its kind in Northern Italy, overcoming challenges posed by fragmented and reworked artifacts in previous research, enabling detailed analytical studies like those conducted here. Moreover, this study of the paint-plastered ceiling of the Late Roman villa of Negrar aims to provide a new impulse for the knowledge of Late Antique painting techniques and materials, which were only marginally considered within Roman painting tradition so far.

Sedimentary facies and mineral provenance of Upper Triassic sandstones offshore Kvitøya, Svalbard: implications for palaeogeographic interpretations in the northern Barents Shelf area

Upper Triassic (Carnian) sandstones of the De Geerdalen Formation cored south of the island of Kvitøya (80°N), north-easternmost Svalbard, are described in terms of sedimentary facies and petrography and compared regionally in the northern Barents Shelf. The succession off Kvitøya is characterized by its great thickness and is dominated by deltaic deposits with high sand content of lithic–feldspathic compositions. Comparison of sediment facies and sandstone compositions with adjacent areas suggest that the succession off Kvitøya is part of a larger delta system with its main sediment source from the east. The delta sedimentation was terminated by marine transgression in the earliest Norian. The sandstone compositions off Kvitøya differ from nearby locations by the higher content of cherty rock fragments and reworked volcanic debris in the Kvitøya sandstone, which is most distinct in the lower part of the succession. Provenance signatures are investigated by mineral–chemical analysis of detrital feldspars, rock fragments, garnet and Cr-spinel, characterizing a wide variety of igneous, metamorphic and sedimentary terranes, including palaeo-Urals and areas farther to east. Additional, more proximal sediment source areas may also have existed that could explain the increased sediment thickness and the mineralogical immature sandstone compositions of the Carnian sediments off Kvitøya.

Petrology, Geochemistry and Mantle Minerals of the Walgidee Hills Lamproite, West Kimberley, Western Australia

Abstract The 17.44 Ma Walgidee Hills lamproite in the West Kimberley province of Western Australia is the type locality for several K-, Ba- and Ti-rich minerals characteristic of lamproites and, at 490 ha, the largest known lamproite. The Walgidee Hills pipe comprises a thin sequence of tuffs and breccia formed by explosive eruptions that excavated a large shallow crater that was infilled by lamproite magma which cooled and crystallised in situ. The lamproite is zoned in grain size, mineralogy, and mineral and rock composition from porphyritic olivine lamproite at the margin through medium grained lamproite comprised of olivine (altered), titanian phlogopite, diopside, leucite (altered) and titanian potassic richterite to coarse gained lamproite rich in potassic richterite, priderite, jeppeite, perovskite, apatite, wadeite and noonkanbahite at the centre of the body. Compositional zoning is evident across the lamproite in phlogopite (to lower Mg and Al, higher Fe), potassic richterite (to higher Fe and Na, lower Ti), priderite (to lower Cr) and perovskite (to lower Cr and Fe, higher Na, Sr, Y, Nb, U, REE). The Walgidee Hills lamproite is ultrapotassic and ranges from olivine lamproite (up to ~21 wt % MgO, ~800 μg/g Ni, ~4 wt % K2O) to sanidine/leucite-rich lamproite (~7 wt % MgO, ≤100 μg/g Ni, ~7 wt % K2O) at the centre of the pipe. The lamproite has low Al2O3, total Fe, Na2O and CaO (except for intensely carbonate-veined rocks at the centre) and is highly enriched in TiO2 (3−6.5 wt %), Ba, Rb, Sr, Zr and LREE (LaN = 150−520 x primitive mantle). A transect and geochemical contours show MgO, Ni and Cr contents decrease and P, K, Ti, Fe, Rb, Sr, Y, Zr, Nb, REE, Hf, Pb, Th and U abundances increase inwards to the most evolved rocks at the centre of the pipe, consistent with fractionation by inwards in situ crystallisation. The parent magma is estimated from the composition of the porphyritic olivine lamproite at the margins of the pipe to have ~16 ± 1 wt % MgO, ~600 μg/g Ni, ~6 wt % K2O with La/Yb ~ 150. Modelling suggests that the most MgO-rich lamproites result from entrainment of ~15–20 wt % mantle olivine in the parent magma. Cooling of the magma resulted in fractional crystallisation of olivine and in situ crystallisation with the evolved coarse-grained lamproites at the centre of the pipe crystallised from residual magma enriched in the more incompatible elements. Mantle xenocrysts include abundant Cr-Al spinel, chrome diopside, chrome pyrope, and rare diamond. Thermobarometry on the Cr diopside xenocrysts defines a cold paleogeotherm of ~38 mW/m2 and a thick lithosphere (~235 km) extending from the Kimberley craton. Many of the Cr diopsides from the deeper lithospheric mantle are enriched in K, Ba and LREE and these, and the Ti-rich spinel xenocrysts, are inferred to be derived from metasomatised mantle peridotite. The enriched trace element and Sr-Nd-Pb isotopic signatures of the Walgidee Hills lamproite suggest derivation from or extensive incorporation of ancient formerly depleted lithospheric mantle that has undergone metasomatism and long term (≥2 Ga) geochemical enrichment including by melts from Paleoproterozoic subducted crust.

Effect of thermal treatment on microcracking characteristics of granite under tensile condition based on bonded-particle model and moment tensor

It is known that the heterogeneity caused by thermally induced micro-cracks and thermal stress can affect the mechanical behavior of granite. The laboratory-scale tests have the intrinsic limitation of non-repeatability and lack of effective methods to characterize the interaction effect between thermal micro-cracks and thermal stresses. In this study, we demonstrate how advancements in particle bonded model and moment tensor can help better understand the roles of high temperature in weakening granite and thermally induced cracking process in Brazilian test. Our results show that the types of micro-cracks (intergranular, intragranular, and transcrystalline ones) are related to their thermal expansion coefficients of mineralogical compositions. The intergranular tensile micro-cracks are predominant during the heating and heating–cooling processes. An obvious weakening of granite and non-central initiation is associated with the heterogeneity caused by the thermal damage and thermal stress. We also quantitatively evaluate the thermal damage based on orientation distribution, b-value, and nature of the sources, which gives a new microcracking perspective on tensile characteristics subjected to high temperature.

Evaluation and application of Moroccan clay materials in ceramic tiles: Composition and technological behavior

This paper aims to assess the suitability of various Moroccan clay materials for application in ceramic tile production. Six clay samples (S1–S6) sourced from cities including Fez-Meknes, Safi, Berrechid, and Benslimane were collected and subjected to comprehensive characterization to elucidate their chemical and mineralogical composition, as well as their morphological and thermal behavior. The impact of sintering temperatures ranging from 900 to 1100 °C on parameters such as bulk density, porosity, water absorption, shrinkage, flexural strength, and chemical resistance was investigated. Results revealed elevated levels of Fe2O3 (>3 %), indicative of dark firing clays across all samples. Additionally, the samples exhibited a composition comprising clay minerals, quartz, feldspars, and carbonates. Based on the findings, it was determined that these clay materials are suitable for the production of cottoforte and majolica falling within the BIIb and BIII ceramic classes (ISO 13006). The study underscores the potential of these materials for utilization in industrial ceramic products, given their demonstrated characteristics.