Double-walled Carbon Nanotubes Research Articles

Plasmonic excitations in double-walled carbon nanotubes

The interactions of charged particles moving paraxially in multi-walled carbon nanotubes may excite electromagnetic modes. This wake effect has recently been proposed as a potential novel method of short-wavelength high-gradient particle acceleration and for obtaining brilliant radiation sources. In this work, the excitation of wakefields in double-walled carbon nanotubes is studied by means of the linearized hydrodynamic theory. General expressions have been derived for the excited longitudinal and transverse wakefields and related to the resonant wavenumbers which can be obtained from the dispersion relation. In the absence of friction, the stopping power of the wakefield driver, modelled here as a charged macroparticle, can be written solely as a function of these resonant wavenumbers. The dependencies of the wakefields on the radii of the double-walled carbon nanotubes and the driving velocity have been studied. Double-walled carbon nanotubes with inter-wall distances much smaller than the internal radius may be a potential option to obtain higher wakefields for particle acceleration compared to single-walled carbon nanotubes.

Stability and regularity for double wall carbon nanotubes modeled as Timoshenko beams with thermoelastic effects and intermediate damping

Stability and regularity for double wall carbon nanotubes modeled as Timoshenko beams with thermoelastic effects and intermediate damping

Enhancing Sensitivity of Double-Walled Carbon Nanotubes with Longitudinal Magnetic Field

In this study, the behavior of double-walled carbon nanotubes (DWCNTs) used as mass sensors is explored under various boundary conditions; particular attention is paid to the crucial topic of resonant nanomechanical mass sensors. In the presented approach, nanotubes are subjected to a distributed transverse magnetic force and supported by an elastic foundation. The impacts of the longitudinal magnetic field, elastic medium, and diverse physical parameters on the responsiveness of the sensors are assessed. Using the energy method, governing equations are formulated to determine the frequency shifts of the mass nanosensors. Our findings reveal significant variations in the frequency shifts due to a longitudinal magnetic field, which depends on the applied boundary conditions. This research holds significance in the design of resonant nanomechanical mass sensors and provides valuable insights into the interplay of factors affecting their performance. Through exploring the intricate dynamics of DWCNTs used as mass sensors and thus contributing to the broader understanding of nanoscale systems, the implications for advancements in sensor design are offered and applications are introduced.

Investigation of the effects of single and double-walled carbon nanotube utilization on diesel engine combustion, emissions, and performance

In this study, single-walled carbon nanotubes (SWCNT) and double-walled carbon nanotubes (DWCNT) were separately added to diesel fuel to investigate their effects on the combustion, performance, and emission characteristics of a diesel engine. SWCNT and DWCNT were added to diesel fuel at concentrations of 100 mg/L with the assistance of ultrasonication, resulting in the creation of DFCNT-1 and DFCNT-2 fuels. Fuel samples were tested at 1500 rpm under varying load conditions. The results indicated significant increases in combustion parameters such as cylinder pressure (CP), Net Heat Release Rate (NHRR), Rate of Pressure Rise (ROPR), Cumulative Heat Release (CHR), and average gas temperature (MGT) for DFCNT-1 and DFCNT-2 fuels. Additionally, the use of DFCNT-1 and DFCNT-2 fuels led to a decrease in carbon monoxide and smoke emissions while nitrogen oxide and carbon dioxide emissions increased. The Brake Specific Fuel Consumption (BSFC) decreased by 7.59% and 4.29% with the use of DFCNT-1 and DFCNT-2, respectively. Moreover, a shorter ignition delay (ID) and combustion duration (CD) were observed with DFCNT-1 and DFCNT-2 fuels. Overall, it was concluded that the addition of SWCNT was more effective than DWCNT in terms of combustion efficiency, performance, and emissions.

Dynamics and Stability of Double-Walled Carbon Nanotube Cantilevers Conveying Fluid in an Elastic Medium

The paper concerns the dynamics and stability of double-walled carbon nanotubes conveying fluid. The equations of motion adopted in the current study to describe the dynamics of such nano-pipes stem from the classical Bernoulli–Euler beam theory. Several additional terms are included in the basic equations in order to take into account the influence of the conveyed fluid, the impact of the surrounding medium and the effect of the van der Waals interaction between the inner and outer single-walled carbon nanotubes constituting a double-walled one. In the present work, the flow-induced vibrations of the considered nano-pipes are studied for different values of the length of the pipe, its inner radius, the characteristics of the ambient medium and the velocity of the fluid flow, which is assumed to be constant. The critical fluid flow velocities are obtained at which such a cantilevered double-walled carbon nanotube embedded in an elastic medium loses stability.

Nitrogen Adsorption on Double-Walled Carbon Nanotube at Different Temperatures: Mechanistic Insights from Molecular Dynamics Simulations

Nitrogen Adsorption on Double-Walled Carbon Nanotube at Different Temperatures: Mechanistic Insights from Molecular Dynamics Simulations

An Experimental Investigation on Performances and Emission Characteristics in a Multi-Cylinder Diesel Engine Using Nahar Oil Biodiesel Blended With Carbon Nano Tube

In recent years, the number of automobiles has drastically increased. As a result, the need for energy in the transportation sector is continuously rising. Additionally, using fossil fuels results in many hydrocarbon emissions, carbon monoxide, carbon dioxide, and particulate matter, spoiling the environment. Renewable energy sources like solar power, biodiesel, wind turbine, bioethanol, methanol, hydrogen, and various biomasses from wastes become a great subject of interest. This paper includes biodiesel production from Nahar oil with two-step transesterification and the performance and exhaust emission in a four-cylinder diesel engine fueled with double-walled carbon nanotubes blended with Nahar oil biodiesel. In this case, the B30 blend of Nahar oil biodiesel is taken as base fuel and different proportionate carbon nanotubes blends are compared with pure diesel. The performance analysis is done in a multi-cylinder test engine setup, and the emission of different exhaust gases is considered. The outcomes from the tests demonstrate that Nahar oil biodiesel and its mixes with carbon nanotubes can substitute diesel engines in the future when nonrenewable energy source stores become compromised.

A study on the effect of defects on the buckling of double-walled carbon nanotubes under compression based on a new atomic-continuum coupling method

An atomic-continuum coupling (ACC) method is developed for the nonlinear mechanical analysis of defective double-walled carbon nanotubes (DWCNTs). The moving least squares (MLS) approximation is resorted to bridge the fully atomic discrete structures of defective DWCNTs and the corresponding virtual continuum solids. The intrinsic mechanic laws implied in nanostructures can be accurately mapped into the mechanical governing equations of the continuum models. Based on ACC method, a numerical computational scheme is developed for predicting the buckling and contact behaviors of defective DWCNTs, which do not need any numerical integration method to calculate potential functional and its derivatives. The numerical tests show that this method can furnish good predictions even with a small number of nodes. It is found that Stone–Wales (SW) defects can lead to greatly decrease in the buckling properties of DWCNTs. In contrary, the complex interlayer van der Waals (vdW) interactions can enhance the buckling resistance of DWCNTs.

Preparing a liquid crystalline dispersion of carbon nanotubes with high aspect ratio.

We successfully prepared a surfactant-assisted carbon nanotube (CNT) liquid crystal (LC) dispersion with double-walled CNTs (DWCNTs) having a high aspect ratio (≈1378). Compared to dispersions of single-walled CNTs (SWCNTs) with lower aspect ratio, the transition concentrations from isotropic phase to biphasic state, and from biphasic state to nematic phase are lowered, which is consistent with the predictions of the Onsager theory. An aligned DWCNT film was prepared from the DWCNT dispersion by a simple bar-coating method. Regardless of the higher aspect ratio, the order parameter obtained from the film is comparable to that from SWCNTs with lower aspect ratios. This finding implies that precise control of the film formation process, including a proper selection of substrate and deposition/drying steps, is crucial to maximize the CNT-LC utilization.

Terahertz electric field induced melting and transport of monolayer water confined in double-walled carbon nanotubes.

Understanding the structures and dynamics of confined water in nanochannels holds great promise for various applications, ranging from membrane separation to blue energy collection. A setting of particular interest is the confined monolayer water within double-walled carbon nanotubes (DWCNTs), which demonstrates rich ice morphologies; however, the dynamics of this peculiar system are still unexplored. In this work, a series of molecular dynamics (MD) simulations reveal that the two-dimensional ice in DWCNTs can be effectively melted by terahertz electric fields but not by static electric fields, exhibiting an interesting ice to vapor-like transition along with extraordinary dynamical behaviors. Specifically, under appropriate field frequency, the water flow presents a sharp increase with the increase in field strength, indicating an excellent gating behavior. These remarkable findings are attributed to the resonance effect between the terahertz electric field and inherent vibration of water hydrogen bonds, causing the water molecules to change from the frozen to super permeation states. The amount of confined water exhibits a sudden reduction, confirming the breakdown of the hydrogen bond network. The distributions of density profiles, hydrogen bond number and dipole orientation demonstrate more details of the water structural change. Furthermore, under a certain field strength, the water flow shows a peculiar maximum behavior with the increase in field frequency, implying frequency optimization for water transport. These findings not only enhance our understanding of the phase transition behavior of water molecules confined within DWCNTs under the influence of a terahertz electric field but also provide a promising avenue for designing innovative nanofluidic devices.

Unraveling the governing properties of confined carbyne through the interaction with its carbon nanotube host

Linear carbon chains (LCCs), synthesized using carbon nanotubes (CNTs) as templates, exhibit intriguing properties that are not dependent on their length. Consequently, LCCs can also be identified as carbyne. Since such carbyne only exists confined to CNT, it is commonly called confined carbyne (CC). In this study, we investigate the interaction between CC and double-walled CNTs (DWCNTs) through resonance Raman spectroscopy. The optical band gaps and Raman frequencies of inner (6,4) and (6,5) CNTs are influenced both externally by the outer CNTs and internally by the encapsulated CCs. Remarkably, our findings demonstrate that the properties of CC are determined by the interaction between the encapsulated CC and the CNT. As a result, the optical band gap of the encapsulated CC is solely dictated by the hosting CNT, rendering it identical to the host's gap. Therefore, we propose a novel approach to tailor the properties of CC by selecting the appropriate chirality of the CNT. These findings pave the way for future applications of CC with tailored properties, offering promising application opportunities of this material as semiconductor.

Large hysteretic hydrogen adsorption in Double Wall Carbon Nanotubes bundles

We have observed isothermal large hysteretic hydrogen adsorption in samples made out of Double Wall Carbon Nanotubes (DWCNTs) bundles at 50 K, 77 K and 150 K and up to 1.3 MPa of pressure. In order to gain information about the microscopic mechanisms responsible for this remarkable phenomena we made a series of inelastic neutron scattering measurements at various temperatures and H2 loads. The elastic component of the signals (diffraction) observed at different loads are consistent with the uptake of the H2 molecules within the interstitials of the bundles. The quasielastic part, i.e., that centered around the null energy transfer, displays a dependence on momentum transfer which is reproduced by a 1D dimensional diffusion model as expected for interstitial confinement of the H2 fluid. Finally, the inelastic signals reveal rotational spectra that preclude the possibility of chemisorption onto the sample metallic impurities. To the best of our knowledge this is the first observation of supercritical H2 hysteretic adsorption in nanostructured carbons not ascribed to chemisorption onto metallic centers. Instead, the results point to the hierarchy of energy and entropic barriers associated with the adsorption into the bundle interstitials through the external grooves as the microscopic origin of the observed metastable adsorption.

Double-walled carbon nanotubes as effective conducting agents for lithium iron phosphate cathodes

The aim of this study was to compare the effectiveness of carbon black, single-walled carbon nanotubes (SWCNTs), and double-walled carbon nanotubes (DWCNTs) as conducting agents for lithium iron phosphate (LFP) cathodes. A water-based slurry system was employed by incorporating SWCNTs and DWCNTs with polyvinylpyrrolidone (PVP) as a dispersing agent and binder. Both SWCNTs and DWCNTs exhibited remarkable wrapping ability on the surface of LFP particles, affecting the electrical conductivity and physical properties (including adhesion and cohesion strengths) of the electrode, and then influencing the electrochemical performance of the cathode. Notably, the DWCNTs outperformed the SWCNTs as conducting agents, demonstrating higher electrical conductivity and adhesion/cohesion strengths, as well as improved rate performances. This can be attributed to the higher aspect ratio, better crystallinity, and superior mechanical strength of the DWCNTs. In situ Raman measurements conducted during the charge–discharge process showed significant changes in the Raman peaks. SWCNTs exhibited complete suppression of Raman signals upon lithiation, while DWCNTs displayed the unique ability of retaining the Raman peaks originating from the inner nanotubes, indicating the protective function of the outer tubes. These findings highlight the promising potential of the incorporation of SWCNTs and DWCNTs into cathodes, as their exceptional wrapping ability distinguishes them from multi-walled carbon nanotubes and carbon black. In particular, owing to their high aspect ratio and superior wrapping capabilities, the DWCNTs are expected to serve as effective conducting agents for advanced lithium-ion batteries.

Tribology Characteristic of Ball Bearing SKF RB-12.7/G20W using SAE 5W-30 Lubricant with Carbon-Based Nanomaterial Addition

The thermophysical, rheological, and tribological properties in lubricant are essential for preserving the engines, power steering systems, and engine components from damage caused by friction and wear. The incorporation of nano-sized particles into lubricating oils has been reported to enhance these properties. Therefore, this study explores the impacts resulting from the incorporation of graphene, multiwalled carbon nanotubes (MWCNT), double-walled carbon nanotubes (DWCNT), and single-walled carbon nanotubes (SWCNT) at a quantity of 0.04 grams into the SAE 5W-30 base oil. These nanoparticles were synthesized using a two-step method, resulting in nanolubricants. The addition of carbon-based nanomaterials increases the density and decreases the viscosity of the base lubricant. The flow of nanolubricants exhibits non-Newtonian shear thinning behavior during the test at elevated temperatures. The results of the four-ball tribo-tester test reveal the increase of Coefficient of Friction (CoF) values and the extent of wear scar area. Further, the Scanning Electron Microscopy (SEM) analysis was employed to observe the wear morphology of the nanolubricants on the SKF RB-12.7/G20W ball bearing. Its results indicate a prevalence of groove-type wear as compared to conventional lubricants.

Solving complex nanostructures with ptychographic atomic electron tomography

Transmission electron microscopy (TEM) is essential for determining atomic scale structures in structural biology and materials science. In structural biology, three-dimensional structures of proteins are routinely determined from thousands of identical particles using phase-contrast TEM. In materials science, three-dimensional atomic structures of complex nanomaterials have been determined using atomic electron tomography (AET). However, neither of these methods can determine the three-dimensional atomic structure of heterogeneous nanomaterials containing light elements. Here, we perform ptychographic electron tomography from 34.5 million diffraction patterns to reconstruct an atomic resolution tilt series of a double wall-carbon nanotube (DW-CNT) encapsulating a complex ZrTe sandwich structure. Class averaging the resulting tilt series images and subpixel localization of the atomic peaks reveals a Zr11Te50 structure containing a previously unobserved ZrTe2 phase in the core. The experimental realization of atomic resolution ptychographic electron tomography will allow for the structural determination of a wide range of beam-sensitive nanomaterials containing light elements.

Terahertz Generation through Coherent Excitation of Slow Surface Waves in an Array of Carbon Nanotubes

In this paper, we present a scheme for generating terahertz (THz) radiation using an array of parallel double-walled carbon nanotubes (DWCNTs) subjected to a direct current (DC). The longitudinal surface plasmon polaritons (SPPs) in the DWCNTs are coherently excited by two near-infrared laser beams with slightly different frequencies. Through numerical methods, we investigate the spectral characteristics of the SPPs in the presence of a DC current in the nanotubes. We identify high-quality plasmonic modes with a slowdown factor exceeding 300 in the terahertz frequency region. The amplification of these slow SPP modes is facilitated by the DC current in the DWCNTs, fulfilling a synchronism condition. This condition ensures that the phase velocity of the SPPs is closely matched to the drift velocity of the charge carriers, allowing for an efficient energy exchange between the current and the surface electromagnetic wave. The high-frequency currents on the nanotube walls in the DWCNT array enable the emission of THz radiation into the far field, owing to an antenna effect.

A CPC fractional model of the heat and mass transport mechanism in Carbon nanotubes with slip effects on velocity

A fractional technique is used to evaluate the temperature, mass, and velocity flow of single and double wall CNTs over a vertical plate. Slip boundary conditions and applied magnetic force are addressed. Human blood is used to examine how base fluid behaves. Applying the proper dimensionless variables results in the dimensionless formulation of initial and boundary conditions related to the governed dimensional concentration, momentum, and energy equations. The Laplace transform technique is used to resolve the dimensionless governing partial differential equations and get the solutions. The constant proportional Caputo (CPC) time-fractional derivative is a unique class of fractional model used in the simulation technique. The fundamental definitions are used to support the said model first. Using MWCNTs and SWCNTs in comparison to the flow characteristics, a thermal and mass study is given. The heat and mass transfer processes for single-walled carbon nanotubes (SWCNTs) have been shown to typically be progressive. The momentum profile decreases as the fractional variables rise. Multi-walled carbon nanotubes (MWCNTs) show more progressive velocity control as a result of the magnetic parameter. Graphs demonstrate the influence of embedding factors on the velocity, energy, and concentration profiles.

Enhanced Thermal Conductivity of Free-Standing Double-Walled Carbon Nanotube Networks.

Nanomaterials are driving advances in technology due to their oftentimes superior properties over bulk materials. In particular, their thermal properties become increasingly important as efficient heat dissipation is required to realize high-performance electronic devices, reduce energy consumption, and prevent thermal damage. One application where nanomaterials can play a crucial role is extreme ultraviolet (EUV) lithography, where pellicles that protect the photomask from particle contamination have to be transparent to EUV light, mechanically strong, and thermally conductive in order to withstand the heat associated with high-power EUV radiation. Free-standing carbon nanotube (CNT) films have emerged as candidates due to their high EUV transparency and ability to withstand heat. However, the thermal transport properties of these films are not well understood beyond bulk emissivity measurements. Here, we measure the thermal conductivity of free-standing CNT films using all-optical Raman thermometry at temperatures between 300 and 700 K. We find thermal conductivities up to 50 W m-1 K-1 for films composed of double-walled CNTs, which rises to 257 W m-1 K-1 when considering the CNT network alone. These values are remarkably high for randomly oriented CNT networks, roughly seven times that of single-walled CNT films. The enhanced thermal conduction is due to the additional wall, which likely gives rise to additional heat-carrying phonon modes and provides a certain resilience to defects. Our results demonstrate that free-standing double-walled CNT films efficiently dissipate heat, enhancing our understanding of these promising films and how they are suited to applications in EUV lithography.

Fabrication of a Co-Mo-Based Metal-Organic Framework for Growth of Double-Walled Carbon Nanotubes.

Double-walled carbon nanotubes (DWCNTs) make up a unique class of carbon nanotubes (CNTs) that are particularly intriguing for scientific research and are promising candidates for technological applications. A more precise level of control and greater yields can be achieved via catalytic chemical vapor deposition (CCVD), which involves the breakdown of a carbonaceous gas over nanoparticles. The addition of molybdenum to the system can increase the selectivity with regard to the number of walls that exist in the obtained CNTs. As reported herein, we have designed and synthesized a novel Co-Mo-MOF, [Co(3-bpta)1.5(MoO4)]·H2O (where 3-bpta = N,N'-bis(3-pyridyl)terephthalamide), and employed the Co-Mo-MOF as a bimetallic catalyst precursor for the CCVD approach to prepare high-quality DWCNTs. The Co-Mo-MOF was employed after being calcined in N2 and H2 at 1100 °C and decomposing into CoO, CoMoO4, and MoO3. Existing CoMoO4 is unaltered after reduction in H2 at 1100 °C, while CoO and MoO3 are converted into Co0 and MoO2, and more CoMoO4 is created at the expense of Co0 and MoO2 without clearly defining agglomeration. Finally, the interaction between metallic Co particles and C2H4 is what initiates the formation of DWCNTs. In-depth discussion is provided in this paper regarding the mechanism underlying the high selectivity and activity of Co-Mo catalysts in regulating the development and structure of DWCNTs. The DWCNTs also offer excellence performance when they are used as water purification agents and as selective sorbents. This work opens a feasible way to use MOFs as a way to produce MWCNTs, thus blazing a new trail in the field of MOF-derived carbon-based materials.

Nanoparticle-Exposure-Triggered Virus Reactivation Induces Lung Emphysema in Mice.

Nanoparticles (NPs) released from engineered materials or combustion processes as well as persistent herpesvirus infection are omnipresent and are associated with chronic lung diseases. Previously, we showed that pulmonary exposure of a single dose of soot-like carbonaceous NPs (CNPs) or fiber-shaped double-walled carbon nanotubes (DWCNTs) induced an increase of lytic virus protein expression in mouse lungs latently infected with murine γ-herpesvirus 68 (MHV-68), with a similar pattern to acute infection suggesting virus reactivation. Here we investigate the effects of a more relevant repeated NP exposure on lung disease development as well as herpesvirus reactivation mechanistically and suggest an avenue for therapeutic prevention. In the MHV-68 mouse model, progressive lung inflammation and emphysema-like injury were detected 1 week after repetitive CNP and DWCNT exposure. NPs reactivated the latent herpesvirus mainly in CD11b+ macrophages in the lungs. In vitro, in persistently MHV-68 infected bone marrow-derived macrophages, ERK1/2, JNK, and p38 MAPK were rapidly activated after CNP and DWCNT exposure, followed by viral gene expression and increased viral titer but without generating a pro-inflammatory signature. Pharmacological inhibition of p38 activation abrogated CNP- but not DWCNT-triggered virus reactivation in vitro, and inhibitor pretreatment of latently infected mice attenuated CNP-exposure-induced pulmonary MHV-68 reactivation. Our findings suggest a crucial contribution of particle-exposure-triggered herpesvirus reactivation for nanomaterial exposure or air pollution related lung emphysema development, and pharmacological p38 inhibition might serve as a protective target to alleviate air pollution related chronic lung disease exacerbations. Because of the required precondition of latent infection described here, the use of single hit models might have severe limitations when assessing the respiratory toxicity of nanoparticle exposure.