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Nanostructuring, fractal characterization and wettability of ion irradiated Au thin films and their thickness effect

This study proposes a method for modifying the wettability of Au thin films of thicknesses 5 nm and 10 nm on Si substrates using 8 keV Ne ion beam irradiation at different fluences, thereby enabling surface wettability adjustment at the nano-scale and its thickness dependence. This advancement would be highly beneficial for applications such as high-resolution printing and nano-biotechnology. The contact angle of the irradiated region for the 5 nm thin film changed from hydrophobic to hydrophilic with increasing ion dosage, whereas for the 10 nm thin film, it changed from hydrophilic to hydrophobic under the same conditions. Fractal analysis was performed on pristine and ion beam modified surfaces to investigate the underlying nano-structuring process, with reported values for average roughness (Ra), Hurst exponent (H), fractal dimension (Df), contact angle (CA), and wettability at different ion dosages. Atomic Force Microscopy and Rutherford Backscattering Spectroscopy were used to examine surface roughness and depth profile. The process of sputtering becomes crucial when the ion range approaches the thickness of thin films, with the sputter yield showing dependence on the thickness of thin films at different ion fluence levels. Monte Carlo simulations SRIM/TRIM and TRIDYN were used for comparison with the experimental results, with TRIDYN taking into account dynamic changes in the target's morphology and composition.

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Characterization of an enhanced formulation N-(3-methoxypropyl) acrylamide polymer gel dosimeter by the addition of an organic sensitizer for clinical practice

Polymer gel dosimeters are being developed and improved to perform measurements of radiation dose distributions in 3-dimensions (3-D) for the purpose of patient specific quality assurance for cancer patients and the configuration of treatment planning systems. The effect of organic glucose sensitizer (GL) material on N-(3-methoxypropyl) acrylamide polymer gel dosimeter (NMPAGAT) was presented in this study and evaluated after irradiation using nuclear magnetic resonance (NMR) read-out technique in terms of spin–spin relaxation rate (R2) of hydrogen protons within the water molecule. The improved tissue equivalent polymers of GL-NMPAGAT were irradiated using a medical linear accelerator with photon beams with doses up to 20 Gy, energies range 6–15 MV, dose rates range 50–500 cGy/min, and irradiation temperatures range 15–25 °C. The R2 dose sensitivity of GL-NMPAGT polymer with a concentration of 25 % wt GL was improved significantly and found to be two times higher than the same gel without GL in the linear dose response of 0.07–8 Gy. The 0.07 Gy represents the minimum detectable dose in the improved dosimeters. The dosimeter was found stable within a period of up to two weeks after irradiation, which is significant. No significant dose rate, energy dependence, and irradiation temperature for the dosimeter was observed over the range studied. There is decrease in R2 values with increasing scanning temperature. The gel is water equivalent and has theoretical energy-independent response from 0.1 to 20 MeV with density of 1.023 ± 0.003 g/cm3 and Zeff of 7.53. The results of the improved dosimeter in this study (i.e., 100 %, 0.32 s−1 Gy−1, and 8 Gy linearity) are toward the upper limit compared to other polymer gel dosimeters even with sensitizer additives.

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