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17 - Cathodic Protection of Ships

Cathodic protection of ships extends from the external protection of the underwater area including all attachments and openings, to the internal protection of various tanks, pipework, and bilges. Ships are exposed to water of very different compositions. The salt content and conductivity are particularly important because they have a profound influence on the action of corrosion cells. In addition, on ships problems of dissimilar metals must be considered. A distinction is made between complete and partial protection of the underwater area, depending on the extent of the protected region. In partial protection, only the stern is protected; it is particularly endangered because of the high flow rate and aeration as well as the formation of cells on attachments such as the propeller and rudder. Partial protection can also be extended to the bow, which also experiences high rates of flow. The complete protection of the ship with galvanic anodes or impressed current is becoming increasingly important because defects in the coating due to mechanical damage are more frequent at the bow and amid ships. The extent to which attachments such as propellers and rudders can be covered by the protection or be given individual cathodic protection depends on the design of the ship and the method of protection. The design of cathodic protection must involve the calculation of the Protection Current Requirement, Protection by Galvanic Anodes, and Protection with Impressed Current.

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21 - Internal Electrochemical Corrosion Protection of Processing Equipment, Vessels, and Tubes

Electrochemical corrosion protection of the internal surfaces of reaction vessels, tanks, pipes, and conveyor equipment in the chemical, power, and petroleum industries is usually carried out in the presence of strongly corrosive media. The range stretches from drinking water through more or less contaminated river and seawater frequently used for cooling, to reactive solutions such as caustic soda, acids, and salt solutions. Galvanic anodes are used for smaller objects to be protected such as water heaters and feedwater tanks. Large objects, such as power station condensers and inlet structures, are mainly protected with impressed current on economic grounds. Galvanic anodes are, however, also installed if an account has to be taken of protection against explosion and safety regulations regarding products of electrolysis. Areas of application include tanks for ballast, loading, petrol, water, and exchange tanks of ships as well as crude oil tanks. The choice of protection method and protection criteria should always be properly tailored. Coatings are usually applied to reduce the protection current requirement as well as to improve the protection current distribution in cathodic internal protection systems because they raise the polarization parameter. If the polarization parameter lies in the same range as the protected object, the current distribution is sufficiently good.

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23 - Interference Effects of High-Voltage Transmission Lines on Pipelines

In the context of this chapter, “ac interference” refers to the action of a high-voltage power plant on a pipeline by capacitive, ohmic, and inductive coupling. The results in frequent crossings and contiguity, and in stretches of lines running parallel for several kilometers, can lead to ac interference. This results not only in danger to the pipeline maintenance personnel, but also in damage to the cathodic protection. There are various kinds of interference: (1) capacitive interference (the production of electrical potentials in conductors due to the influence of alternating electrical fields), (2) ohmic interference (the production of electrical potentials in conductors by electrical contact), and (3) inductive interference (the production of electrical potentials in conductors due to the induction from alternating magnetic fields). Depending on the length of time the interference processes are active, a distinction is made among short-term and long-term interference. Short-term interference is a rare occurrence resulting from a failure in a high-voltage installation and very high interference currents. Long-term interference is a continuing action that involves lower voltages than short-term interference. To avoid disruption or danger to installations and people, recommendations for avoiding interference should be taken into account in planning pipelines and high-voltage installations. These should include regulations for routing energy corridors, measures to be taken in the construction and operation of pipelines, and the methods used to determine pipeline potentials under long- and short-term interference and safety requirements.

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9 - Impressed Current Ground Beds and Interference Problems

Cathodic protection of long pipelines, distribution networks, pipelines in industrial plants, and other buried installations with a high protection current requirement is achieved mostly by means of impressed current anodes. With a high protection current requirement, the grounding resistance of the anodes, as the highest resistance in the protection current circuit, determines the necessary rectifier voltage and also the power of the protection station. The lowest grounding resistance should be designed to keep down the electric power and therefore, the operating costs. The protection current is transmitted to the soil via the impressed current anode bed. Therefore, the current density and the field strength, the voltage drop per meter, are greatest in the vicinity of the anode bed; they decrease with the increase of distance from it. Where there is available ground and the specific resistivity of soil in the upper layers is low, the anodes are laid horizontally. Deep anodes are installed where the resistivity is high in the upper layers of soil and decreases with increasing depth. This type of installation is recommended for densely populated areas and for local cathodic protection on account of the small space needed and the smaller voltage cone, which avoids interference with foreign structures.

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20 - Internal Cathodic Protection of Water Tanks and Boilers

The chapter discusses the internal cathodic protection of water tanks and boilers, which is most economical if it is taken care of at the design stage. It also details the description and function of objects to be protected, such as boilers with enable linings and electrolytically treated water and water storage and filter tanks. In uncoated cathodically protected tanks, inserts must have an electrical connection to the tank to avoid damage due to anodic interference in the cathodic voltage cone of the surfaces of the object to be protected. Materials for metal tanks and installations include plain carbon steel, hot-dipped galvanized steel, stainless steel, and copper and its alloys. The corrosion resistance of these materials in water is very variable. Plain carbon steel that is uncoated is not corrosion resistant. Stainless steel can suffer chloride-induced localized corrosion. The rest of the materials are corrosion resistant due to the formation of protective films but can be attacked if the films have defects locally. Different linings and coatings are used to provide corrosion protection for the tank, which often makes economical cathodic protection possible. Organic coatings include phenol formaldehyde, epoxy, polyacryl and polyacryl acid resins, polyamide, polyolefin, bitumen and rubber. Cathodic blistering is not expected with high-resistance polyolefins and rubberized coatings; however, where there are defects, local reduction in adhesion (cathodic disbonding) is apparent. Enamel linings have the best resistance against cathodic influence.

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