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Study of the Mineral and Chemical Variation of the Raw Material Mix Used for Production of the Clinker and the Sulfate Resistant Portland Cement of Al-Hadbaa Plant, Hammam Al-Alil, Iraq

Twenty-four samples (6 samples of raw material mix slurry, 9 samples of cement clinker, 9 samples of sulfate resistant cement) are collected during four months from the production line of Al-Hadbaa Cement Plant, which operates in a wet production method, in Hammam Al-Alil district, south of Mosul city. Some of the studied samples are analyzed for mineral diagnosis by X-ray diffraction device, chemical analysis by X-ray fluorescence device, gravimetric titrimetric chemical methods, and petrographic study for the clinker samples by reflected light microscope and using etching solutions. The research aims to study the variation of the mineral and chemical content in the studied samples. The mineral and petrographical study show that there is no significant difference in the mineral content between the samples of the same type and that the difference is in the percentage of the presence of minerals. The raw materials mix mainly contains calcite and quartz. As for clinker and cement, it contains a lite phase C3S with a stable growth (pure) type with a monoclinic crystal system and a type of unstable growth (impure and containing inclusions) with a trigonal crystal system. In addition to the belite phase C2S of shapes β, α, and ᾱ, the aluminate phase C3A and C12A7 type and the alkaline type containing Na, the ferrite phase C4AF and C2F and the phase of fine crystalline glass. The chemical study indicates that the content of most of the main components SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Na2O, K2O, TiO2, MnO, P2O5, Cl, and LOI for the raw materials mix, clinker, and cement are close to the samples of the same type of the studied samples. It confirms the proposed specifications by some researchers, except for the deviation in K2O, Fe2O3. It is noticed from comparing the expected clinker content with the actual clinker, as well as calculating some of the qualitative control modules (lime saturation factor, silica, and alumina modulus) to the presence of relative stability in the content of the raw mix and cement produced in the studied cement plant.

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Morphometric Characteristics of Erosion Activity in the Komel River Basin

The study area is represented by the Komel River basin, which is located in Duhok Governorate, northern Iraq. Several secondary basins are selected in the northeast of Sheikhan district within the main Komel River basin. This basin is located between longitudes (43º 29´ 00= – 43º 10´ 30=) east, and latitudes (36º 57´ 30= – 36º 46´ 30=) north. The study aims to determine the erosion activity of the main Komel River basin and the secondary basins that make up the basin, by finding the morphometric characteristics and the shape of the hypsometric curve for these basins using the WMS7.1 Watershed Modeling System program. The results of the morphometric analysis are represented by the value of (Hi) and the shape of the hypsometric curve of the Great Komel River basin and its secondary basins showing a discrepancy in erosion activity from one basin to another. The topographical variation of the basins such as the rocky discoveries and the vegetation cover of each basin has been seen. The morphometric characteristics of the basins in general and the main basin, in particular, show the possibility of exploiting the main Komel basin in the water harvesting, as it is a basin in the maturity stage presented by the (Hi) value of (0.40) and is compatible with its hypsometric curve shape. The validity of the Komel River basin in the field of water harvesting is an encouraging conclusion for the development of planting this area with forest trees, pastoral plants, and crops. In a manner that suits the climatic environment of the region, especially if we take into account the basin area of (536,253) square kilometers, which will make the area a facility Tourist.

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Rock Magnetic Properties during the Paleocene-Eocene Thermal Maximum (PETM): Records from P/E boundary Sections (Sinjar, Shaqlawa) in Iraq

Rock magnetic properties have been investigated across the Paleocene/Eoceneboundary in two distally separate sections of Paleogene marine sedimentary rocksfrom Iraq, namely the Sinjar and the Shaqlawa sections. The sediments at thestudied sections belong to the Aaliji and the Kolosh formations respectively, whichwere previously examined for their biostratigraphy by the authors using planktonicand benthonic foraminifera to delineate the Paleocene/Eocene (P/E) transition.Measured magnetic properties include; bulk magnetic susceptibility, hysteresiscycles, isothermal remnant magnetization (IRM) acquisition, and thermomagneticcurves analysis. Rock-magnetic results (i.e. low magnetic coercivity component)indicate greigite as the main magnetic phase at Aaliji rocks, while a mixture ofmagnetite and greigite with high magnetic coercivity has been observed at Koloshclastics. Magnetic susceptibility is induced by related to both biogenic minerals(mainly at Aaliji Formation) and transported terrigenous material sources. Multivaried magnitude phases of high bulk rock magnetic susceptibility observed inboth formations along PETM lithosomes are attributed to two sources: greigite orbiogenic iron oxides source and increase in terrigenous discharge source asinferred by anoxic to suboxic iron - sulfate-reducing conditions and lithologicalchange respectively. Both sources referred to some of environmental conditionsassociated with Paleocene - Eocene thermal maximum events such as methanedissociation, water stratification, enhanced hydrological and weathering cycles.

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Validity of clay for Al-Fat’ha and Injana formations for the brick and ceramic industry in Nineveh Governorate

The scarcity of clay and alluvial deposits in the valley of the Tigris River and its tributaries in the northern region of Iraq called for the search for suitable clays for the construction ceramic industry in geological formations. A geological survey of the mudstone layers of the Al-Fat’ha and Injana formation rocks was conducted in the districts of Al-Hamdaniya, Telkaif, and Al-Shekhan in the Nineveh Governorate. Samples were taken of the layers that have an appropriate thickness and a topographical and mining position that facilitate exploitation in the event of the success of the raw materials for the industry. The study was conducted on five selected clay models from the village of Mehiwarat and the intersection of the Wana-Mosul Dam road, with two models, the village of Al-Nouran and Ain Al-Nouran. The results showed that most of the muddy geological layers are characterized by a high percentage of calcium and magnesium carbonate, and that the lowest percentage of calcium carbonate was in the layers of the Injana Formation taken from the village of Mehiwirat, which amounted to 16.83%, and that its classification is low-liquidity clay. Through the plasticity coefficient diagram and the plasticity limit, it was found that the clays of the Muhiwirat and Al-Nouran areas fell in the preferred range, while the rest were in the acceptable range. The prepared from Mehiwarat clay was characterized by a volume shrinkage of 16.1% and a weight loss of 23.4%, while the results of the tests indicated the brick models prepared from the clays of the intersection of Wana - Mosul Dam Road and Al-Nouran Village were within the category B, all according to the Iraqi standard specifications.

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Biostratigraphy and Sequence Stratigraphy and Depositional Environment of Kolosh Formation in Dohuk Area, Northern Iraq

The present study deals with biostratigraphy, depositional environment and sequence stratigraphy of Kolosh Formation in two sections of Bekher anticline, northeastern Iraq by using the planktonic and benthonic foraminifera. Therefore, (48) species of planktonic foraminifera belonging to (14) genera and (34) species of benthonic foraminifera belonging to (19) genera have been recognized. The detailed planktonic foraminiferal investigation permits the recognition of seven well defined biozones and three subzones; they indicate that Kolosh Formation extends from the Early Paleocene (Danian) to Late Paleocene (Thanetian) age. The depositional environment of the formation was studied throughout relying on the variation in the diversity of planktonic forminifera, as well as throughout the ratio of the planktonic foraminifera to the whole mass of foraminifera, and the ratio of planktonic forminifera to the benthonic formiminifera. The lower part of the formation represents the upper bathyal environment, while the middle part deposited within the outer shelf environment, then deposition basin became within the middle shelf area in the upper parts of the formation. Sequence stratigraphic analysis for the studied sections of Kolosh Formation delineated three sequences which is interpreted as 3rd order sequences, and it is found that the deposition of Kolosh Formation in the Badi section had been occurred in shallower level for most sedimentation intervals compared to the Linwa section which represents a somewhat deeper marine environment.

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Geochemistry and Petrogenesis of Dioritic-Gabbroic Pegmatites in the Bulfat Complex, Qala Diza, Northeastern Iraq

The pegmatite dikes and associated plutonic rocks stand as a part of the igneous complexes associated with the Bulfat complex, located in the Zagros Suture Zone (ZSZ), NE Iraq. The Bulfat complex is a part of the ophiolite-bearing terranes that are allochthonous sheets. The complex represents the upper allochthon of the Albian-Cenomenian. The study area is located within Bulfat complex of ZSZ, specifically in the northwestern part of this zone and within the second unit of the Penjween-Walash Subzone. The rock samples were collected from pegmatite dike which is located to the northeast of the Darishmana village, the thickness of dike is about 5 m. Electron microprobe analyses (EMPA) of plagioclase in 8 spots of dioritic pegmatites ranges between oligoclase (An18.00-An28.23) and andesine (An32.53-An33.62). Bulk whole-rock chemical analysis of fourteen samples using ICP-MS analysis reveals alkalinity Index (AI) of pegmatites to be metaluminous (A/NK > 2). Generally, the silica content in these pegmatites is from 46.70 wt. % to 52.67 wt. %. The relatively flat pattern of REEs is characterized by the slight enrichment of LREEs compared to HREEs indicating the common ancestry of the studied pegmatites. Also, the enrichment of these pegmatites in LILEs (Sr, Pb, Rb) and depletion in HFSEs especially (Nb, Ta, Y) indicate the environment of the island arcs. Moreover, the low ratios of (Rb/Sr)N and (Ba/Sr)N refer to that these pegmatites are derived from a basic origin. Tectonic discriminate diagrams show that the tectonic environment of studied pegmatites is I-type, which is the oceanic island arcs environment of sub alkaline rocks. The pegmatites of the present study have a genesis relationship with intrusions close to them in the study area; these intrusions are gabbros of Wadi Rashid that represent the environment of E-MORB. Moreover, the gabbros of Wadi Rashid and studied pegmatites are part of ophiolite-bearing terranes, they are found within upper allochthon thrust sheet. The current study of pegmatites reflects the oceanic island arcs environment, this indicates the existence of double island arcs, the first adjacent to the Arabian shelf, and the second close to the middle of paleo-ridge. Numerous evidences support that the gabbros of Wadi Rashid being as the likely parent to the studied pegmatites such as geochemistry, tectonogenesis, and the close spatial distribution of the pegmatites to the gabbros of Wadi Rashid. Moreover, the studied pegmatites appear to entail further dissection mainly due to the fact that the occurrence of dioritic- and gabbroic-pegmatites with a small-scale in the single intrusion might have its explanation in the liquid associated immiscibility.

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