The rapid rise in atmospheric CO2 necessitates strategies for mitigation and valorization. Microalgae offer potential through simultaneous CO2 capture and production of high-value biomolecules. Five Chlorophyta strains (A–E: Micractinium sp., Chlamydomonas sp., Micractinium sp., Chlorococcum sp., and Chlorella vulgaris) were isolated from temperate waters and soils and tested for growth and biochemical responses under controlled nitrogen availability (low: 0.346 g L−1 nitrate; high: 0.6 g L−1 nitrate + ammonia), carbon supply (low: 0.04% CO2; high: 4% CO2), and cultivation systems (batch reactors, fermenters, and varied illumination). Over 14 days, maximum dry biomass was achieved in batch cultivation with CO2 sparging, low nitrogen, and continuous light, ranging from 1.47 g L−1 (strain A) to 2.67 g L−1 (strain D). Biomass composition varied: proteins, 25–45%; carbohydrates, 20–35%; and lipids, 18–28%. Nitrogen limitation promoted lipid accumulation (e.g., strain D: +40%) with concurrent protein decline (−25%). Chlorophyll a/b displayed strain-specific plasticity; high CO2 generally increased chlorophyll, while nitrogen stress reduced it up to 50%. Overall, this study demonstrates that locally adapted Chlorophyta strains can achieve high biomass productivity under CO2 enrichment while allowing for flexible redirection of carbon flux toward lipids, carbohydrates, or pigments through nutrient management. Among the tested isolates, strains D and E emerged as the most promising candidates for integrated CO2 sequestration and biomass production, while strains B, C, and D showed strong potential for biodiesel feedstock; strain A for carbohydrate valorization; and strain E for chlorophyll extraction. Future research should focus on scale-up validation in pilot photobioreactors under continuous operation, optimization of two-stage cultivation strategies for lipid production, integration with industrial CO2 point sources, and strain improvement using modern genomics-assisted breeding and genome-editing technologies. These efforts will support the translation of regional microalgal resources into scalable carbon-capture and bioproduct platforms.

Ammonia (NH3) is a key precursor to secondary particulate matter in Southeast Asia, yet Thailand has lacked a country-specific, policy-focused emission inventory. This study creates the first spatially gridded (12 × 12 km) and monthly resolved national NH3 inventory for 2019, using detailed agricultural activity data, survey-based livestock management practices, and crop-specific fertilizer application profiles. Satellite-derived burned-area data were included to constrain emissions from open burning. National NH3 emissions are estimated at 459.1 kt per year, with an overall uncertainty of ±15.3%. Agriculture accounts for 95.8% of total emissions. Livestock and manure management contribute 225.3 kt per year (49.1%), reflecting high densities of poultry, cattle, and pigs, as well as regional differences in manure handling and storage practices that enhance ammonia volatilization. Fertilizer-related emissions total 192.4 kt per year (41.9%), with seasonal peaks during primary planting cycles, in contrast to the more episodic biomass-burning emissions. Comparison with the global EDGARv8.1 inventory shows significant sectoral and temporal differences, including considerably higher livestock emissions and lower fertilizer emissions in this study, due to Thailand-specific emission factors and temporal emission allocation methods. These findings clarify the spatial and temporal drivers of NH3 emissions in Thailand and offer actionable insights for targeted mitigation—notably improved manure management and optimized nitrogen use in regions where dry-season emissions coincide with severe PM2.5 episodes. The THAI-NH3 Inventory provides a strong foundation for chemical-transport modeling and evidence-based policymaking to reduce ammonia-related haze in Thailand.

Plastic pollution, particularly in marine environments, has become a major global concern; therefore, monitoring and controlling these contaminants is essential to safeguard ecosystem integrity and human health. This study evaluates the ability of Posidonia oceanica spheroids to incorporate and retain plastic debris, with a particular focus on microplastics (MPs). A total of 1300 spheroids were collected along the Latium coast (Central Italy); among these, 454 (34.9%) contained plastic debris, with an average of 3.1 items per spheroid. Overall, 1415 plastic items were extracted and identified. Based on size classification, 48.7% were microplastics, 29.6% mesoplastics, and 21.9% macroplastics. Plastic items mainly consisted of filaments (40.9 ± 12.6%) and fibers (21.5 ± 5.2%). Eleven different colors were recorded, with white (28.8 ± 9.1%), transparent (13.4 ± 6.0%), and black (11.1 ± 6.8%) being the most frequent. A strong correlation was observed between the number of plastic items contained in the spheroids and proximity to wastewater treatment plants, which are known sources of synthetic fibers. Fourier transform infrared spectroscopy (FTIR) identified a total of 15 polymer materials, with nylon (18.2 ± 11.0%) and polyethylene terephthalate (PET; 17.3 ± 7.2%) being the most abundant. Structural alterations observed in FTIR spectra, together with carbonyl index values, indicate that most MPs are of secondary origin, resulting from prolonged environmental degradation. These results demonstrate that P. oceanica spheroids effectively promote plastic trapping and highlight their potential as a simple and cost-effective monitoring tool for marine plastic pollution.

The remote monitoring and quantification of industrial gas emissions, such as sulfur dioxide (SO2), are critical for environmental protection. This research demonstrates an integrated methodology for estimating SO2 emission rates (kg/s) from an industrial chimney using passive Fourier transform infrared (FTIR) spectroscopy combined with atmospheric dispersion modeling. Infrared spectra were acquired at a stand-off distance of 570 m within the 7–14 μm spectral range at a resolution of 4 cm−1. Path-integrated SO2 concentrations were determined through cross-sectional scanning of the gas plume. To translate these optical measurements into an emission rate, the atmospheric dispersion of the plume was modeled using the Pasquill–Briggs approach, incorporating source parameters and meteorological data. Over two experimental series, the calculated average SO2 emission rates were 15 kg/s and 22 kg/s. While passive FTIR spectroscopy has long been applied to remote gas detection, this work demonstrates a consolidated framework for retrieving industrial emission rates from stand-off, line-integrated measurements under real industrial conditions. The proposed approach fills a niche between local in-stack measurements and large-scale remote sensing systems, which contributes to the development of flexible ways to monitor industrial emissions.

The sustainable management of organic residues remains a major challenge in agriculture. Vermicomposting offers an environmentally friendly strategy to convert organic waste into nutrient-rich, biologically stable biofertilizers. This exploratory study evaluated the effects of vermicompost and its leachate, produced from sewage sludge and vineyard pruning residues, on cucumber (Cucumis sativus L.) germination and 25-day early seedling growth. Treatments included a control (peat and perlite, CNT), two vermicompost doses, 20 g kg−1 and 40 g kg−1 (VC_D1 and VC_D2, respectively) and a 5% (v/v) vermicompost leachate (VC_L) applied as the sole irrigation source. Foliar nutrient contents and physicochemical properties of the substrate and leachate were determined. Germination was not significantly affected (p > 0.05), but VC_D1 promoted slightly faster and more uniform seed emergence. Growth responses were dose dependent, with VC_D1 significantly enhancing shoot biomass (approximately 15% than the CNT and VC_D2) and providing a balanced foliar nutrient profile, whereas VC_D2 significantly reduced growth, promoted excessive foliar K and P, and lower Ca, Fe, and Mn contents. VC_L enhanced foliar N accumulation but did not significantly (p > 0.05) increase biomass. Both vermicompost and its leachate were pathogen-free, with metal concentrations below regulatory limits. Overall, these findings suggest that, under the tested conditions, vermicomposting these residues can generate potentially safe amendments for cucumber seedling growth, though dose optimization is essential. This exploratory approach supports residue valorization and contributes to circular economy principles and sustainable agriculture goals.

With rapid socioeconomic development and intensified human activities, nitrogen (N) loads have continued to rise, exerting significant impacts on the environment. Most existing studies focus on single cities or short time periods, which limits their ability to capture nitrogen dynamics under rapid urbanization. Based on statistical data from multiple cities in Zhejiang Province from 2011 to 2021, this study applied nitrogen balance accounting and statistical analysis to systematically evaluate the spatiotemporal variations in nitrogen inputs, outputs, and surpluses, as well as their driving factors. The results indicate that although nitrogen inputs and outputs fluctuated over the past decade, the overall nitrogen surplus showed an increasing trend, with the nitrogen surplus per unit area rising from 49.89 kg/(ha·a) in 2011 to 62.59 kg/(ha·a) in 2021. Zhejiang’s nitrogen load was higher than the national average but remained below the levels of highly urbanized regions such as the Yangtze River Delta and Pearl River Delta. Accelerated urbanization and increasing anthropogenic pressures were identified as major contributors to the rising nitrogen surplus, with significant inter-city disparities. Cities like Hangzhou, Ningbo, Wenzhou, and Jinhua were found to face higher risks of nitrogen pollution. Redundancy analysis and Pearson correlation analysis revealed that nitrogen surplus was positively correlated with cropland area, livestock population, total population, precipitation, GDP, and industrial output, further highlighting the dominant role of human activities in nitrogen cycling. This study provides the long-term quantitative assessment of nitrogen balance under multi-city coupling at the provincial scale and identifies key influencing factors. These findings provide scientific support for integrated nitrogen management across multiple environmental compartments in Zhejiang Province, including surface water, groundwater, agricultural systems, and urban wastewater, under conditions of rapid urbanization.

Every year, crustacean shell waste amounts to nearly 8 million tons worldwide, representing both an environmental challenge and a valuable resource. Crustacean shells can be repurposed as raw material for products in various industries, including agriculture, construction, and biomedicine. They are a valuable resource for creating functional materials due to their high content of chitin, protein, and calcium carbonate. These compounds can be extracted and processed to create various products, such as the biopolymer chitosan, antioxidants like astaxanthin, and adsorbents for water treatment, aligning with a circular economy approach by converting waste into valuable by-products. Chitosan films from crustacean waste are promising active packaging materials developed over the last decade, featuring enhanced antimicrobial and antioxidant properties. Extensive research confirms that crustacean shell waste is an excellent, low-cost adsorbent for removing heavy metals from water. This review analyzes current trends and opportunities for crustacean shell waste utilization in packaging materials and wastewater treatment. Key applications include replacing conventional plastic in biodegradable packaging and improving water treatment, which enhances resource efficiency and minimizes environmental pollution.

The principal global sources of platinum-group elements (Os, Ir, Ru, Rh, Pt, Pd), collectively referred to as PGEs, are magmatic Ni-Cu sulfide deposits associated with large, layered intrusions, such as the Bushveld Complex. Recent exploration efforts have identified rock types with elevated PGE concentrations, although their potential remains uncertain. This comprehensive review synthesizes the current knowledge regarding potential sources from both natural magmatic and anthropogenic activities, as well as the environmental risks associated with the Pt, Pd, and Rh sub-group, or PPGEs. The order of Pd > Pt > Rh content in emitted particulates has been documented in dust and soil along roadsides, whereas in Fe-Ni laterite, Pt tends to accumulate residually at the top of profiles due to the higher mobility of Pd compared to Pt and Rh. The greater mobility and transfer of Pd are evidenced by higher bioaccumulation factors for Pd in plants and crops, with a higher Pd content observed in roots than in shoots. The effects of chronic occupational exposure to Pt compounds, such as allergic reactions affecting the skin and respiratory system of workers, are well-documented. Although no established permissible limits for Pt, Pd, and Rh in soil, water, or plants exist within major regulatory frameworks, the increasing applications of PPGEs and the use of Pd in catalytic converters (due to its lower cost) underscore the need for further studies on the recycling of spent catalytic converters, health impacts, ecotoxicological assessments, and the application of current technological advances to mitigate exhaust emissions.

Soil degradation and limited root-exploitable depth restrict maize productivity in Plinthosols of tropical regions. However, the combined effects of subsoiling and amendments derived from termite mound materials on soil functionality and yield remain insufficiently quantified. This study examines how variations in a functionally exploitable rooting depth, within a management system combining subsoiling and termite mound amendments, are associated with soil physicochemical properties and spatial variability of maize (Zea mays L.) grain yield in the Lubumbashi region of the Democratic Republic of the Congo. Spatial soil sampling and correlation analyses were used to identify the dominant pedological factors controlling yield variability. The results indicate a reduced vertical stratification of most nutrients within the explored depth, reflecting a more homogeneous distribution of soil properties within the managed profile, although direct causal attribution to specific practices cannot be established in the absence of untreated control plots. Improved rooting conditions were reflected by high and spatially variable productivity (2.3 to 11.1 t ha−1 across blocks), accompanied by a moderate average gain between seasons (<1 t ha−1), while extractable manganese emerged as a consistent negative predictor of yield. These patterns are consistent with a larger functionally exploitable rooting depth and an improved soil environment, although causal contributions of subsoiling and termite mound amendments cannot be isolated in the absence of control plots. Overall, the results highlight the importance of jointly considering structural and chemical soil properties when interpreting productivity gradients in Plinthosols and designing sustainable management strategies for degraded tropical soils.

Microplastics, defined as particles up to 5 mm in size, present a significant environmental and health concern due to their ubiquity, capacity to accumulate in organisms, and potential to cause toxic effects, inflammation, and endocrine disruption. A major challenge in addressing this issue is the lack of a universal method for sample preparation and analysis across different environmental matrices. This study addresses this gap by applying a custom-developed method for isolating microplastics from freshwater, followed by a comparative analysis of their abundance using three techniques: spectral (μ-FTIR) and thermal (TGA and pyro-GC-MS). The study was conducted on water samples from the Ob River near Novosibirsk, a major industrial center in Siberia. Field processing entailed filtering 20 L water volumes through a polyamide fabric with a nominal 100 µm pore size. Subsequent characterization established that the entire population of detected particles fell within the 100 to 500 µm interval. The results revealed microplastic concentrations of 0–10,000 particles/m3 (μ-FTIR), 6–19 mg/m3 (TGA), and 0.47–2.96 mg/m3 (pyro-GC-MS). Critically, the data showed spatially variable contamination, with higher microplastic levels identified near industrial wastewater discharge stations and urban recreational areas.