- New
- Research Article
- 10.3390/atoms14030023
- Mar 11, 2026
- Atoms
- Randy Kuang
Quantum Encryption in Phase Space (QEPS) is a physical-layer encryption framework that harnesses the quantum-mechanical properties of coherent states to secure optical communications against both classical and quantum computational threats. By applying randomized phase shifts, displacements, or their dynamic combinations—implemented as unitary transformations in phase space—QEPS disrupts the phase reference essential for coherent detection, establishing aphase synchronization barrier. This review synthesizes the theoretical foundations, security mechanisms, and experimental progress of the QEPS framework, encompassing its three principal variants: the round-trip Quantum Public Key Envelope (QPKE) protocol—a public-key-like scheme built upon phase randomization (QEPS-p), the symmetric phase-only QEPS-p, and the displacement-based QEPS-d. Experimental validations demonstrate that authorized users achieve bit-error rates (BERs) below the forward-error-correction threshold, whereas eavesdroppers are confined to BERs near 50%, equivalent to random guessing—all while utilizing standard coherent optical transceivers at data rates up to 200 Gb/s over 80 km of fiber. We further examine QEPS’s robustness to channel impairments, its seamless compatibility with existing digital signal processing (DSP) pipelines, and its distinctive position within the post-quantum cryptography landscape. Finally, we outline key challenges and future research directions toward deploying QEPS as a practical, quantum-resistant security layer for next-generation optical networks.
- New
- Research Article
- 10.3390/atoms14030022
- Mar 11, 2026
- Atoms
- Patrick Palmeri + 5 more
Osmium is an element of the Periodic Table with an atomic number Z equal to 76. In Tokamaks with divertors made of tungsten (Z=74), it is produced in the neutron-induced transmutation of the latter. Therefore one can expect that their sputtering may generate ionic impurities of all possible charge states in the fusion plasma. As a consequence, these could contribute to radiation losses in these controlled nuclear devices. The knowledge of radiative rates in all the spectra of osmium is thus important in this field. In this framework, a multiplatform approach has been used to determine the Os V radiative properties and estimate their accuracy. The transition probabilities have been computed for the 2677 electric dipole (E1) transitions falling in the spectral range from 400 Å to 12,000 Å. Three independent atomic structure models have been considered; one based on the fully relativistic ab initio multiconfiguration Dirac–Hartree–Fock (MCDHF) method and two based on the semi-empirical pseudo-relativistic Hartree–Fock (HFR) method.
- New
- Research Article
- 10.3390/atoms14030020
- Mar 9, 2026
- Atoms
- Gediminas Gaigalas
This paper presents a methodology that allows for calculated energy levels and other atomic characteristics in relativistic atomic theory, i.e., using the jj-coupling scheme, to be identified in terms of LSJ-coupling characteristics. The paper begins with outlining the general principles for effectively addressing this problem. Furthermore, it provides a general expression that enables such identification when the atomic state function consists of any number of configuration state functions, each with any number of open shells, and explains how this expression was obtained. The methodology developed in this paper has been successfully implemented in the General Relativistic Atomic Structure Package and can be applied to other similar packages.
- New
- Research Article
- 10.3390/atoms14030021
- Mar 9, 2026
- Atoms
- Gediminas Gaigalas
In this study, an extension of the general method [G. Gaigalas, Z. Rudzikas, C. Froese Fischer, J. Phys. B, At. Mol. Phys. (1997). DOI: 10.1088/0953-4075/30/17/006] is described for finding algebraic expressions of the spin-angular parts of the reduced matrix elements of any one- and two-particle operator for an arbitrary number of shells in an atomic configuration. This extension is related, at first, to a change in the definition of tensor structure, where a non-scalar space with respect to l and s for any two-particle operator acts on four different shells. This leads to more efficient expressions for recoupling matrices and amplitudes, which are presented in the paper. In addition, the paper presents new expressions for some of the recoupling matrices, in which 6j- and 9j-coefficients are summed up algebraically. All this leads to a significantly simpler and faster calculation of the spin-angular parts of any non-scalar two-particle operator.
- New
- Research Article
- 10.3390/atoms14030019
- Mar 8, 2026
- Atoms
- Yuchen Wang
The accurate description of nonadiabatic quantum molecular dynamics represents one of the most significant challenges in modern computational chemistry, serving as a gateway to understanding complex phenomena ranging from photochemistry and electron transfer to surface scattering and biological exciton transport. A key difficulty lies in bridging high-level electronic structure theory for ground and excited states with accurate quantum dynamics theory. Although on-the-fly semiclassical approaches are increasingly viable, most quantum dynamics simulations still rely on pre-constructed potential energy surfaces, or in the nonadiabatic context, diabatic potential energy matrices (DPEMs). This perspective paper addresses the theoretical foundations, construction methodologies, and emerging frontiers of DPEMs. We examine the mathematical framework of the adiabatic-to-diabatic transformation, addressing the inherent topological challenges imposed by the geometric phase and the curl condition. We further analyze the transformative impact of machine learning, detailing how machine learning algorithms, such as permutation invariant polynomial neural networks and deep learning architectures, are reshaping the construction of global, high-dimensional DPEMs. Finally, we explore the disruptive potential of quantum computing, discussing how quantum algorithms are automating the direct simulation of nonadiabatic dynamics. In emerging quantum-centric workflows, DPEMs will continue to provide the critical bridge which enables the mapping of realistic, time-dependent molecular Hamiltonians onto quantum hardware.
- Research Article
- 10.3390/atoms14020013
- Feb 13, 2026
- Atoms
- Houke Huang + 9 more
Dielectronic recombination (DR) is widely recognized as a fundamental atomic process in many astrophysical and laboratory plasmas, where it plays a crucial role in determining ionization balance and level populations over a broad temperature range. Reliable DR resonance strengths and plasma rate coefficients for such plasma modeling can be computed using the Jena Atomic Calculator (JAC)—a relativistic code based on the multiconfiguration Dirac–Hartree–Fock (MCDHF) method. In this work, we investigate the DR of Li-like Ar15+ ions in their ground state (2s), focusing on resonances associated with the fine-structure core excitations 2s1/2→2p1/2,3/2. The resulting fine-structure-resolved DR resonance strengths and plasma rate coefficients are in good agreement with recent high-resolution DR measurements of Ar15+ ions performed at the Main Cooler Storage Ring (CSRm) in Lanzhou, China. These results provide a stringent benchmark for JAC calculations and support their applicability in plasma modeling.
- Research Article
- 10.3390/atoms14020012
- Feb 6, 2026
- Atoms
- Paul R Berman
The radiation pattern emitted by two atoms, interacting with each other via the vacuum radiation field, has been calculated, including effects of magnetic state degeneracy for atoms with a ground state having G=0 angular momentum and an excited state having H=1 angular momentum. For an initial condition in which both atoms are inverted, the time-integrated radiation pattern is identical to that for non-interacting atoms if the atoms lie on the z-axis, but differs if the atoms lie on the x-axis. The underlying dynamics giving rise to this behavior are examined.
- Research Article
- 10.3390/atoms14020011
- Feb 5, 2026
- Atoms
- Miguel E Gómez Quintanar + 1 more
We study the planar repulsive two-center Coulomb system in the presence of a uniform magnetic field perpendicular to the plane, taking the inter-center separation a and the magnetic field strength B as independent control parameters. The free-field system B=0 is Liouville integrable and the motion is unbounded. The magnetic confinement introduces nonlinear coupling that breaks integrability and gives rise to chaotic bounded dynamics. Using Poincaré sections and maximal Lyapunov exponents, we characterize the transition from regular motion at aB=0 to mixed regular–chaotic dynamics for aB≠0. To probe the recoverability of the dynamics, we apply sparse regression techniques to numerical trajectories and assess their ability to capture the equations of motion across mixed dynamical regimes. Our results clarify how magnetic confinement competes with two-center repulsive interactions in governing the emergence of chaos and delineate fundamental limitations of data-driven model discovery in nonintegrable Hamiltonian systems. We further identify an organizing mechanism whereby the repulsive two-center system exhibits locally one-center-like dynamics in the absence of any static confining barrier.
- Research Article
- 10.3390/atoms14020009
- Jan 31, 2026
- Atoms
- Bratislav P Marinković + 2 more
In this work, the He and Ar triplet autoionizing states have been studied using a non-monochromatic electron beam and a high-resolution electrostatic analyzer at low incident electron energies and three ejection angles: 40°, 90°, and 130°. Low-energy electrons have been used because they have a high probability of exciting triplet states regardless of whether they are discrete isolate states or are embedded in the ionization continuum. Additionally, the He ejected electron spectra have been measured at several ejection angles between 20° and 130° and two incident energies, namely 60.5 eV and 101 eV. The anisotropic angular distributions indicate that orbital angular momentum exchange between the ejected and scattered electrons occurred. The energies of the first triplets 3s3p64s(3S) and 3s3p64p(3P) states of argon are found to be (24.985 ± 0.020) eV and (26.52 ± 0.02) eV, respectively.
- Research Article
- 10.3390/atoms14010006
- Jan 20, 2026
- Atoms
- Linkai Li + 7 more
Inspired by the well-known experimental connections between X(3872), Zcs(4220), and Y(4620), we systematically study the recently reported strange partner of Tcc, the 1+ccq¯s¯ system, and its orbital excitation state 1−ccq¯s¯. A chiral quark model incorporating SU(3) symmetry is considered to study these two systems. To better investigate their spatial structure, we introduce a precise few-body calculation method, the Gaussian Expansion Method (GEM). In our calculations, we include all possible physical channels, including molecular states and diquark structures, and consider channel coupling effects. To identify the stable structures in the system (bound states and resonance states) we employ a powerful resonance search method, the Real-Scaling Method (RSM). According to our results, in the 1+ccq¯s¯ system, we obtain two bound states with energies of 3890 MeV and 3940 MeV, as well as two resonance states with energies of 3975 MeV and 4090 MeV. The decay channels of these two resonance states are DDs∗ and D∗Ds, respectively. In the 1−ccq¯s¯ system, we obtain only one resonance state, with an energy of 4570 MeV, and two main decay channels: DDs1∗ and D∗Ds1′. We strongly suggest that experimental groups use our predictions to search for these stable structures.