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Applications of bio-composites in electronics

Abstract Functional biomaterials are being used in many promising industries to improve human quality of life and advance environmental objectives. Consideration has been given to many applications in the domains of medical, electronics, food, and pharmaceuticals. The use of bio-inspired materials enables the creation of more sustainable alternatives that strive to advance environmental preservation while simultaneously ensuring customer satisfaction. It was discovered that biopolymers are used in a number of different industries for the production of a wide range of functional bio-products. These bio-products include organic thin film transistors, organic phototransistors, emitting diodes, photodiodes, photovoltaic solar cells, hybrid dental resins, sustainable medicines, and consumer food packaging. A growth of this magnitude makes it possible to conduct substantial research in order to more inspection of the limitless requests and uses of bio-based composites. In order to fulfill the needs of certain applications, it is necessary to adjust and reassess attributes and parameters– such as hardness, durability, crack toughness, binding, solubility, polarization, plasticity, hydrogen bonding, thermal characteristics, and dielectric behavior. By virtue of their electronic and electrical properties, bio-composites and biopolymers have been put to use in a variety of applications; some includes organic thin-film transistors, electrical applications, electromagnetic insulation, energy harvesting, and thermoelectric processes. Substantial proportions of electronic waste, also referred to as E-waste, are regularly released into the environment due to the continuous growth in the production of electronic devices. Consequently, this leads to substantial environmental and ecological problems caused by the release of non-degradable polymers, hazardous compounds, and toxic heavy metals into the environment. The advancement of biodegradable polymers has significant potential for effectively reducing the environmental burden, since they may be decomposed or absorbed into the surrounding environment without generating any toxic effects. Hence, the purpose of this study is to illustrate the creation of biocompatible composites and their prospective uses in electrical applications.

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ZIF-67 derived N doped carbon embedded Co<sub>x</sub>P for superior hydrogen evolution

Abstract Developing a sustainable non-noble hybrid electrocatalyst for effective electrocatalysis is the most crucial task; particularly in sustainable hydrogen energy production in the realm of energy conversion. In this work, effective thermal pyrolysis process followed by phosphorization strategy was employed to prepare and fabricate ZIF-67 (Zeolitic imidazole) assisted Co2P/N doped carbon electrocatalyst for hydrogen evolution reaction (HER). The optimized Co2P/N–C electrocatalyst exhibited hollow porous nanostructures as confirmed from the scanning electron microscopy. The achieved porous nanostructure improved the efficiency of the charge and mass transportation which is confirmed by the BET analysis, has high surface area value of 94.731 m2/g. In addition, a transition metal atom can regulate reactants adsorption and desorption capacity by modulating Co and P electronic configuration. The electrochemical studies of fabricated ZIF-67 derived Co2P/N–C electrode were analyzed using 1.0 M alkaline potassium hydroxide (KOH) medium in 3 electrode system process. Whilst, optimizing the pyrolysis temperature during the phosphorization will remarkably enhance the favourable characteristics of the hydrogen generation. Notably, the optimized ZIF-67 derived Co2P/NC at 350 °C electrode exhibited low overpotential (135 mV) at minimum 10 mA/cm2 and low 120.3 mV/dec Tafel slope. Besides, electrode stability at 10 mA/cm2 current density was verified by chronoamperometry test. Hence, this study furnishes the potential technique for the development of advanced hybrid MOF electrocatalyst as a successful alternative on large scale.

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Assessing the role of circular economy and green innovation in mitigating carbon emissions in the Visegrad countries

The shift towards a circular economy is an essential measure in achieving sustainable development because it seeks to separate economic expansion from resource use and environmental deterioration. To meet the European Union green deal, waste management, and the net zero emissions targets various countries are developing and adopting prudent strategies. This study investigates the dynamic affiliation between circular economy (CIR), green innovation (INV), renewable energy (REE), economic progress (GDP), and urbanisation (URB) on carbon emissions (CO2) in the Visegrad (V4) countries, comprising the Czech Republic, Hungary, Poland, and Slovakia. Using the CS-ARDL technique and quantile regression, data curation from 1990-2022 was analysed after checking for cross-sectional, unit root, and cointegration. The outcome demonstrates that circular economy, green innovation, and renewable energy had a negative effect on carbon emissions. In addition, GDP and URB had an immaterially positive influence on carbon emissions. Lastly, the quantile regression confirmed that the study provides useful information for policymakers and stakeholders in the Visegrad countries. It emphasised how important it is to take a broad approach to circular economy initiatives, support eco-friendly innovations, carry out renewable energy projects, and manage the urbanisation process well to achieve long-term economic growth and environmental health.

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On the Effect of Current Stabilizer on Dynamics of a Small Hybrid Wind Power Generator

The use of small wind power generators remains quite relevant. In particular, they can be efficient for charging batteries in remote locations where there is no centralized power supply (including in the Arctic, Far East, etc.). They can also be used as part of missions to planets with atmospheres. One of the promising design solutions for a small wind power generator with a vertical axis of rotation is a hybrid device. It consists of two wind turbines that have a common axis of rotation: external (Darrieus wind turbine) and internal (Savonius rotor). This scheme represents a compromise between the relatively high power coefficient of the Darrieus turbine and the good startup characteristics the Savonius rotor. It is known that one of the typical battery charging modes is constant current charging. Here we consider a hybrid installation, the generator of which is connected to a current stabilizer. The load is simulated with an active resistance. It is assumed that the generator is a DC generator. A closed mathematical model of the studied system is constructed. The aerodynamic load is described using the quasi-steady approach. It is assumed that the characteristic time of electrical processes is much smaller than the characteristic time of mechanical processes. The influence of load resistance on the behavior of the system is investigated. It is shown that, under certain conditions, several steady modes (up to five) exist in the system. In this case, at least two of them are attracting. Therefore, the hysteresis of the angular speed of the steady mode is possible when the load resistance changes. It should be noted that in a number of situations, an unstable steady mode (which corresponds to a lower angular speed of the turbine than a stable one) may be preferable (for example, to reduce the load on bearings). In this regard, a resistance control strategy has been proposed to ensure stabilization of the unstable stationary regime.

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