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3D printing of continuous cellulose fibre composites: microstructural and mechanical characterisation

PurposeAdditive manufacturing is a recent technology used in the production of composite materials. The use of continuous fibres as reinforcement is necessary to achieve high mechanical performance. However, making these materials more environmentally friendly is still challenging. The purpose of this study was to investigate the feasibility of 3D printing a composite made of continuous regenerated cellulose fibres using a standard 3D printer generally used for printing polymers.Design/methodology/approachThe production process was based on a pre-impregnated filament made from a tape containing continuous cellulose fibres and Pebax® matrix. 3D printed composite samples were fabricated using fused deposition modelling. The tape, filament and 3D printed composites were first analysed by means of modulated differential scanning calorimetry and micrography. Tensile tests were then performed, and the mechanical characteristics were determined at each step of the production process. Fracture surfaces were investigated by field-emission gun–scanning electron microscopy.FindingsResults showed that the mechanical behaviour of the material was maintained throughout the production process, and the 3D printed biocomposites had a stiffness equivalent to that of traditionally manufactured continuous cellulose fibre composites. The obtained 3D printed composites showed an increase in strength value by a factor of 4 and in tensile modulus by a factor of 20 compared to those of unreinforced Pebax® polymer.Originality/valueThis paper demonstrates the feasibility of 3D printing composites based on continuous cellulose fibres, paving the way for new biocomposites made by additive manufacturing.

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Experimental and Numerical Study of the Effect of the Presence of a Geometric Discontinuity of Variable Shape on the Tensile Strength of an Epoxy Polymer

Abstract The presence of geometric discontinuity in a material reduces considerably its resistance to mechanical stresses, therefore reducing the service life of materials. The analysis of structural behaviour in the presence of geometric discontinuities is important to ensure the proper use, especially if it is regarding a material of weak mechanical properties such as a polymer. The objective of the present work is to analyse the effect of the notch presence of variable geometric shapes on the tensile strength of epoxy-type polymer specimens. A series of tensile tests were carried out on standardised specimens, taking into account the presence or absence of a notch. Each series of tests contains five specimens. Two notch shapes were considered: circular (hole) and elliptical. The experimental results in terms of stress–strain clearly show that the presence of notches reduces considerably the resistance of the material, where the maximum stress for the undamaged specimen was 41.22 MPa and the lowest stress for the elliptical-notched specimen was 11.21 MPa. A numerical analysis by the extended finite element method (XFEM) was undertaken on the same geometric models; in addition, the results in stress–strain form were validated with the experimental results. A remarkable improvement was obtained (generally an error within 0.06%) for strain, maximum stress, Young’s modulus and elongation values. An exponential decrease was noted in the stress, strain, and Young’s modulus in the presence of a notch in the material.

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X-Ray Crystallography, Spectral Analysis, DFT Studies, and Molecular Docking of (C9H15N3)[CdCl4] Hybrid Material against Methicillin-Resistant Staphylococcus aureus (MRSA)

The one dimensional polymer complex (C9H15N3)[CdCl4], was synthesized and characterized by X-ray crystallography, FT-IR vibrational, and thermal analysis, UV–Visible and photoluminescence (PL) spectroscopic investigations. The crystal structure crystallizes in the monoclinic space group C2/c with Z = 4. The experimental geometric data of the crystalline molecule and the results of density functional theory (DFT) generated utilizing computational methods at DFT/ωB97XD and DFT/B3LYP-D3/Gen/6-311++G(d, p)//LanL2DZ levels of theory were compared. Significantly, in order to reveal the vibrational modes of the named chemical, the Infrared and Raman spectra were registered. Then, 13C and 113Cd solid-state NMR was employed to characterize this hybrid material using a polar solvent to conduct an investigation of the optical characteristics for the UV–visible range. Consequently, utilizing the highest occupied molecular orbital and the lowest unoccupied molecular orbital (HOMO–LUMO) calculations, the molecule’s energy gap (Eg) was determined. More so, the PL tests revealed two peaks at about 400 and 423 nm while the Hirshfeld surface (HS) analysis and DFT calculations were also carried out to acquire insight into the role of weak molecular interactions in the complex that affect the self-assembly process and crystal packing. In addition, molecular docking experiments with the 6U3Y, 1SAX, and 2D45 receptors reveal ideal postures with intriguing binding affinities of −5.2, −5.6, and −5.7 kcal.mol−1, respectively. Lastly, thermo-differential analysis techniques (DTA) and thermogravimetric analysis techniques (TGA) were used to account for the thermal degradation of the current complex.

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