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Comparison of volatiles evolving from selected highland and mare lunar regolith simulants during vacuum sintering

Volatiles evolving from JSC-1A, NU-LHT-4M and CSM-LHT-1G lunar regolith simulants during in vacuo thermal processing were analyzed using mass spectrometry as a function of temperature. Two high-fidelity simulants, JSC-1A (mare) and NU-LHT-4M (highland), were compared to a newly developed CSM-LHT-1G highland simulant, modified to closely match lunar geochemistry. Large autogenous gas loads were observed for all investigated materials. Mineralogical knowledge was used to identify and attribute individual volatile species to reacting, transforming, or decomposing constituents (hydrates, carbonates, sulfates, sulfides, clays, etc.) of the respective regolith simulant in the self-generated gas environment. Cumulative mass losses for individual simulant components as a function of temperature were quantified using mass spectrometry in conjunction with thermogravimetric analysis. Investigation of the four components of CSM-LHT-1G – anorthosite, basalt, augite, and glass – aided the attribution of volatile species to specific compounds and their respective sources. The results showed significant decomposition of non-lunar phases present in the man-made regolith simulants below the typical glass crystallization temperatures, which paves the way to devising methods for enhancing the fidelity of the simulants. High gas loads and corrosive gases (HF and HCl) were recognized as potential hazards, pertaining to the development of large testbed facilities.

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The thermal impact of the self-heating effect on airless bodies. The case of Mercury’s north polar craters

Thermal models are essential for studying airless planetary surfaces, as the interaction between topography and thermophysical properties plays a crucial role in determining a surface’s response to localized illumination. Accurate temperature distribution calculations require a comprehensive investigation of sunlight scattering, a process that, despite its computational challenges, cannot be overlooked, especially when high resolution is necessary. Furthermore, thermal analysis is fundamental for assessing the stability of volatiles in polar regions. In this study, we introduce a novel approach by discretizing the Sun into 100 individual elements, allowing for a highly precise simulation of solar flux—an innovation crucial for accurately capturing temperature distributions in Mercury’s polar craters, given the planet’s proximity to the Sun. This level of discretization significantly enhances the accuracy of the thermal model, ensuring a more realistic depiction of how sunlight interacts with crater topography. We developed a dual-model approach that simulates both direct solar illumination and its scattering on two craters, Laxness and Fuller, located at Mercury’s north pole. The illumination and thermal model predict temperature distribution and heat transfer based on the material’s thermal properties and topography. The study examines the interaction between direct sunlight, causing localized heating, and scattered light, which influences the thermal response of surface materials. Detailed illumination maps and temperature profiles were generated over two Hermean years, revealing the significant impact of the self-heating effect on temperature distribution. The results show that specific regions experience indirect solar flux due to the craters’ morphology, particularly in permanently shadowed regions (PSRs) that are heated exclusively by scattered radiation. Maximum temperature profiles for the Laxness and Fuller craters show a substantial temperature increase within PSRs compared to areas exposed to direct illumination. However, while self-heating does not affect the stability of water ice in the Laxness crater, in the Fuller crater, a section within the radar-bright material reaches temperatures of up to 210 K, potentially threatening the stability of water ice. Further investigation with the onboard SIMBIO-SYS instrument on the BepiColombo mission will help to better understand the current state of these craters and their volatile deposits.

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