Concrete Zone Research Articles

Effect of cellulose nanofiber addition on the microstructure characterization and nano-mechanical behavior of interfacial transition zones in recycled concrete

Effect of cellulose nanofiber addition on the microstructure characterization and nano-mechanical behavior of interfacial transition zones in recycled concrete

Impact of PVA-coated aggregate on concrete impermeability and creep characteristics under hydraulic pressure and development of a creep model

In marine engineering projects such as sea dikes, concrete must exhibit both exceptional impermeability and plastic deformation to prevent cracking and subsequent internal corrosion due to synergistic deformation with the foundation. This study enhances the interface transition zone (ITZ) and plastic deformation of concrete by applying a PVA film to the aggregate surface. We use nuclear magnetic resonance to investigate the internal pore distribution and conduct permeability tests to assess its impermeability. Utilizing a self-developed triaxial hydraulic creep apparatus, we tests the concrete's creep performance under hydraulic pressure. Compared with conventional waterproof concrete, the findings reveal that the PVA film on the aggregate surface significantly increases the water penetration pressure of the concrete and markedly enhances the momentary deformation and creep deformation under hydraulic pressure, significantly extending the time to creep. Furthermore, the study proposes a creep model incorporating a fractional derivative-based dashpot model, combined with the Burgers model. This research offers a novel approach and theoretical support for developing impermeable and plastic concrete suitable for marine engineering applications.

Assessment of the Influence of Features of Crack Formation in Reinforced Concrete Products on their Fire Resistance

The paper considers possible scenarios of cracking during heating and their impact on fire resistance using the example of a bending reinforced concrete structure (beam). It is shown that if the calculated critical temperature of reinforcement is less than the critical temperature of concrete (this indicates a significant load on the structure), then cracks in the tensile zone of concrete are formed after reaching the second stage of the stress-strain state. The concrete of the protective layer does not have time to degrade, the depth of the crack remains constant, and the fire resistance limit is calculated taking into account that the thickness of the protective layer of concrete is reduced by the depth of the crack opening. If the calculated critical temperature of the reinforcement is greater than the critical temperature of the concrete (this indicates a slight load on the structure), then cracks are formed as a result of the degradation of the surface layer of concrete. Their depth should constantly increase with the progression of the concrete layer heating to the critical temperature. In this case, the calculation of the fire resistance limit can be performed without taking into account the formation of cracks. Based on the considered assumptions, a methodology for assessing the impact of cracks on the fire resistance limit of bending reinforced concrete structures is proposed, which consists in analyzing the possibility of open cracks (which is facilitated by heating) and estimating their depth. At the next stage, the heating time of the concrete layer to the crack opening depth τΔ1 and the temperature in the crack after this time are estimated. Next, the time until the critical temperature of the reinforcement τΔ2 is estimated when the concrete layer is heated from the bottom of the crack to the reinforcement. The fire resistance limit is defined as the sum of τΔ1 and τΔ2. The results of the calculations according to the proposed methodology showed that the presence of open cracks in bending reinforced concrete structures can almost halve the fire resistance limit.

Interface Transition Zone in Coal Gangue Aggregate Concrete Reinforced by Phosphorus Slag: Macroscopic Properties and Microstructure

Interface Transition Zone in Coal Gangue Aggregate Concrete Reinforced by Phosphorus Slag: Macroscopic Properties and Microstructure

Resistance of compressed elements with small eccentricity taking into account actual height of the compressed concrete zone

Resistance of compressed elements with small eccentricity taking into account actual height of the compressed concrete zone

Numerical and experimental analysis of the effect of multi-ion electrical coupling on the sulfate convection zone in hydraulic concrete

This study centers on investigating the effects of multi-ion electrical coupling on sulfate profiles in the convection zone of hydraulic concrete under drying-wetting cycles. Considering the moisture ingress triggered by capillary negative pressure and electrical potential gradients generated due to the varying speeds of the charged solutes, a coupled numerical model framework for moisture and multi-component ions transport is established. The influence of drying and rewetting conditioning regimes, electrochemical coupling between multi-species ions, sulfate adsorption-binding mechanism, fly ash replacement and porosity of concrete on moisture and multi-ion transport behavior is numerically analyzed. Our findings reveal that more than 60 % of the sulfate ions that penetrate the concrete matrix engage in chemical reactions. After 30 cycles, the sulfate ion content differs by approximately 21 % depending on the presence of the electrical coupling effect. Moreover, the electrostatic potential in the pore solution fluctuates sharply in the ion-rich area near the concrete surface, interacting with ion distribution in the convection zone. The knowledge gleaned from this investigation offers a robust framework for the design of concrete structures that need to withstand challenging aqueous environmental conditions marked by multi-component ions and cyclic drying-wetting processes.

Oil-based drilling cutting pyrolysis residues-recycled fine powder sintered ceramsite: Basic properties, microsintering mechanism, lightweight concrete application and heavy metals solidification

Oil-based Drilling Cutting Pyrolysis Residue (ODPR) is a waste produced during oilfield drilling using oil-based mud. Recycled Fine Powder (RFP) consists of particles less than 0.16 mm, crushed and sieved from waste concrete. China's solid waste is characterized by high production, low utilization rates, and high pollution levels. This study explores the feasibility of preparing ceramsite from ODPR and RFP. By examining the effects of varying temperatures and proportions on the macroscopic and microscopic properties of ODPR-RFP ceramsite (ORC), the optimal process was determined: ODPR: RFP = 7:3, 2 % borax flux, 10 minutes ball milling, 1200℃ sintering temperature, and 30 minutes insulation. The resulting ORC, with a bulk density of 1120 kg/m³, cylinder compression strength of 10.50 MPa, and water absorption rate of 7.8 %, meets the "Lightweight aggregates and its test methods (GT/B17431.2)" standard. Batch production of ORC products of various sizes was conducted to evaluate their practical application in LC30 lightweight aggregate concrete. Replacing the aggregate in lightweight concrete with ORC yielded a concrete with excellent mixing performance, reaching a maximum strength of 31.2 MPa after 7d and 44.8 MPa after 28d. The damage pattern of ORC lightweight concrete is characterized by longitudinal splitting, with varied crack initiation and expansion paths. In the interfacial transition zone of ORC concrete, the ORC form a strong bond with the cement mortar, enhancing the strength of the lightweight concrete. Additionally, the leaching of heavy metals (HMs) from the ORC was examined to assess potential environmental pollution. The results indicated that preparing ORC from these two types of solid waste can effectively immobilize HMs, with a solidification rate of up to 92.10 %. Pb with high content is mainly solidified in the form of solid solution to form (Ba, Pb) SO4. The ecological risk assessment method for HMs shows that using this solid waste and process to prepare ORC does not pose HMs risks and is an environmentally friendly building material.

Suppressing of alkaline aggregate reaction (AAR) through waterproofing of concrete surface, aggregates, and mortars

Water is necessary for the alkali aggregate reaction to occur and this study investigates the impact of waterproofing on alkali-aggregate reaction (AAR) in concrete by separating water from alkali reactive aggregates through surface, aggregate, and matrix treatments. Accelerated mortar bar tests (AMBT) are conducted to analyze the expansion caused by alkali aggregates. Furthermore, the suppressive mechanism of waterproofing on AAR is explored using scanning electron microscopy (SEM), while the influence of waterproof concrete aggregate and matrix on pore characteristics and hydration products is assessed using nuclear magnetic resonance (NMR) and X-ray diffraction (XRD). The results demonstrate that surface waterproofing with silane and polyvinyl alcohol (PVA) effectively suppress AAR. Moreover, PVA-coated aggregates significantly enhance the compactness of the interfacial transition zone (ITZ) in concrete. Based on these findings, an improved model considering waterproofness is proposed to quantify the degree of alkali aggregate reaction. These findings offer valuable guidance for controlling AAR.

Physical characteristics identification of the concrete interfacial transition zone via 3D image scanning

The interfacial transition zone (ITZ) is the weakest link in concrete materials. The physical characteristics of the ITZ, such as its microhardness and thickness, significantly influence the mechanical properties and durability of concrete. Typically, microhardness testing is employed to identify the physical features of the ITZ through line measurements with a certain degree of randomness. In order to accurately describe ITZ physical characteristics, this study proposes a novel physical characteristics identification method via three-dimensional (3D) image scanning. The fundamental principle of this method lies in the varying hardness of each concrete phase, resulting in different surface elevations after polishing. As the polishing abrasiveness changes from coarse (240 mesh) to fine (800 mesh), the ITZ can be clearly observed in the 3D point cloud images of the experimental concrete. The ITZ geometrical information (thickness and different surface heights) can be easily identified using 3D scanned images. It was also found that there was a considerable linear regression relationship between the height difference and the relative microhardness variation; thus, the ITZ microhardness could be indirectly recognized through surface measurements. The physical characteristics of ITZ can be statistically analysed, effectively mitigating the bias inherent in traditional test results and significantly improving identification efficiency and accuracy.

Micromechanical and chemical characteristics of interfacial transition zone in alkali-activated slag concrete containing lightweight iron-rich aggregates

This study explored the time-varying alkali-activation effects of the lightweight aggregates (LWA) on the interfacial transition zone (ITZ) of the alkali-activated slag concrete with different curing ages, molar ratios, and alkali concentrations from 28 to 300 d. The improved micromechanical performance of the ITZ at 28 d stemmed from the early-age internal curing effect of the porous LWA. However, the post-28 d internal curing effect diminished, with the alkali-activation dominating the performance of the ITZ from 28 to 300 d. Although alkali-activated cement possessed early strength characteristics, the deconvolved phase results illustrated that alkali activation persisted in the ITZ between the LWA and cement from 28 to 300 d, leading to a high proportion of calcium silica aluminate hydrate. As a marker, Fe from the lightweight iron-rich aggregates mitigated into the alkali-activated cement, demonstrating the alkali-activated reaction between the LWA and alkali-activated slag matrix. Molecular dynamics simulations further characterized that the low content of Fe did not decrease the overall strength of the ITZ. The interfacial interaction energy revealed the alkali-activation between the LWA and cement compensated for the weakening of mechanical properties caused by Fe ions on the ITZ.

Investigating the Influence of Oil Shale Ash and Basalt Composite Fibres on the Interfacial Transition Zone in Concrete

Investigating the Influence of Oil Shale Ash and Basalt Composite Fibres on the Interfacial Transition Zone in Concrete

Unraveling concrete's interfacial transition zone vulnerability under erosive environments: A molecular dynamics study

The Interfacial Transition Zone (ITZ) in concrete is considered to be the weakest region of the mechanical properties of concrete, owing to the prevalence of microcracks induced by various external factors. These microcracks facilitate the ingress of corrosive solution into the ITZ through pores or crevices, ultimately impacting its mechanical integrity. This study aims to investigate the effects of different erosive environments on the mechanical properties of concrete ITZ and to analyze the intrinsic weakening mechanism via molecular dynamics simulations. The effects of different water contents and different ionic solutions are individually discussed in this study. Simulation results demonstrate a distinct trend in the mechanical properties of ITZ, exhibiting an initial increase followed by a decrease with the rise of water content under various conditions. Moreover, the magnitude of the mechanical properties of ITZ exhibits a hierarchy under different ionic solution conditions, ranked as follows: dry >10 wt% Na2SO4+NaCl >5 wt% Na2SO4 > 5 wt% NaCl >5 wt% Na2SO4+NaCl > H2O. The mechanical properties of ITZ are significantly influenced by its internal chemical bonds, which are susceptible to erosion from the infiltrating solution, resulting in the rupture of original chemical bonds and consequent reduction in ITZ's mechanical strength.

Nano-modified recycled aggregates via vacuum impregnation: Towards stronger and durable recycled concrete

For the first time, this study aimed to enhance the quality of recycled aggregates (RAs) by employing nano-silica (NS) and the vacuum impregnation technique. Specifically, RAs experienced water immersion, ordinary and vacuum impregnation with 2 % NS slurry, and vacuum impregnation with 4 % NS slurry. Subsequently, these nano-modified RAs were incorporated into concrete mixes, and their strength and durability were assessed. Following this, an examination of the pore structures and properties of the interfacial transitional zones (ITZs) in recycled concrete was conducted. The results demonstrate that in contrast to ordinary pretreatment methods, concrete containing nano-modified recycled aggregates after vacuum impregnation exhibits better compressive strength (+18.39 %) and reduced chloride ion penetration (−17.90 %), which is attributable to a more compact pore structure and enhanced ITZs. The findings prove that vacuum impregnation significantly enhances the modification impact of NS on RAs when compared to conventional impregnation methods, owing to the reduced agglomeration effect of NS in concrete.

Progressive Collapse Behavior of a Precast Reinforced Concrete Frame System with Layered Beams

A possible way to improve the structural safety and robustness of precast building structures is to develop effective precast frame systems with layered beams, which combine prefabricated parts with cast-in situ ordinary concrete, high-performance concrete, fiber concrete, or FRP. The paper provides a new type of precast reinforced concrete frame system with layered beams for rapidly erected multi-story buildings resistant to accidental actions. Using a combination of the variational method and two-level design schemes, a simplified analytical model has been developed for structural analysis of the precast reinforced concrete frame system, both for serviceable and ultimate limit states as well as for accidental actions. The proposed model allows for determining shear deformations and the formation and opening of longitudinal cracks in the intermediate contact zone between precast and monolithic parts of reinforced concrete structural elements of the frame, as well as the formation and opening of normal cracks because of the action of axial tensile force or bending moment in these elements. The design model was validated by comparing the calculated and experimental data obtained from testing scaled models of the precast reinforced concrete frame system with layered beams. The paper investigates and thoroughly analyzes the factors affecting the stiffness and bearing capacity of the intermediate contact zone, discusses the criteria for the formation of shear cracks along the contact zone of precast and monolithic concrete, and examines the change in the stiffness and dissipative properties of layered elements at different stages of their static–dynamic loading. The robustness of the experimental models of the structural system was not ensured under the specified load, section dimensions, and reinforcement scheme. Following an accidental action, longitudinal cracks were observed in the contact joint between the monolithic and prefabricated parts in the layered beams. This occurred almost simultaneously with the opening of normal cracks in adjacent sections. A comprehensive analysis of the results indicated a satisfactory degree of agreement between the proposed semi-analytical model and the test data.

Implementation of bio-inspired organic/inorganic layer structures as interphase in carbon fiber reinforced concrete

Biological materials found in nacre or glass sponges reveal specific layered organic and inorganic structures known for their fracture toughness caused by crack deflection and bridging. This work aims to bio-mimic the brick-and-mortar (BnM) structure from nacre and the layer-by-layer (LbL) structure from the glass sponge filaments to incorporate these effects into the contact zone of carbon fiber-reinforced concrete (CFRC) in order to prevent brittle composite failure. To build up BnM- and LbL-structure materials such as nanoclays, sodium water glass, and polymer dispersions were selected since they are well-established low-cost materials in building. Nanoclays were analyzed regarding their size, dispersibility and exfoliation. Montmorillonite (MMT) was used to be mixed with polymers to produce self-assembled BnM-structured films and coatings. Also, LbL-structures were formed by alternating layers of sodium water glass and polymer. Scanning electron microscopy and energy-dispersive X-ray spectroscopy were used to verify the morphology. The MMT-containing coatings demonstrated enhanced nucleation potential when exposed to cementitious eluate. Micromechanical pull-out tests on single carbon fibers with BnM- and LbL-coatings embedded in concrete demonstrate the potential to increase composite toughness. The successful implementation of the bio-inspired structures using affordable materials lays the groundwork for their scalability and integration into composite structures for building.

The Influence of Slag Content on the Structure and Properties of the Interfacial Transition Zone of Ceramisite Lightweight Aggregate Concrete.

Ceramisite lightweight concrete has excellent performance and relatively light self-weight characteristics. At the same time, the recent development of green high-performance concrete and prefabricated components has also brought the abundant utilization of these mineral mixture. An interfacial transition zone exists between the hardened cement paste and the aggregate, which is the weakest part of the concrete, characterized by high porosity and low strength. In order to study the effect of slag content on the interfacial transition zone in lightweight high-strength concrete, experiments were designed to replace cement with slag at different contents (0%, 5%, 10%, 15%). A series of studies was conducted on its macro-strength, microstructure, and composition. The results indicated that the addition of slag improved the porosity and width of the interfacial transition zone. Adding slag did not reduce the thickness of the concrete interfacial transition zone significantly at 3 d, but it led to significant improvement in the thickness of the interfacial transition zone at 28 d, and the thickness of the interfacial zone at 28 d was reduced from 19 μm to 8.5 μm, a reduction of 55%. The minimum value of microhardness in the slurry region of the interfacial specimens also increased from 19 MPa to 26 MPa, an increase of 36%. In addition, the structural density of the interfacial region was further increased, resulting in varying degrees of improvement in the macroscopic anti-splitting strength. One of the important reasons for this phenomenon is that the addition of slag optimizes the chemical composition of the interface and promotes the continuation of the pozzolanic reactivity, which further enhances the hydration at the interface edge.

Simplified nonlinear model and 3D printing model experiment verification of longitudinal joints of shield tunnel segments

The segment joints represent vulnerable and core-bearing areas within shield tunnel structures. Their flexural stiffness, starting from the contact surface of longitudinal joints to the bolt hole, exhibits continuous changes under bending loads, typically demonstrating nonlinear mechanical characteristics. This study investigates the influence of joint contact surfaces on flexural stiffness, extending from the joint contact surface to damaged concrete in the compressed zone. A new simplified model for the variable nonlinear stiffness of longitudinal segment joints in shield tunnels is proposed, considering the flexural stiffness of the joint contact surface and the width of the damaged concrete zone in the segment ring while simulating the flexural stiffness decay induced by the opening of segment joints. Based on the minimum potential energy principle, a design calculation method for joint flexural stiffness is derived, establishing the nonlinear bending stiffness coupling relationship between the segment and the joint. Through similarity theory, 3D printing technology, and indoor loading tests, the theoretical model's accuracy regarding tunnel segment joints is verified. This theoretical model provides a basis for designing and assessing the performance of tunnel-segment joints.

Effect of Graphene Oxide Surface Deposition Process on Synthetic Macrofibers and Its Results on the Microstructure of Fiber-Reinforced Concrete.

The improvement of the mechanical properties of concrete can be achieved with the use of synthetic macrofibers. However, this fiber-matrix interaction will be sufficiently efficient for tensile efforts only when there is a binding agent that associates the characteristics of the paste with the characteristics of the surface of the reinforcing material. As already identified, in a first phase of this research using synthetic microfibers, a better fiber-matrix interaction can be achieved with the surface treatment of synthetic fibers with graphene oxide. In this way, we sought to evaluate the surface treatment with graphene oxide on two synthetic polypropylene macrofibers (macrofiber "A" and macrofiber "B") and its contribution to the concrete transition zone. The surface deposition on the macrofiber was carried out using the ultrasonication method; then, the macrofiber with the best deposition for creating reinforced concrete mixtures was identified. To evaluate the quality of GO deposition, scanning electron microscopy (SEM-FEG) and energy-dispersive spectroscopy (EDS) tests were carried out; the same technique was used to evaluate the macrofiber-matrix transition zone. The SEM-FEG images indicated that macrofiber "B" obtained greater homogeneity in surface deposition and it presented a 13% greater deposition of C in the EDS spectra. The SEM-FEG micrographs for reinforced concrete indicated a reduction in voids in the macrofiber-matrix transition zone for concretes that used macrofibers treated with GO.

Effects of siliceous iron tailings powder on performances of interface transition zone in concrete

At the meso-level, the interface transition zone (ITZ) is an important part of concrete and is closely related to the macroscopic properties of concrete. In this paper, the influences of siliceous iron tailings powder on concrete ITZ have been researched, in order to better reveal the mechanism of the powder as an auxiliary cementitious material in concrete. Based on XRD, SEM, hardness test and numerical simulation, the Ca(OH)2 (CH) crystal orientation, calcium-silicon ratio (Ca/Si), porosity, microhardness and elastic modulus of ITZ have been explored, and the results are as follows. When water-to-binder ratio (w/b) is 0.38 and 0.48, iron tailings powder increases the complexity of CH crystal orientation in the ITZ, but the effects of w/b and hydration age on the CH crystal orientation index with and without iron tailings powder are similar. The Ca/Si of ITZ blended with iron tailings powder is lower than that of benchmark group with the same w/b. The porosity in ITZ first decreases with the distance from aggregate surface, and stabilizes at about 40 μm, and the ITZ porosity in groups of iron tailings powder is less than that in the reference group at the same w/b and the same age. The microhardness and elastic modulus of ITZ decreases by mixing the iron tailings powder, and microhardness increases with the distance from aggregate surface, and at last stabilized at also about 40 μm, and elastic modulus increased with the decrease of w/b and the extension of hydration age. The findings show that incorporation of iron tailings powder has some degree of improvement on the microscopic structure of ITZ, but does not reduce its size, and the thickness of ITZ both with and without iron tailings powder are all 40μm. In particular, the variation law of pore in IZT needs to be studied more comprehensively and in-depth in the future.

Study on fracture characteristics and fracture mechanism of fully recycled aggregate concrete using AE and DIC techniques

Fracture behaviors of manufactured sand-recycled coarse aggregate concrete (MSRCAC), recycled fine aggregate concrete (RFAC), and fully recycled aggregate concrete (FRAC) were investigated by performing three-point bending tests on single-edge notched beams using acoustic emission (AE) and digital image correlation (DIC) techniques. The effects of recycled fine aggregate (RFA), recycled coarse aggregate (RCA), and their interaction on fracture parameters, AE characteristics and fracture process zone (FPZ) of concrete were comparatively analyzed. The results indicated that it was mainly transgranular failure and intergranular failure for RFAC, while transgranular failure for MSRCAC and FRAC. The RFA and RCA reduced the initial fracture toughness, unstable fracture toughness and fracture energy of concrete, and their interaction resulted in poor fracture properties of FRAC. In addition, the RFA and RCA significantly increased the AE activities, the proportion of tensile cracks, and the high-frequency amplitude and peak frequency of concrete. The toughening effect of FPZ was weakened by the RFA and RCA, resulting in an obvious increase in FPZ length and damage propagation of FRAC. Meanwhile, the width of FPZ was reduced, the maximum FPZ width of concrete with different combinations of recycled aggregates was approximately 1.8–3.1 times the maximum aggregate size, which could be explained as the RFA and RCA reduced the aggregate interlocking effect of concrete, while the RCA had a greater effect on the damage mechanism and FPZ of concrete than the RFA.