The modulational instability (MI) of ion-acoustic waves (IAWs) is examined theoretically in a four-component plasma system containing inertialess electrons featuring a non-thermal, non-extensive distribution, iso-thermal positrons, and positively as well as negatively charged inertial ions. In this connection, a non-linear Schrödinger equation (NLSE), which dominates the conditions for MI associated with IAWs, is obtained by using the reductive perturbation method. The numerical analysis of the NLSE reveals that the increment in non-thermality leads to a more unstable state, whereas the enhancement in non-extensivity introduces a less unstable state. It also signifies the bright (dark) ion-acoustic (IA) envelope solitons mode in the unstable (stable) domain. The conditions for MI and its growth rate in the unstable regime of the IAWs are vigorously modified by the different plasma parameters (viz., non-thermal, non-extensive q-distributed electron, iso-thermal positron, the ion charge state, the mass of the ion and positron, non-thermal parameter α, the temperature of electron and positron, etc.). Our findings may supplement and add to prior research in non-thermal, non-extensive electrons and iso-thermal positrons that can co-exist with positive as well as negative inertial ions.
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