Waste Loading Rate Research Articles

Recent Advances in Alternative Cementitious Materials for Nuclear Waste Immobilization: A Review

Since the emergence of the problem of nuclear waste conditioning, cementation has become an important and developing part of the waste management system, owing to its simplicity and versatility. The continued development of the cementation technique is driven by the improvement and expansion of cementitious materials that are suitable and efficient for nuclear waste solidification. Advances in cement theory and technology have significantly impacted improvements in nuclear waste cementation technology, the quality of fresh and hardened waste forms, waste loading rates, and the reliability and sustainability of the nuclear industry. Modern mineral matrices for nuclear waste immobilization are a broad class of materials with diverse chemical–mineralogical compositions, high encapsulation capacities, and technological and engineering performance. These matrices include not only traditional Portland cement, but also non-Portland clinker inorganic binders. This review focuses on recent trends and achievements in the development of calcium aluminate, calcium sulfoaluminate, phosphate, magnesium silicate, and alkali-activated cements as cementitious matrices for nuclear waste stabilization/solidification.

Structural change by phosphorus addition to borosilicate glass containing simulated waste components

Simulated nuclear waste glass samples containing phosphorus, which increase the solubility of molybdenum, were prepared and analyzed using synchrotron X-ray Absorption Fine Structure (XAFS) analysis for some constituent elements and Raman spectroscopic analysis of their complex structure. Changes in local structure and chemical state due to different phosphorus additions and waste loading rates were systematically studied. Consequently, no crystalline phase due to the molybdate compound was observed even at a maximum waste content of 30 wt% (corresponding to 1.87 mol% MoO3). Oxidation proceeded when the waste-loading rate was increased, whereas the reduction proceeded when phosphorus was added. In some cases, the effects of oxidation and reduction were offset. The local structure around specific elements can be classified as follows; Zn that is affected mainly by the waste-loading rate, Ce that is affected by both the waste-loading rate and phosphorus addition, and Zr element that is not affected by either of them. From the comparison between the analytical results of Mo and other elements, it was considered that the added phosphorus exists as a free PO4 structural unit and may deprive the alkali metal coordinated to the molybdate ion.

Sound enhances wastewater degradation and improves anaerobic digester performance

Biogas production and wastewater quality from anaerobic digesters were studied to determine whether sound at sonic frequencies (< 20,000 Hz) could enhance their performance. In three trials with increasing waste loading rates, each of 100-day duration, the performance of control and sound-treated digesters was compared. Anaerobic digesters exposed to sound produced approximately 12% more biogas than did non-exposed digesters, and sound-treated digestate had significantly lower chemical oxygen demand. Sludge at the end of the 100-day digestion averaged 19% less carbon and 18% less nitrogen in sound-treated digesters as compared to sludge from untreated digesters. Although the mechanism(s) responsible for enhanced biogas production due to sound exposure are unknown, recordings of sound-treated digesters indicate that acoustically induced cavitation may play a role.

Opportunities to improve the conversion of food waste to lactate: Fine-tuning secondary factors.

Extensive research has demonstrated the potential for bioconversion of food waste to lactate, with major emphasis on adjusting temperature, pH, and loading rate of the fermentation. Each of these factors has a significant effect on lactate production; however, additional secondary factors have received little attention. Here we investigate three additional factors where opportunities exist for process improvement: freezing of samples during storage, discontinuous pH control, and holdover of fermentation broth between fermentations. Freezing samples prior to fermentation was shown to reduce the production rate of lactate by 8%, indicating freeze-thaw should be avoided in experiments. Prior work indicated a trade-off in pH control strategies, where discontinuous pH control correlated with higher lactate accumulation while continuous pH control correlated with higher production rate. Here we demonstrate that continuous pH control can achieve both higher lactate accumulation and higher production rate. Finally, holding over fermentation broth was shown to be a simple method to improve production rate (by 18%) at high food waste loading rates (>140 g volatile solids L-1) but resulted in lower lactate accumulation (by 17%). The results inform continued process improvements within the waste treatment of food waste through fermentation to lactic acid.

Effects of co-substrate on biogas production from cattle manure: a review

This literature review surveys the previous and current researches on the co-digestion of anaerobic processes and examines the synergies effect of co-digestion with cattle manure. Furthermore, this review also pays attention to different operational conditions like operating temperature, organic loading rate (OLR), hydraulic retention time (HRT), chemical oxygen demand (COD) and volatile solid (VS) removal efficiency and biogas or methane production. This review shows that anaerobic mono-digestion of cattle manure usually causing poor performance and stability. Anaerobic studies were generally performed under mesophilic conditions maintained between 35 and 37 °C. Organic waste loading rate generally ranges from 1 to 6 g VS–COD L−1 day−1 stable condition in anaerobic digester. Generally, studies show that HRT for co-digestion of fruit–vegetables waste and industrial organic waste appears to exceed 20 days. However, the anaerobic co-digestion process is generally operated at HRT of between 10 and 20 days. VS and COD removal efficiency usually reaches up to 90 % due to co-digestion with different type organic waste. Methane–biogas production is generally obtained between 0.1 and 0.65 L CH4–biogas g−1 VS.

Optimisation of sewage sludge anaerobic digestion through co-digestion with OFMSW: Effect of collection system and particle size

The effect of organic fraction of municipal solid waste (OFMSW) loading rate and particulate size on the sewage sludge (SS) mesophilic anaerobic co-digestion was assessed in continuous stirred tank reactor at hydraulic retention time of 20days. The SS–OFMSW mixture composed by 54% of the volatile solids fed (inlet-VS), at OLR of 3.1kgCODm−3d−1 (1.9kgVSm−3d−1), showed the highest increment on the volumetric methane production and yield of +200% and +59% respectively, under stable conditions. The effect of particulate size was assessed with the same mixture and same operational conditions but reducing the OFMSW particulate size from 20mm to 8mm with the aim to improve the hydrolysis step, but the results showed any influence in the OFMSW particulate size range analysed. In addition, specific biomass activity was assessed at the end of each co-digestion period. Results showed that OFMSW promoted β-oxidation syntrophic acetogens and the acetoclastic methanogens activity; although the last increase of the OFMSW percentage (from 47% to 54% inlet-VS) affected negatively the specific substrate activity, but not inhibitory effect was observed. Therefore, the results obtained in the continuous experiment could be related with some inhibitory or toxic effect and not due to hydrolysis limitation. The specific biomass activity test was demonstrated to be an interesting tool to evaluate and control the co-digestion process, especially when conventional parameters did not explain the behaviour of the biological system.

Influence of soil physical parameters on removal efficiency and hydraulic conductivity of vertical flow constructed wetlands

Low cost filter materials for efficient waste water treatment in constructed wetlands are worldwide in demand. However, information on soil physical parameters needed for efficient treatment is scarce. We investigated 5 different lava and one fluviatile operating sand filters in Germany for their differences in pore size distribution spectra, specific inner surface area and cumulative pore volume. While these soil physical parameters did have an influence on purification capacity and hydraulic conductivity, differences in mineralogy (presence of zeolites), waste water distribution systems (baffle plates versus pipes) and loading rates were the dominating factors determining filter efficiency. Lava sands convince with high purification capacities during permanent loading rates of >100mmd−1, average loading rates of 20gCODm−2d−1 (chemical oxygen demand) and approximate effective loading rates of up to 250gCODm−2d−1.

The Effect of Various Waste Materials' Contents on the Attenuation Level of Anti-Radiation Shielding Concrete.

Samples of concrete contain various waste materials, such as iron particulates, steel balls of used ball bearings and slags from steel industry were assessed for their anti-radiation attenuation coefficient properties. The attenuation measurements were performed using gamma spectrometer of NaI (Tl) detector. The utilized radiation sources comprised 137Cs and 60Co radioactive elements with photon energies of 0.662 MeV for 137Cs and two energy levels of 1.17 and 1.33 MeV for the 60Co. Likewise the mean free paths for the tested samples were obtained. The aim of this work is to investigate the effect of the waste loading rates and the particulate dispersive manner within the concrete matrix on the attenuation coefficients. The maximum linear attenuation coefficient (μ) was attained for concrete incorporates iron filling wastes of 30 wt %. They were of 1.12 ± 1.31×10−3 for 137Cs and 0.92 ± 1.57 × 10−3 for 60Co. Substantial improvement in attenuation performance by 20%–25% was achieved for concrete samples incorporate iron fillings as opposed to that of steel ball samples at different (5%–30%) loading rates. The steel balls and the steel slags gave much inferior values. The microstructure, concrete-metal composite density, the homogeneity and particulate dispersion were examined and evaluated using different metallographic, microscopic and measurement facilities.

Effect of a water-based drilling waste on receiving soil properties and plants growth

This investigation was undertaken to determine the relative effects of recommended land spraying while drilling (LWD) loading rate application for a source of water-based drilling waste material on selected soil properties and phytotoxicity. Drilling waste material was obtained from a well where a nitrate gypsum water based product was used to formulate the drilling fluid. The fluid and associated drill cuttings were used as the drilling waste source to conduct the experiment. The study was carried out in triplicate and involved five plant species, four drilling waste loading rates and a representative agricultural soil type in Alberta. Plant growth was monitored for a period of ten days. Drilling waste applied at 10 times above the recommended loading rate improved the growth and germination rate of all plants excluding radish. Loading rates in excess of 40 and 50 times had a deleterious effect on radish, corn and oat but not on alfalfa and barley. Germination rate decreased as waste loading rate increased. Effects on soil physical and chemical properties were more pronounced at the 40 and 50 times exceeding recommended loading rate. Significant changes in soil parameters occurred at the higher rates in terms of increase in soil porosity, pH, EC, hydraulic conductivity, SAR and textural classification. This study indicates that the applications of this type of water based drill cutting if executed at an optimal loading rate, may improve soil quality and results in better plant growth.

Drained response of municipal solid waste in large-scale triaxial shear testing

A comprehensive laboratory investigation was performed on municipal solid waste (MSW) from a landfill located in northern California using a large-scale triaxial (TX) apparatus. An improved, standardized waste specimen preparation method was developed and used to prepare 27 large-scale TX specimens (d=300mm, h=600–630mm). The effects of waste composition, confining stress, unit weight, loading rate, and stress path on the drained stress–strain response of MSW were investigated. Waste composition has a significant effect on its stress–strain response. The commonly observed upward curvature of the stress–strain response of specimens composed of larger-sized waste materials results from the fibrous constituents (primarily paper, plastic and wood) reinforcing the waste matrix. This effect is greatest when the MSW specimen is sheared across the long axis of the fibrous particles. Due to this significant strain hardening effect and waste’s in situ stress state, a limiting strain failure criterion of 5% axial strain from the Ko field consolidation state is judged to be most appropriate. Results from this test program and data from the literature indicate that the TX compression secant friction angle of MSW varies from 34° to 44°, with 39° as a best estimate, at a confining stress of one atmosphere (assuming c=0). The friction angle decreases as confining stress increases. The friction angles measured in this testing program are representative of failure surfaces that are oriented at an angle to the predominant orientation of the long axis of the fibrous waste particles. These friction angles are higher than those obtained in direct shear tests where shearing typically occurs parallel to the orientation of the fibrous waste particles.

Large-scale direct shear testing of municipal solid waste

Large direct shear testing (300 mm × 300 mm box) of municipal solid waste (MSW) collected from a landfill located in the San Francisco Bay area was performed to gain insight on the shear response of MSW. The study investigated the effects of waste composition, confining stress, unit weight, and loading rate on the stress–displacement response and shear strength of MSW. The amount and orientation of the fibrous waste materials in the MSW were found to play a critical role. The fibrous material had little effect on the MSW’s strength when it was oriented parallel to the shear surface, as is typically the case when waste material is compressed vertically and then tested in a direct shear apparatus. Tests in which the fibrous material was oriented perpendicular to the horizontal shear surface produced significantly stronger MSW specimens. The test results indicate that confining stress and loading rate are also important factors. Based on 109 large-scale direct shear tests, the shear strength of MSW at low moisture contents is best characterized by cohesion = 15 kPa, friction angle = 36° at a normal stress of 1 atmosphere, and a decrease in the friction angle of 5° for every log-cycle increase in normal stress.

Parametric sensitivity analysis of coupled mechanical consolidation and contaminant transport through clay barriers

In this paper, an extensive parametric sensitivity analysis of coupled consolidation and solute transport in composite landfill liner systems has been undertaken. The analysis incorporates results of more than 3000 simulations for various combinations of barrier thickness, waste loading rate, initial void ratio, compression index, hydraulic conductivity and dispersion coefficient. However, it is noted that to limit the extent of the study a constant coefficient of consolidation is assumed in the analysis presented here, though this assumption is easily relaxed. Results of the parametric sensitivity analysis are succinctly presented using dimensionless plots, which allow the comparison of results for a large number of parameter values, and so the clear identification of the most important determinants on contaminant transport through the liner system. The dimensionless plots demonstrate a pessimum (for which the ‘breakthrough time’ is minimised). Numerical results reveal that in cases of extreme liner compressibility an order of magnitude reduction in contaminant transit time may arise due to coupling between solute transport and consolidation, while for barriers of low compressibility and porosity (such as well-engineered composite compacted clay landfill liners), it is found that the contaminant transit time may still be reduced by more than 30%. The numerical results suggest that the use of coupled consolidation–contaminant transport models are sometimes required for informed and conservative landfill liner design.

Anaerobic digestion of municipal solid wastes containing variable proportions of waste types

In many parts of the world there are significant seasonal variations in the production of the main organic wastes, food and green wastes. These waste types display significant differences in their biodegradation rates. This study investigated the options for ensuring process stability during the start up and operation of thermophilic high-solids anaerobic digestion of feedstock composed of varying proportions of food and green wastes. The results show that high seed sludge to feedstock ratio (or low waste loading rate) is necessary for ensuring process pH stability without chemical addition. It was also found that the proportion of green wastes in the feedstock can be used to regulate process pH, particularly when operating at high waste loading rates (or low seed sludge to feedstock ratios). The need for chemical pH correction during start-up and digestion operation decreased with increase in green wastes content of the feedstock. Food wastes were found to be more readily biodegradable leading to higher solids reduction while green wastes brought about pH stability and higher digestate solid content. Combining both waste types in various proportions brought about feedstock with varying buffering capacity and digestion performance. Thus, careful selection of feedstock composition can minimise the need for chemical pH regulation as well as reducing the cost for digestate dewatering for final disposal.

A model for optimal operation of land-treatment sites for oily wastes.

Land treatment as a disposal technology has been extensively used for the disposal of oily wastes. Effective management of land treatment sites require optimal operation of the system in order to achieve the fastest and most complete degradation of petroleum hydrocarbons without contamination of the environment. This paper describes a model that can be used for optimising the operation of land treatment sites for oily wastes. The model is composed of system simulator and optimisation submodels. Conceptually, the system simulation submodel is composed of a waste mixing zone, lower treatment zone and aquifer modules. The system simulation model allows for periodic waste applications and determines the spatial and temporal variation of the state variables such as phase summed (total) and aqueous phase contaminant concentrations and water content in the system. The optimisation submodel coupled with the system simulator determines the optimal values of system control variables, such as waste loading rate, infiltration rate, water content, frequency of waste application and the dimensions of the land treatment site. Optimisation of these system control variables is accomplished by maximising the hydrocarbon mass removal from the waste mixing zone under the constraint of satisfying a prespecified water quality criteria in the aquifer. Selected model applications are presented to demonstrate the applicability and utility of the model. Such model applications include determination of the optimal operating conditions for the land treatment of oily wastes under various different site and soil environmental conditions and practical waste disposal scenarios.

Use of constructed wetlands to process agricultural wastewater

Constructed wetlands are emerging as a serious challenge to conventional wastewater treatment because of lower construction and operating costs, less requirement for trained personnel, more flexibility, and lower susceptibility to variations in waste loading rates. Water quality improvements can be achieved by removal of plant nutrients, such as N and P, organics (natural and manmade) as well as inorganic contaminants. Wetland treatment is now advocated by regulatory agencies and has been determined as the technology of choice by municipalities and industries required to meet stringent discharge regulations. These same regulations have not usually been imposed on the agricultural community, but deteriorating water sources will likely change this regulatory anomaly. Use of this technology in treating agricultural wastewater is still in its infancy with few, although rapidly expanding, applications. This paper aims to highlight different aspects of wetland treatment by exploring its use for the treatment of agricultural run-off as well as wastewater from the agri-food industry. It is concluded that natural wetlands will be quite limited in absorbing agricultural wastewater while constructed wetlands can be designed for optimum pollutant removal. Key words: Constructed wetlands, wastewater treatment, agriculture, food processing, nutrient removal, nitrogen, phosphorus, organics

Assessing detoxification of a complex hazardous waste, using the Microtox bioassay.

Research has demonstrated the usefulness of the Microtox™bioassay in assessing the acute toxicity of organic compounds. Recently, the use of the Microtox™bioassay has been extended to applications in hazardous waste management. The rapidity of the test, low sample requirements, and low cost provide several advantages over chemical analysis, especially for complex waste mixtures. Microtox™bioassay results correlate closely with results from rainbow trout bioassays, and are more sensitive to inhibitory chemicals than activated sludge organisms. An experimental approach using batch reactors and soil columns was implemented in the laboratory to evaluate the detoxification and mobility of a toxic complex hazardous waste in soil. The objective of the study reported here was to quantify the extent and rate of detoxification of a complex hazardous waste as affected by soil type and waste application rate. The extent and rate of detoxification was directly related to waste loading rate for both soil types investigated, in both batch reactors and soil column reactors. Analysis of the toxicity of aqueous soil extracts at incremental depths through soil columns and of soil columnn leachate indicated a low leaching potential for the complex petroleum refinery waste.

Methanogenesis in a Thermophilic (58°C) Anaerobic Digestor: Methanothrix sp. as an Important Aceticlastic Methanogen

Aceticlastic methanogens and other microbial groups were enumerated in a 58 degrees C laboratory-scale (3 liter) anaerobic digestor which was fed air-classified municipal refuse, a lignocellulosic waste (loading rate = 1.8 to 2.7 g of volatile solids per liter per day; retention time = 10 days). Two weeks after start-up, Methanosarcina sp. was present in high numbers (10 to 10 CFU/ml) and autofluorescent Methanosarcina-like clumps were abundant in sludge examined by using epifluorescence microscopy. After about 4 months of digestor operation, numbers of Methanosarcina sp. dropped 2 to 3 orders of magnitude and large numbers (most probable number = 10 to 10/ml) of a thermophilic aceticlastic methanogen morphologically resembing Methanothrix sp. were found. Methanothrix sp. had apparently displaced Methanosarcina sp. as the dominant aceticlastic methanogen in the digestor. During the period when Methanothrix sp. was apparently dominant, acetate concentrations varied between 0.3 and 1.5 mumol/ml during the daily feeding cycle, and acetate was the precursor of 63 to 66% of the methane produced during peak digestor methanogenesis. The apparent K(m) value obtained for methanogenesis from acetate, 0.3 mumol/ml, indicated that the aceticlastic methanogens were nearly saturated for substrate during most of the digestor cycle. CO(2)-reducing methanogens were capable of methanogenesis at rates more than 12 times greater than those usually found in the digestor. Added propionate (4.5 mumol/ml) was metabolized slowly by the digestor populations and slightly inhibited methanogenesis. Added n-butyrate, isobutyrate, or n-valerate (4.5 mumol/ml each) were broken down within 24 h. Isobutyrate was oxidized to acetate, a novel reaction possibly involving isomerization to n-butyrate. The rapid growth rate and versatile metabolism of Methanosarcina sp. make it a likely organism to be involved in start-up, whereas the low K(m) value of Methanothrix sp. for acetate may cause it to be favored in stable digestors operated with long retention times.

Reliability of River‐Treatment Plant Systems

The reliability of river‐treatment plant systems is determined by considering fluctuations in both the streamflow rate and waste loading rate. The method involves an application of the elementary theory of hydrologic statistics and waste assimilation models to the cumulative density functions of the flow rates and loading rates. The products of the method are the expected number of system failures per drought, the interval between failures and the annual return period of droughts containing at least one systems failure. It is shown that the usual methods based on rare drought flows (e.g., the seven‐day average flow with a 10‐yr return period) cannot provide this information. Also, designs based on rare drought flows are not conformable to stream standards, whereas designs based on the proposed method are intrinsically conformable to stream standards.

Mineralization of Soil‐Incorporated Tomato Solid Waste

AbstractSolid waste from the processing of tomatoes (Lycopersicum esculentum Mill.) consisting primarily of fruit peels and seeds was incorporated into Yolo sandy loam soil, wetted, and incubated at 10, 20, or 30°C for 32 weeks. At 2‐week intervals the soil was analyzed for NO3‐N, PO4‐P, SO4‐S, Cl, total N, organic C, and exchangeable Ca, Mg, K, and Na. Soil pH and electrical conductivity were measured at the beginning of the study and after 32 weeks.With each increment of dried tomato waste applied at rates of 2.5, 5.0, and 10.0% of air‐dry soil, the total organic C and N content of the soil increased. The amount of NO3‐N released from 2.5% rate of waste at 20°C soil temperature was similar to that released from 60 ppm N applied as (NH4)2SO4. Nitrogen released from waste applied at rates of 5.0 and 10.0% air‐dry soil exceeded the level of N usually applied for crop production at about 76 kg N/ha.Significant interactions occurred on NO3‐N release among waste application rates, soil temperatures, and times. At 10°C, there was an increase in NO3‐N released with each increase in waste application. At 20°C, a NO3‐N increase occurred at 2.5 and 5.0% waste application rates, but the increase was less at 10.0 than at 5.0%. At 30°C, a marked reduction of NO3‐N release occurred between 16 and 32 weeks of incubation at all rates of waste application, but was more acute at 10.0% than at lower rates. A similar response, but of lesser magnitude, occurred with release of PO4‐P. Variability in release of NO3‐N and PO4‐P was attributable to the composition of tomato waste and to microbiological activity.Release of SO4‐S was a function of waste loading rate and time. Essentially, all Cl was released within the first week of incubation. An appreciable increase of K, slight increase of Ca, minimal increase of Na, and no change of Mg was found in the soil after 32 weeks of incubation. Although tomato waste is acidic, soil pH decreased only at the highest loading rate after 32 weeks of incubation.

Phosphorus Adsorption‐Desorption Characteristics of Two Soils Utilized for Disposal of Animal Wastes

AbstractThe purpose of this study was to determine the effect of animal waste loading rates on P adsorption‐desorption characteristics of two soils. In a laboratory incubation study, Norfolk soil was treated with beef, poultry, or swine wastes; and allowed to decompose under optimum moisture conditions for a period of 30 days. Phosphorus adsorption‐desorption characteristics of the soil were measured at the end of the incubation period. Application of beef, poultry, and swine wastes to a Norfolk soil decreased adsorption capacity of the soil and increased soluble P (in 0.01M CaCl2), acid‐extractable P (0.05N HCl + 0.025N H2SO4), equilibrium P concentration (EPC), and P desorption (after four 1‐hour extractions).In a field study, increased rates of swine lagoon effluent application over a period of 5 years to a Norfolk soil (Site 1) and for 3 years to a Cecil soil (Site 2) also increased soluble P (in 0.01M CaCl2), acid extractable P, P desorbed, and EPC values, and decreased the adsorption capacity. At high loading rates of swine lagoon effluent, soluble P movement occurred to a depth of 75 and 30 cm at Site 1 and 2, respectively. Phosphorus adsorption increased with depth, and EPC values decreased with increasing depths of soil profile. A significant relationship was observed between EPC values, and soluble and acid extractable P.