Waste Incineration Bottom Ash Research Articles

Impacts of advanced metals recovery on municipal solid waste incineration bottom ash: aggregate characteristics and performance in portland limestone cement concrete

The optimization of alternative materials in concrete production continues to garner considerable attention in order to meet sustainability goals and supplement natural materials. Portland limestone cement (PLC) and municipal solid waste incineration (MSWI) bottom ash (BA) have been proposed separately as green cement and coarse aggregate supplement in low-strength concrete production, creating sustainable products and alternative disposal scenario for a waste material. This study discusses the impact of advanced ash processing techniques on aggregates and presents the performance of concrete incorporating both of these products with PLC for the first time. Two sources of MSWI BA were investigated, one as-produced (TMR) and one processed with novel advanced metals recovery (AMR). The AMR process reduced total Al content in ash compared to TMR (20,500 vs 17,000 mg/kg), though not aluminum oxide content, as the AMR process targets metallic aluminum. A composition study on both aggregates supports a reduction in ferrous and non-ferrous metals following the AMR process. All control and test mixes met 28-day compressive strength requirements (17 Mpa). Both AMR and TMR MSWI BA-amended concretes yielded compressive strengths below control specimens (no ash) ranging from 17 to 23 MPa, with little to no difference observed dependent on MSWI BA processing. The life-cycle discussion supports benefits deriving from supplementing naturally mined materials and recovering ferrous and nonferrous metals with the AMR process.

Converting municipal solid waste incineration bottom ash into the value-added artificial lightweight aggregates through cold-bonded granulation technology

To effective recycle the Municipal solid waste incineration bottom ash (MSWIBA), this study adopts cold consolidation granulation technology to develop eco-friendly artificial lightweight aggregates (ALCBAs), and the materials are over 50 % dosage of MSWIBA, less 50 % fly ash (FA) or ground granulated blast furnace slag (GGBFS), and 10 % ordinary Portland cement (OPC). This study investigated the effects of different binder types and dosages on the properties of ALCBAs, including compressive strength, water absorption rate, bulk density, microstructures, pore development, heavy metal leaching behavior, and sustainability. The feasibility of ALCBAs to design green concrete was also explored. The results show that with higher content of MSWIBA and binders of FA, GGBFS and OPC, the ALCBAs with compressive strength greater than 2.5 MPa, bulk density of about 1000 kg/m3 and water absorption rate greater than 12 % was successfully developed. Increasing the content of FA/GGBFS is beneficial to improve the compressive strength and reduce the water absorption rate and the total porosity and lower the air bubbles percentage of ALCBAs. More importantly, both FA and GGBFS are mixed into ALCBAs, the compressive strength is at 2.5 MPa-3.0 MPa, the water absorption rate is significantly reduced, and the energy consumption, carbon footprint and cost are also significantly reduced. As the content of ALCBAs increases, although the compressive strength and splitting tensile strength are not as good as concrete with natural aggregates, the density of low-carbon concrete with ALCBAs gradually decreases, and the interface transition zone is gradually improved. Overall, ALCBAs can be beneficial to the conservation of natural resources (natural aggregates) and effectively solve the shortage of natural aggregates, and can be used to deal with the accumulation of solid waste in a green way, and it also can open up new channel for solid waste recycling.

NaAlO2 activated slag and MSWI bottom ash: Phase assemblages and thermodynamic assessment of long-term leaching behavior

Long-term leaching (heavy metal ions) behavior of municipal solid waste incineration bottom ash (MSWI BA) is one of the issues limiting its application in alkali activated materials (AAMs). This study investigates NaAlO2 activated slag (partially replaced by MSWI BA) in terms of the reaction process and leaching behavior. A combined approach of experimental observation and thermodynamic modeling is utilized. The hardened pastes were evaluated by reaction kinetics, mineralogy, microstructure, strength, and leaching. The thermodynamic modeling included consideration of the raw materials chemistry and activator types. Results show that the modeled C(N)−A−S−H is in line with quantitative results. Specifically, modeled hydrotalcite content (3g/100g binder) is slightly higher than the experimental results (2g/100g binder) at 28 days. Furthermore, the uptake of Cu dramatically increases at 20 days by the generated C(N)−A−S−H gels, while the binding capacity of Sb, sulfates, and chlorides increases with the formation of hydrotalcite formation over time.

Insights into the usage of biobased organic acids for treating municipal solid waste incineration bottom ash towards metal removal and material recycling

The recycling of incineration bottom ash (IBA) is crucial for sustainable municipal solid waste (MSW) management and alleviating landfill burdens. However, limited environmentally friendly methods exist to effectively treat IBA for safe recycling. This study systematically examined the performance of biobased organic acids, namely citric acid (CA), oxalic acid (OA), lactic acid (LA), and levulinic acid (LEA), for IBA treatment. CA shows high extraction efficiency for most trace metals (e.g., Mn > 65 %, Pb > 50 %, Co approx.100 %, Cd > 85 %, Zn > 80 %, Ni > 80 %), while OA performs better for certain trace metals (e.g., Sn approx.99 %, Sb > 70 %, Mo > 70 %, Cr > 50 %). Multivariate statistical analysis and instrumental techniques were used to gain deeper insights into the critical mechanisms, including proton promoted dissolution, ligand related dissolution and precipitation/co-precipitation. The latter two mechanisms are distinctive metal extraction behaviours by organic acids compared to their inorganic counterparts. Both CA- and OA-treated alkaline-washed IBA residues demonstrate high leaching reduction efficiency (>99.9 %) of the critical heavy metals, making the treated IBA residues suitable for safe recycling as construction materials. This study highlights the potential of environmentally friendly organic acids which can be derived from bio-wastes for treating and repurposing IBA as resources for construction materials, promoting sustainable waste management for MSW incineration ash.

Atomic-Scale Insights into the Effects of the Foaming Degree on the Glass-Ceramic Matrix Derived from Waste Glass and Incineration Bottom Ash.

Precise management of the inverse correlation between the total porosity and compressive strength is crucial for the progress of foaming glass-ceramics (FGCs). To deeply understand this relationship, we investigated the atomic-level transformations of five CO2-foaming FGC samples using molecular dynamics simulation. The short-range and intermediate-range structures of the FGCs with varying total porosities (36.68%, 66.28%, 66.96%, 72.21%, and 79.88%) in the system were elucidated. Na cations were observed to exhibit a strong interaction with CO2, accumulating at the surface of the pore wall and influencing the oxygen species. Therefore, the change in the atomic structure of the matrix was accompanied by an increase in the total porosity with an increasing CO2 content. Specifically, as the total porosity increased, the bridging oxygen content within the FGCs rose accordingly. However, once the total porosity exceeded 66.96%, the bridging oxygen content began to decline. This observation was significant considering the role of the bridging oxygen content in forming a continuous cross-linked network of chemical bonds, which contributed to the enhanced mechanical strength. Consequently, the influence of the total porosity on the oxygen species resulted in a two-stage reduction in the compressive strength. This study offers valuable insights for the development of high-strength lightweight FGCs.

Preparation and Hydration Properties of Sodium Silicate-Activated Municipal Solid Waste Incineration Bottom Ash Composite Ground-Granulated Blast Furnace Slag Cementitious Materials.

The production of municipal solid waste incineration bottom ash (MSWIBA) is substantial and has the potential to replace cement, despite challenges such as complex composition, uneven particle size distribution, and low reactivity. This paper employs sodium silicate activation of MSWIBA composite Ground-granulated Blast Furnace slag (GGBS) to improve the reactivity in preparing composite cementitious materials. It explores the hydration performance of the composite cementitious materials using isothermal calorimetric analysis, Fourier-transform infrared (FTIR) spectroscopy, XRD physical diffraction analysis, and SEM tests. SEM tests were used to explore the hydration properties of the composite gelling. The results show that with an increase in MSWIBA doping, the porosity between the materials increased, the degree of hydration decreased, and the compressive strength decreased. When the sodium silicate concentration increased from 25% to 35%, excessive alkaline material occurred, impacting the alkaline effect. This inhibited particle hydration, leading to a decrease in the degree of hydration and, consequently, the compressive strength. The exothermic process of hydration can be divided into five main stages; quartz and calcite did not fully participate in the hydration reaction, while aluminum did. The vibrational peaks of Si-O-Ti (T = Si and Al) were present in the material. The vibrational peaks of XRD, FTIR, and SEM all indicate the presence of alumosilicate network structures in the hydration products, mainly N-A-S-H and C-A-S-H gels.

Treatment of waste marine clay by alkaline-activated ground granulated blast-furnace slag and municipal solid waste incineration bottom ash

The construction of coastal areas generates a substantial volume of waste marine clay (WMC), which poses environmental and safety challenges during the stockpiling process. The improved preparation of WMC as roadbed materials emerges as a crucial pathway for resource utilization. However, the engineering performance and durability of roadbed materials prepared from WMC have always been a concern for scholars and engineers. This study employs alkali-activated ground granulated blast-furnace slag (GGBFS) and municipal solid waste incineration bottom ash (MSWIBA) to solidify WMC for preparation of the roadbed materials. The results showed that the combined utilization of alkali-activated GGBFS and MSWIBA to improve WMC can meet the environmental and mechanical requirements of roadbed materials. The incorporation of 5-20% MSWIBA could improve the water stability coefficient and California bearing ratio to more than 85% and 80%, respectively. The durability of roadbed material was significantly improved by addition of MSWIBA. After 12 dry–wet cycles, the strength of the material without MSWIBA and with 5% MSWIBA was 0 and 2.87 MPa, respectively. Following analysis of engineering properties and durability, the optimal dosage of MSWIBA was determined to be 5%. The enhanced durability can be attributed to the optimization of material gradation and pore structure achieved through the incorporation of a small quantity of MSWIBA. The carbon emission and normalized global warming potentials of roadbed material treated by MSWIBA and GGBFS were much lower than that of cementitious binders such as ordinary Portland cement. These findings indicate that MSWIBA has the potential to substitute natural aggregates like sand and gravel, effectively improving the durability of roadbed materials and promoting the safe and efficient recycling of solid waste resources.

A Preliminary Study on the Beneficiation and Recovery of Valuable Metals from Municipal Solid Waste Incineration Bottom Ash

A Preliminary Study on the Beneficiation and Recovery of Valuable Metals from Municipal Solid Waste Incineration Bottom Ash

Utilization of Aluminosilicate Industrial Wastes as Precursors in CO2-Cured Alkali-Activated Precast Concrete Pavement Blocks

This research focuses on the utilization of recently investigated aluminosilicate industrial wastes as precursors to produce non-structural precast alkali-activated concrete pavement blocks. For this purpose, conventional blocks (200 mm × 100 mm × 80 mm) were produced using electric arc furnace slag and municipal solid waste incineration bottom ashes as the sole binders. Portland cement and fly ash blocks were produced as references. The blocks underwent a curing regimen comprising thermal, dry, and carbonation curing stages. Control uncarbonated specimens were subjected to dry curing instead of CO2-based curing to evaluate the influence of carbonation on the blocks’ strength development. The specimens were subsequently examined following EN 1338, which is the European standard for assessing and ensuring the conformity of conventional concrete pavement blocks. The carbonated blocks revealed improved mechanical and physical properties in relation to the uncarbonated ones. All blocks met standard dimensions, showed minimal skid potential (most indicating extremely low potential for slip for reporting unpolished slip resistance values exceeding 75), and had enhanced abrasion resistance due to carbonation, showing 30% and 11% less volume loss due to abrasion for fly ash and bottom ash, respectively. Carbonated blocks performed better than non-carbonated ones, displaying lower water absorption (0.58% and 0.23% less water absorption for bottom ash and slag, respectively) and higher thermal conductivity (20%, 13%, and 8% increase in values for fly ash, slag, and bottom ash, respectively). These results confirm the effectiveness of the accelerated carbonation curing technique in improving the block’s performance. Despite the promising outcomes, further optimization of the alkaline solution and carbonation curing conditions is recommended for future research.

Enhancing mechanical performance and durability of high strength mortar with incineration bottom ash via Al2O3 micro-powder: An experimental study

The untreated application of municipal solid waste incineration bottom ash (IBA) in cementitious materials can lead to compromised workability, deterioration of mechanical properties, and compromise durability. This paper examines the potential of utilizing Al2O3 micro-powder (ALMP) to enhance the mechanical performance and durability of cementitious materials fabricated with IBA. This paper focuses on the effect of different dosages of ALMP on the workability, mechanical performance and durability of high strength mortar (HSM) prepared by IBA. In addition, effect of ALMP on the ultrasonic pulse velocity (UPV), dynamic modulus of elasticity (DME) and microstructure of HSM was also investigated. Finally, the micro-mechanical performance of HSM paste was determined via nanoindentation experiment. Our study discovered that the integration of ALMP in HSM contrived with IBA notably amplified the flexural and compressive strengths by ranges of 1.12 %∼9.84 % and 3.78 %∼21.26 %, respectively. Simultaneously, the ALMP improved the UPV by an interval of 3.16 %∼9.49 %, and the DME by a parameter of 9.64 %∼18.69 %. Additionally, we observed considerable lowering of drying shrinkage in HSM by 4.96 %∼28.36 % and decline in the chloride migration coefficient by 7.45 %∼38.75 % due to ALMP's presence. Overall, based on the observed impact of ALMP on HSM's workability, mechanical properties, and microstructure, we suggest 10 wt% as the optimal doping amount for ALMP in HSM. Our investigation puts forward that implementing IBA in place of traditional quartz sand in the preparation of HSM could potentially attenuate energy consumption, carbon emissions, and production overheads. The findings of this study may offer instructive significance for improving the resource utilization of IBA in cement-based materials.

Utilizing municipal solid waste incineration bottom ash and volcanic tuff to produce geopolymer materials

Large volumes of municipal solid waste incineration bottom ash (MSWIBA) are produced annually in China; however, their improper disposal causes serious ecological and environmental problems. This study investigated the feasibility of using MSWIBA and volcanic tuff to produce geopolymers. The effects of the MSWIBA content, silicon–sodium molar ratio, and alkali equivalent on the uniaxial compressive strength (UCS) and bulk density of the geopolymer samples were examined using single-factor and optimization tests. The test results showed that the UCS and bulk density of the geopolymer decreased as the MSWIBA content increased, whereas they increased as the alkali equivalent increased. As the silicon–sodium molar ratio increased, the UCS first increased and then decreased, and the change in bulk density was limited. In the final geopolymer preparation, the MSWIBA content was 17.85%, the silicon–sodium molar ratio was 1.71, and the alkali equivalent was 9.49%. According to X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy-dispersive spectrometry, and nuclear magnetic resonance analyses, the main phases of the geopolymer under the final preparation parameters were quartz, sanidine, calcite, orthoclase, gismondine, and illite. During the geological polymerization process, a large amount of CNASH gel was generated and attached to the surface of the particles or filled the pores between the particles, resulting in a pore size of 0.01–1 μm. The heavy metals in the geopolymers exhibited a good stabilization effect owing to the CNASH gel. Except for Cd, which posed a medium risk, the remaining heavy metals posed low or no risk.

Research on using municipal solid waste incineration bottom ash for cement-stabilized macadam

Municipal solid waste incineration bottom ash (MSWIBA) is the waste generated by incineration power plants. Because of its low activity, it is an effective way to apply it to cement-stabilized macadam (CSM) in road construction. CSM was prepared using varying proportions of bottom ash (0%, 15%, 20%, 25%, 30%, and 35%) and different proportions of cement (3.5%, 4%, 4.5%, 5%, and 5.5%), respectively, to explore the effects of MSWIBA as fine aggregates on the characteristics of cement-stabilized MSWIBA macadam (CSBAM). MSWIBA was examined in terms of its microstructure, chemical makeup, and physical characteristics. Heavy metal leaching, water stability, splitting strength, unconfined compressive strength, and dry shrinkage were all investigated for CSBAM. The findings demonstrated that there was some cementitious and volcanic ash activity and that the bottom ash had a rough, porous surface. The strength of CSBAM decreased with the increase of MSWIBA dosage and increased with the increase of cement reference. Replacing fine aggregate with MSWIBA reduced the water stability of CSBAM. The water stability was better when the bottom ash dosage was more than 20%. Bottom ash reduced the dry shrinkage strain of cement-stabilized macadam, and CSBAM had better anti-dry shrinkage performance. CSBAM had a curing effect on heavy metals, and the leaching concentration of heavy metals was in accordance with the standard, which had less impact on the environment.

Valorisation of municipal solid waste incinerator bottom ash for the production of compressed stabilised earth blocks

This research centres its attention on the valorisation of incinerator bottom ash derived from municipal solid waste with the aim of producing compressed stabilised earth blocks. Compressed stabilised earth blocks is prepared with 6–12% cement and 10–40% MSWIBA, whose performance is assessed in terms of strength and durability. This includes several properties of compressed stabilised earth blocks, including dry compressive strength, flexural strength, tensile strength, water absorption, wetting-drying cycle, ultrasonic pulse velocity and acid attack. The findings indicate that the inclusion of municipal solid waste incinerator bottom ash as a 20% replacement of soil enhances the compressive strength and ultrasonic pulse velocity of the blocks. Nevertheless, the excessive use of municipal solid waste incinerator bottom ash (beyond 20%) results in an augment of void content and a reduction in compressive strength. The results of the study suggest that the usage of municipal solid waste incinerator bottom ash in the blocks leads to the enhancement of their aesthetic qualities. The study employing scanning electron microscopy indicates an excessive quantity of ettringite crystals in the samples derived from ash of quantity beyond 20%. This is because these samples have higher porosity, which enables the acidic medium to penetrate samples easily and react with the cement hydration products. Hence, though showing less discolouration on the surface, these samples show a significant reduction of compressive strength at the end of the testing regime. Similar results were obtained for the wetting and drying test as well. Therefore, this study recommends a maximum usage of 20% municipal solid waste incinerator bottom ash as a replacement for soil.

A sustainable treatment method to use municipal solid waste incinerator bottom ash as cement replacement

This paper studies the use of municipal solid waste incinerator bottom ash as a supplementary cementitious material in concrete products using an innovative chemical treatment approach. The primary objective is to address emissions associated with waste-to-energy facilities and the heavy reliance on ordinary Portland cement as the primary binder in concrete. The proposed method involves the removal of metallic aluminium from the bottom ash and the subsequent use of the treated bottom ash as a partial cement replacement to produce concrete. Concrete specimens were produced with varying proportions of treated or untreated municipal solid waste incinerator bottom ash, replacing 20%, 35%, and 55% of ordinary Portland cement according to EN 197 European standard for common cement. Moreover, class F fly ash was incorporated in equivalent percentages as a reference supplementary cementitious material, and a control mix was prepared using solely Portland cement. The evaluation encompassed multiple visual and analytical techniques, including scanning electron microscopy, X-ray diffraction, X-ray fluorescence, and setting time analyses on pastes made with Portland cement, fly ash, and bottom ash. All specimens were evaluated in terms of mechanical performance, namely compressive strength. The chemical treatment process facilitated the release of a significant quantity of hydrogen, a by-product of aluminium oxidization. Consequently, this resulted in significantly reduced formation of gas bubbles in concrete in the fresh state and, therefore, diminished expansion during the setting process. As the proportion of cement replacement with bottom ash increased, a decline in strength was observed. However, this decline was less pronounced when using treated bottom ash, particularly with lower levels of incorporation.

Experimental study on municipal solid waste incineration bottom ash as a component of alkali-activated coal gangue-based geopolymer.

This study explores the potential of municipal solid waste incineration bottom ash (MSWI BA) and coal gangue as precursors for alkali-activated cementitious materials (CG-MBA). An examination of the impact of MSWI BA content, NaOH/Na2SiO3 ratio, liquid-solid ratio, and NaOH concentration on strength and reaction through the application of diverse analytical methodologies. Results demonstrate that CG-MBA offers significant environmental benefits compared to conventional cement. When used as a construction filling material, CG-MBA exhibits a remarkable 74.5 ~ 79.2 wt% reduction in carbon dioxide emissions and 70.6 ~ 77.0 wt% reduction in energy consumption. Additionally, CG-MBA effectively immobilizes heavy metal ions in MSWI BA, with a fixation efficiency exceeding 56.0%. These findings suggest that CG-MBA is a promising sustainable solution for waste management, offering significant environmental benefits while demonstrating effective heavy metal immobilization. This approach contributes to pollution control and promotes environmental sustainability in the construction industry.

FORMING AND PROPERTIES OF GLASSES MADE FROM TWO THAI BOTTOM ASHES

Industrial wastes are often an under-utilized source of raw materials. Bottom ashes resulting from incineration processes can contain various metal oxides, including many commonly used in glass making. This research studied the forming and properties of glasses made from two bottom ashes. Lignite bottom ash (BL) from Lampang, Thailand and a municipal solid waste incinerator bottom ash (BP) from Phuket, Thailand. Both bottom ashes were found to contain significant amounts of SiO2, CaO, Al2O3, and Fe2O3. After ball milling, the ashes were melted without additions, at temperatures from 1300 to 1500°C. The resulting glasses, as confirmed by XRD, were black and fully opaque, a result of the high Fe2O3 content. It was found that the BP glasses were slightly more refractory, had a greater average thermal conductivity of 1.52 W/m·K and a lower coefficient of thermal expansion (CTE) of 6.97x10-6/°C, compared to the BP glasses, which had an average thermal conductivity of 1.39 W/m·K and a CTE of 7.98x10-6/°C. The BL glasses also had a higher average density of 2.88 g/cm3 and a Vickers hardness of 6.29 GPa, compared to the BP glasses, with average values of 2.74 g/cm3 and 6.06 GPa, respectively. The increase of glass melting temperature up to 1450°C tended to improve the observed properties, followed by a decrease at 1500°C. Despite the atypical glass chemistry of the two bottom ashes, they were successfully melted to produce glasses and the measured properties demonstrated suitable potential to warrant further study.

Characterization, pre-treatment, and potential applications of fine MSWI bottom ash as a supplementary cementitious material

With the development of waste recovery techniques, previous research has revealed that coarse fractions of municipal solid waste incineration (MSWI) bottom ash (BA) after proper treatment could be applied in the construction sector, while the fines are seldom recovered in practice and normally landfilled. This study explores the potential application of fine MSWI BA (0–2 mm) as a supplementary cementitious material (SCM) in Portland cement (PC) mixtures. Mechanical and chemical pre-treatment approaches have been designed with various conditions to optimize the treating process. The chemical and mineralogical compositions, as well as the metallic Al content in BA were characterized before and after the pre-treatment. It was found that both methods are effective in removing the metallic Al content in BA, Moreover, BA derived from mechanical treatment exhibited more contribution to the hydration reaction in PC mixtures, as revealed by the amount of reaction products and mineral phases formed in hardened trial mixtures. BA obtained was further partially blended in PC mortars to evaluate the performance as compared to SCMs and inert fillers. It was found that treated BA resulted in a slight retarding effect on the reaction kinetics. Treated BA behaved better than the coal fly ash to contribute to the strength development, while the inclusion of BA did not lead to significant influences on the workability.

Municipal solid waste incineration bottom ash recycling assessment: Carbon emission analysis of bottom ash applied to pavement materials

Inspired by the concept of conserving resources, bottom ash has been increasingly utilized in road construction as a readily available waste material. This study sought to address this gap by quantifying the carbon benefits associated with bottom ash application. Through a comprehensive analysis grounded in life cycle theory, author evaluated the changes in energy consumption and carbon emissions before and after the integration of bottom ash into the road construction process. The analysis employed the raw material production stages of different pavement materials as the system boundary. By determining the optimal amount of bottom ash and calculating the associated values, the study proposed an efficient application scheme for utilizing bottom ash in urban engineering construction projects. The results showed that bottom ash had the least carbon reduction effect in permeable bricks, followed by cement concrete and cement stabilized macadam mixture. The most significant effect was observed in asphalt mixtures. However, energy consumption increased with the addition of bottom ash in asphalt mixtures, whereas it decreased in the other three products. The carbon reduction after applying bottom ash was predicted based on the annual growth rate of urban road construction. Under the premise of maintaining the non-destructive application performance of asphalt mixtures, the optimal carbon reduction benefit for a 20% addition of bottom ash was approximately 17,369.9 tons. In cement-stabilized crushed stone mixtures, the optimal carbon reduction benefit ws achieved with a bottom ash content of 30%, approximately 15,797.7 tons. The practice of utilizing bottom ash in road works was significant in terms of maximising the benefits of carbon reduction.

Hydrological and geochemical properties of bottom ash landfills

In Switzerland, municipal solid waste incineration bottom ash is deposited in open landfills, which leads to its interaction with rainwater and thus the formation of a polluted leachate. This study attempts to provide a better understanding of the hydraulic and geochemical properties of bottom ash landfills by combining field and laboratory investigations. The results show that a bottom ash landfill can be described as a generally unsaturated body with several layers of different grain sizes. Three different water domains with variable hydraulic and geochemical properties were identified in the landfill: (1) zones of preferential flow, (2) a reservoir of mobile porewater, and (3) an immobile porewater reservoir. Preferential flow systems account for approximately 5–10 vol.%. The landfill layering is primarily responsible for the formation of various flow systems during heavy rainfall events. The domains and reservoirs provide variable volumetric contribution to the leachate, depending on precipitation rates and duration of dry periods. Sampling of leachate during heavy rainfall events revealed dilution effects for Na (− 59–61% compared to concentrations prior to the event), Ca (− 44–47%), Cl (− 57–77%), and SO4 (− 35–47%), while pH (+ 7–8%) and concentrations of Al (+ 368–1416%), Cu (+ 7–58%), Cr (+ 29–48%), V (+ 100–118%), and Zn (+ 289%) increased significantly. The findings of this study serve as a basis for the development of a hydrogeochemical model of a bottom ash landfill, which allows better prediction of the future evolution of leachate quality.

Utilization of Municipal Solid Waste Incineration Bottom Ash in Cement-Bound Mixtures

In order to protect the natural resources, it is beneficial for the environment when materials that are not valuable, such as waste or recycled materials, are used in engineering. This article presents laboratory studies on the use of mixtures of incineration bottom ash (IBA) from municipal waste incinerators with natural, fine grain and uniform aggregate in cement-bound layers. The mechanical and engineering properties of aggregates were studied, their usefulness was assessed and possible applications are indicated. The chemical composition of the material was found to be consistent with typical IBA from other incineration plants, and leachability studies were carried out, confirming lack of any environmental impact. The authors’ own mixtures were prepared based on optimal water content and maximal dry densities of solid particles, and the compressive strength was calculated after 7 and 28 days of hardening. The results indicate that replacing natural aggregates with IBA permits an increase in the compressive values for the specimens using the same amount of CEM I 42.5R while improving the frost resistance of cement–aggregate mixtures.