The use of magnetic nano-sized adsorbents for the removal of heavy metals from water possesses significant potential in water remediation sector. The goal of this study was to develop economically feasible magnetite nanoparticles with an appropriate surface functionalization that will simultaneously provide adsorption efficiency, hydrophilicity, and recyclability without compromising magnetic properties. Magnetite nanoparticles (MNPs) were produced via the thermal decomposition process of iron oleate precursor due to monodispersity provided by this method. The particles were coated with mesoporous silica layers by utilizing cetyltrimethylammonium bromide (CTAB) as the surfactant. The coated particles were subjected to chitosan coating by stirring in chitosan solution. The success of the coating process was confirmed by performing Fourier-transform infrared spectroscopy (FTIR) analysis between each step. The particles were used as an adsorbent in heavy metal salts solutions of known concentrations. The adsorption study was conducted with varying contact time and initial concentration and the data was analyzed for fitting to pseudo 1st order and pseudo 2nd order kinetic models, and the Langmuir and Freundlich isotherm models to determine the adsorption characteristics. The kinetic model and isotherm fitting indicted that the adsorption occurred by monolayer chemical adsorption. The developed adsorbent exhibited a satisfactory adsorption capacity of 150.33 mg/g and 126.26 mg/g for Pb2+ and Cd2+ respectively which is a good indication for further exploration and analysis.
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