Vapor Liquid Research Articles

Leidenfrost Effect-Induced Chaotic Vortex Flow for Efficient Mixing of Highly Viscous Droplets.

Efficiently mixing highly viscous liquids in microfluidic systems is appealing for green chemistry such as chemical synthesis and catalysis, but it is a long-standing challenge owing to the unfavorable diffusion kinetics. In this work, a new strategy is explored for mixing viscous droplets by harnessing a peculiar Leidenfrost state, where the substrate temperature is above the boiling point of the liquid without apparent liquid evaporation. Compared to the control experiment where the droplet stays at a similar temperature but in the contact boiling regime, the mixing time can be reduced significantly. Moreover, it is demonstrated that the liquid mixing originates from the chaotic convection flow in the Leidenfrost droplet, characterized by the internal vortex motion evidenced by the microscale visualization. A correlation between mixing time and droplet volume is also proposed, showing a good agreement with experimental results. It is further shown that Leidenfrost droplets can be used to synthesize nanoparticles of the desired morphology, and it is anticipated that this simple and scalable fabrication approach will find applications in the biological, pharmaceutical, and chemical industries.

Study of the Dynamics of a Single Bubble

The behaviour of bubbles in cavitation and boiling processes is determined by the thermodynamic parameters of the two-phase medium and the intensity of heat and mass transfer, which affect the final dynamic effects. In this review, we analyse the influences of these factors on bubble behaviour, as described in existing mathematical models. In particular, we analyse the physical processes that govern bubble behaviour, the influence of mass transfer, vapor and liquid temperature, vapour, and liquid pressure on the inertial and dynamic stages of development. In conclusion, we summarize the problems associated with modelling, the accuracy of numerical predictions, and propose directions for further research.

L-carnitine supplementation in conventional slow and ultra-rapid freezing media improves motility, membrane integrity, and fertilizing ability of dog epididymal sperm

This study aimed to assess the impact of L-carnitine (LC) supplementation in conventional-slow (CS) and ultra-rapid (UR) freezing media on post-thaw quality and fertilizing ability of dog epididymal spermatozoa. Sperm samples were collected from 60 epididymides obtained from 30 adult orchiectomized dogs via retrograde flushing. Twenty pooled sperm samples were then created (3 epididymal samples/pool). Four treatments were established according to the freezing method (CS and UR) and LC supplementation (5 and 0 mM [control, Co]): CS-LC5, CS-Co, UR-LC5, and UR-Co. The CS freezing involved exposing 0.25 mL straw to liquid nitrogen vapors (LN2), while UR freezing submerged 30-µL drops of sperm samples directly into LN2. Sperm kinematics, membrane integrity, and fertilizing ability (by heterologous in vitro fertilization using bovine oocytes) were evaluated for all treatments. Post-thaw results revealed that the CS freezing treatments resulted in significantly higher values (P < 0.05) of curvilinear and average-path velocities, and beat-cross frequency compared to the UR freezing treatments, regardless of LC supplementation. The CS-LC5 and UR-LC5 treatments cryoprotected the sperm by increasing (P < 0.05) the percentage of ‘live-sperm/intact-acrosome’ compared to their controls treatments CS-Co and UR-Co. Regarding fertilizing ability, the CS-LC5 treatment yielded a higher percentage (P < 0.05) of pronuclei formation compared to both UR treatments. The UR-LC5 treatment, however, obtained greater percentage (P < 0.05) than their control UR-Co. In conclusion, supplementation with L-carnitine in conventional-slow and ultra-rapid freezing improved sperm motility, plasma, and acrosome membranes integrity and fertilizing ability of dog epididymal spermatozoa.

Platinum-Catalyzed Silicon Nanowire Growth─Evidence for a Switch from Vapor–Liquid–Solid to Vapor–Solid–Solid Mechanism with Platinum Nanoparticle Size

Platinum-Catalyzed Silicon Nanowire Growth─Evidence for a Switch from Vapor–Liquid–Solid to Vapor–Solid–Solid Mechanism with Platinum Nanoparticle Size

Refrigerant charge influence on the performance of a transcritical CO2 system with flash-tank for low-temperature refrigeration

While the use of CO2 as a natural refrigerant become widespread, there is a scarcity of research on refrigerant charge effects in transcritical CO2 refrigeration applications, especially for systems with flash-tank and two-stage compressors. In this work, an experimental investigation of the effect of the Normalized Refrigerant Charge (NRC) on the parameters and performance of a Flash-Tank Vapor Injection (FTVI) CO2 refrigeration system is carried out. Within the explored NRC range of −0.02 to 0.247, an optimal NRC of 0.18 was identified that yields a maximum COP regardless of operating conditions. Results suggest that typical operating parameters such as temperature and pressure are not being affected by the NRC because of the charge buffering function of the flash-tank. However, the liquid–vapor separation capacity of the flash-tank causes a reduction in the refrigeration capacity when the system is not charged properly. This refrigeration capacity detriment related to undercharged conditions becomes more severe under high ambient temperatures, with a maximum COP penalty of 20 % when comparing the lowest charge versus the optimal charge performances at a gas cooler outlet temperature of 40 °C.

Fluid Phase Equilibria Carbon Dioxide + Decane + Hexadecane Ternary System

The interest in understanding reservoir fluids' phase behavior is to increase hydrocarbon production without any flow assurance issues. Due to its opacity, the evident complexity of determining phase equilibrium data revolves around the thermodynamic modeling of model systems. The article presents experimental phase equilibrium data and thermodynamic modeling for the CO2 + decane + hexadecane ternary system at 283.15, 298.15, and 323.15 K and pressures up to 20 MPa. The transitions observed during this study were liquid-liquid (LL), vapor-liquid (VL), and vapor-liquid-liquid (VLL). The Peng-Robinson equation of state was used to model this ternary system for various compositions. The temperature-dependent binary interaction parameters (kij) for the CO2 + n-alkane mixtures were adjusted to the experimental data. Additionally, a binary interaction parameter for the n-C16H34/n-C10H22 pair, independent of temperature, was obtained through the critical volume of the components. The results reveal complex behaviors as the mixture's composition of hexadecane progressively increases. Adding this longer-chain linear hydrocarbon influences the phase behavior, leading to the emergence of liquid-liquid transitions and barotropic inversion in the system. This study contributes valuable data on model systems representing crude oil, highlighting complex behaviors in ternary systems with high carbon dioxide content.

Study on the instability of FC-72 vapor–liquid interface in a rectangular channel under different gravity conditions

Study on the instability of FC-72 vapor–liquid interface in a rectangular channel under different gravity conditions

Extension of the SpK atomic physics code to generate global equation of state data

Global microphysics models are required for the modelling of high-energy-density physics (HEDP) experiments, the improvement of which are critical to the path to inertial fusion energy. This work presents further developments to the atomic and microphysics code, SpK, part of the numerical modelling suite of Imperial College London and First Light Fusion. We extend the capabilities of SpK to allow the calculation of the equation of state (EoS). The detailed configuration accounting calculations are interpolated into finite-temperature Thomas–Fermi calculations at high coupling to form the electronic component of the model. The Cowan model provides the ionic contribution, modified to approximate the physics of diatomic molecular dissociation. By utilising bonding corrections and performing a Maxwell construction, SpK captures the EoS from states ranging from the zero-pressure solid, through the liquid–vapour coexistence region and into plasma states. This global approach offers the benefit of capturing electronic shell structure over large regions of parameter space, building highly-resolved tables in minutes on a simple desktop. We present shock Hugoniot and off-Hugoniot calculations for a number of materials, comparing SpK to other models and experimental data. We also apply EoS and opacity data generated by SpK in integrated simulations of indirectly-driven capsule implosions, highlighting physical sensitivities to the choice of EoS models.

Experimental investigation on cooling characteristic of transpiration-film combined cooling structure using liquid coolant

Transpiration cooling has gained significant attention as a promising strategy for thermal protection in scramjet engines. However, this approach faces limitations due to its susceptible block in fuel gas environment and significant fluctuation when using liquid coolants. To address these challenges, this work proposes a novel transpiration-film combined cooling structure (CCS), where the lower porous layer could ensure sufficient heat transfer and the upper film-hole layer could keep impurities from blocking porous layer and enhance the mechanical strength. Experimental and theoretical investigation on the combined cooling structure with liquid coolant phase change are carried out, and the cooling efficiency, temperature uniformity and cooling chamber pressure of the combined structure are compared with those of the transpiration cooling structure (TCS). Remarkably, the combined structure effectively suppresses temperature fluctuations, reducing the amplitude of temperature variation to just 1/5 of that observed in the transpiration cooling system. Although the combined structure shows a modest 0.026 drop in time-averaged cooling efficiency, it significantly improves temperature uniformity and reduces pressure peaks within the cooling chamber. Furthermore, the flow characteristics of liquid film and vapor film are analyzed and the coolant utilization rate for vapor film is 6.4 times higher than that for liquid film. Consequently, the design of combined structures using liquid coolant holds great promise for achieving highly efficient thermal protection in scramjet engines.

Solid–Liquid and Vapor–Liquid Equilibria, Volume Properties in Water–Calcium (Magnesium) Methanesulfonate: Experimental Data and Modeling with Pitzer and Pitzer–Simonson–Clegg Formalism

Solid–Liquid and Vapor–Liquid Equilibria, Volume Properties in Water–Calcium (Magnesium) Methanesulfonate: Experimental Data and Modeling with Pitzer and Pitzer–Simonson–Clegg Formalism

Molecular modeling of cryogenic hydrogen behavior in vapor–liquid equilibria and confinement

We report the effect of Feynman–Hibbs corrections on the intermolecular potential to take into account the quantum effects of hydrogen at low temperature and high density for vapor–liquid equilibria (VLE) and confinement into carbon nanotubes. Density against temperature, pressure against temperature and isochoric curves are displayed for VLE, while adsorption isotherms for different pore sizes and different temperatures are showcased to see the effect under confinement. Besides, 5 different models for hydrogen are employed; one atomistic and 4 coarse-grained models, covering both classical and quantum approximations. For the case of VLE we observed that the quantum corrected models lead to more accurate and reliable results in good agreement with the experimental data. The adsorption isotherms produced with the different models showed that the difference between quantum and classical approximations are significant for maximum confinement (smallest pore) and lowest temperature (77K). As we increase both the temperature and the pore size, the difference between the different models become less noticeable.

Predicting three phase (hydrate–liquid–vapour) equilibria of mixed hydrates in guest gas swapping: AI‐based approach versus physical modelling

Predicting three phase (hydrate–liquid–vapour) equilibria of mixed hydrates in guest gas swapping: <scp>AI</scp>‐based approach versus physical modelling

Three-phase crystallization for purification of acrylic acid from acrylic/propionic acid mixture

A new separation technology, three-phase crystallization (TPC), was utilized to purify acrylic acid (AA) from a binary liquid mixture comprising AA and propionic acid (PA). The solid–liquid equilibrium data of AA/PA mixture reported in the literature were adopted to recover the activity coefficients of the liquid mixture; and, subsequently, the vapor–liquid equilibrium conditions of AA/PA mixture were predicted using Raoult’s law and the Wilson equations for the recovered activity coefficients. The reported solid–liquid equilibrium data and the predicted vapor–liquid equilibrium conditions were coupled to determine the three-phase transformation conditions of AA/PA mixture, which were employed to conduct the batch TPC experiments. Upon conclusion of the TPC, the yield and purity were measured to estimate the amount of the AA crystals and volume of the liquid mixture retained in the overall final product, respectively.

The characteristics of frozen-thawed rooster sperm using various intracellular cryoprotectants

Cryopreservation of rooster semen is essential for conserving genetic resources, genetic improvement, and increasing productivity. However, the nature of avian sperm presents a global issue in ensuring superior frozen semen for artificial insemination. Thus, the present study aimed to evaluate the impact of using dimethylacetamide (DMA), dimethyl sulfoxide (DMSO), and ethylene glycol (EG) as cryoprotectants on post-thawed sperm motility, quality, antioxidant indicators, and fertilizing capacity. Twice a week, fresh semen ejaculates were collected from 15 adult roosters and immediately evaluated to constitute a pool from clean and qualified samples. The pooled semen was further diluted at a ratio of 1:2 (v/v) with an extender and then subjected to a freezing protocol in a liquid nitrogen vapor after adding a cryoprotectant solution containing 6% of either DMA, DMSO, or EG, respectively. After thawing, characteristics of sperm motion, quality, antioxidants, and fertilizing ability were evaluated and compared to fresh and cooled semen as controls. The results demonstrated that semen cooling negatively affected some parameters of sperm motility, quality, antioxidant biomarkers, and fertility. In comparison to the DMSO and EG groups, employing DMA considerably (P < 0.05) raised the percentages of sperm progressive motility, viability, plasma membrane intactness, and DNA integrity. The DMA group showed a significant increase in the catalase and glutathione reduced antioxidant enzyme activity and a reduction in nitric oxide and lipid peroxidation. After artificial insemination, the DMA and DMSO groups exhibited considerably (P < 0.05) better rates of hatchability and fertility than the EG group. It is concluded that freezing extenders containing 6% DMA is better than DMSO or EG to improve the post thaw semen quality and fertility in chickens.

Experimental study on the flat loop heat pipe with minichannel wick under low heat flux

Stable operating under low heat flux condition is crucial for loop heat pipe. To investigate the performance of the flat loop heat pipe under low heat flux, a visual structure of evaporator with longitudinal replenishment characterized by minichannel wick is proposed and fabricated. The minichannel wick increases the permeable area and reduces flow resistance to enhance the heat transfer capacity. However, under low heat flux condition, excessive liquid permeation into the vapor line and the local reverse vapor flow may deplete the liquid storage in the compensation chamber, resulting in a wick temperature increase of 4.7 °C under extreme condition. Lowering the heat sink temperature does not necessarily lead to a lower stable wick temperature in specific cases but rather poses operational challenges and further raises the stable wick temperature by 9 °C. By visualizing the flow structure, it is found that arduous vapor–liquid prestart distribution leads to prolonged circulation establishment time and higher wick temperature, resulting in a higher stable wick temperature. As the heat flux increases, the effect of prestart distribution on the stable wick temperature weakens as the redistribution capability improves.

Experimental determination and theoretical modeling of isobaric vapor–liquid equilibria, liquid mass density, surface tension and dynamic viscosity for the methyl butyrate and tert-butanol binary mixture

The purpose of this work is to provide consistent experimental measurements on the vapor–liquid equilibria (VLE) at the isobaric conditions of 50.00, 75.00 and 94.00kPa, as well as experimental determinations of the liquid mass densities, the surface tensions and the dynamic viscosities at 298.15K and 101.3kPa of the methyl butyrate + tert-butanol binary system within the whole composition range. For these goals, a Gillespie-type cell is used to carry out the VLE measurements, whereas an oscillating densimeter, a maximum differential bubble pressure tensiometer, and a rotating viscometer are used to quantify the remaining physical properties. The thermodynamical quality of the reported VLE data is validated by Fredenslund’s consistency test. Based on the VLE results, this zeotropic binary mixture exhibits a positive deviation from Raoult’s law. Furthermore, the validated data are correlated with three activity coefficient models (i.e., Wilson, NRTL, and UNIQUAC), with the Wilson equation being the most accurate one. Excess volumes, surface tensions, and liquid viscosities data are correlated by Redlich–Kister-type expansions, and the Grunberg–Nissan equation is also applied to viscosity modeling. The calculated excess volumes display a positive deviation from the ideal solution model. Regarding surface tensions, this system showcases both negative and positive deviation, althouhg slight, from the linear behavior while exhibiting the linear trend at a molar fraction of methyl butyrate of 0.758. In addition, this bimodal deviation is adequately predicted by the Chunxi model with the Wilson parameters determined from the VLE data. Finally, the dynamic viscosities data obey a strictly monotonic mole dependence predicted by Eyring’s theory, although without high accuracy. These results also reflect some interesting phenomena related to competitive association effects, which are discussed.

Binary aqueous solutions of choline salts: Determination and modelling of liquid density (298.15 or 313.15 K) and Vapour Pressure Osmometry (313.15 K)

Salts composed of the cholinium cation (such as choline hydroxide and choline chloride) have become one of the main reactants for the synthesis of greener ionic liquids, but, for a proper description of the aqueous solutions of these strong electrolytes by thermodynamic modelling, reliable data on liquid density (ρ) and vapour pressure (p) are needed, which are often unavailable. So, in this work, the liquid density (ρ) of binary aqueous solutions of choline bicarbonate ([Ch][Bic]), choline (2R,3R)-bitartrate ([Ch][Bit]), choline chloride ([Ch]Cl), choline dihydrogen citrate ([Ch][H2Cit]) and choline hydroxide ([Ch]OH) were measured at 298.15 or 313.15 K and 0.1 MPa and correlated using second-degree polynomials with salt molality (m), obtaining determination coefficients (R2) higher than 0.9974. Furthermore, the osmotic coefficients (ϕ) of these binaries were determined using vapour pressure osmometry (VPO), at 313.15 K and 0.1 MPa, being satisfactorily described by the Extended Pitzer Model of Archer, which yielded low values of standard deviation (3.58<σϕ·103<12.86). Then, the mean molal activity coefficients (γ±) and excess Gibbs free energies (GE/RT) were calculated, following the order [Ch][H2Cit] > [Ch][Bit] > [Ch][Bic] > [Ch]OH > [Ch]Cl, which corresponds to the decreasing polarity of the choline salts and agrees with the empirical law of matching water affinities (LMWA).

Temperature and pressure jump coefficients at a liquid–vapor interface

The temperature and pressure jump coefficients at a liquid–vapor interface are calculated from the solution of the Shakhov kinetic model for the linearized Boltzmann equation. Complete and partial evaporation/condensation at the vapor–liquid interface are assumed as the boundary condition. The discrete velocity method is used to solve the problem numerically. The jump coefficients are tabulated as functions of the evaporation/condensation coefficient. The profiles of the vapor temperature and pressure deviations from that values at the interface corresponding to the liquid temperature and saturation pressure are plotted, and the solutions obtained from kinetic theory and continuum approach are shown to underline the effect of the jumps at the interface. The obtained results have been compared to those given by other authors, who applied the linearized Boltzmann equation as well as the model proposed by Bhatnagar, Gross, and Krook to it, and it was found that the pressure and temperature jump coefficients are relatively insensitive to the collision laws.

Artificial neural network aided vapor–liquid equilibrium model for multi-component high-pressure transcritical flows with phase change

In this work, an artificial neural network (ANN) aided vapor–liquid equilibrium (VLE) model is developed and coupled with a fully compressible computational fluid dynamics (CFD) solver to simulate the transcritical processes occurring in high-pressure liquid-fueled propulsion systems. The ANN is trained in Python using TensorFlow, optimized for inference using Open Neural Network Exchange Runtime, and coupled with a C++ based CFD solver. This plug-and-play model/methodology can be used to convert any multi-component CFD solver to simulate transcritical processes using only open-source packages, without the need of in-house VLE model development. The solver is then used to study high-pressure transcritical shock-droplet interaction in both two- and four-component systems and a turbulent temporal mixing layer (TML), where both qualitative and quantitative agreement (maximum relative error less than 5%) is shown with respect to results based on both direct evaluation and the state-of-the-art in situ adaptive tabulation (ISAT) method. The ANN method showed a 6 times speed-up over the direct evaluation and a 2.2-time speed-up over the ISAT method for the two-component shock-droplet interaction case. The ANN method is faster than the ISAT method by 12 times for the four-component shock-droplet interaction. A 7 times speed-up is observed for the TML case for the ANN method compared to the ISAT method while achieving a data compression factor of 2881. The ANN method also shows intrinsic load balancing, unlike traditional VLE solvers. A strong parallel scalability of this ANN method with the number of processors was observed for all the three test cases. Code repository for 0D VLE solvers, and C++ ANN interface—https://github.com/UMN-CRFEL/ANN_VLE.git.

A robust three-dimensional numerical model for heat transfer characteristics in sintered–grooved thin flat heat pipes

In the current research, a robust three-dimensional numerical model is developed for thin flat heat pipes (TFHPs) with a hybrid sintered–grooved wick structure. Numerical simulations for laminar incompressible flow in liquid wick and ideal gas incompressible flow in the vapor core are performed to predict temperature, pressure, and velocity profiles. The model utilized non-Darcy transport through a porous wick to determine liquid flow in the liquid-wick section. The mass flow rate of the fluid at the liquid–vapor interface is modeled using kinetic theory. Furthermore, the hybrid wick structure is modeled as an inhomogeneous porous medium. Additionally, this formulation enhances the stability and convergence of the numerical solution and accelerates the solving time. The developed model is validated with experimental data, showing very good agreement with axial wall temperatures, with a maximum error of about 2% in steady-state conditions. The numerical results, including system pressure, wall temperature, mass transfer at the liquid and vapor interface, and velocity magnitude streamlines, are investigated for a comprehensive understanding of the flow physics and performance of the hybrid wick. The results show that, at heat inputs of 5, 10, 20, and 30 W, the thermal efficiency of hybrid wick TFHP is 4.9%, 10.4%, 34.38%, and 23.3%, respectively, greater than that of the grooved wick. The TFHP with a hybrid wick indicates the best thermal efficiency at a heat input of 20 W, with a thermal resistance of 0.95 K/W.