Impedance ac diagnostics is regularly used to study the transport phenomena in conducting systems of differrent dimensionalities. A common reason for using ac methods that are more complex than dc methods is the possibility to exclude the influence on the current-voltage (I−V) characteristic of contact phenomena accompanying dc measurements. In some cases (2d electron systems over helium) dc transport measurements are impossible. In weakly doped semiconductors (diluted electrolytes), the situation is less critical, but problems with the ohmic properties of the conducting contacts remain. The analysis of the details of the formalism that determines the reaction of a conducting medium to an external disturbance depends largely on the form of Ohm’s law for a conductor introduced into the impedance circuit. If there is a reason to define this law by the formula j = σΕ, where j, σ, E correspond to local values of current density, conductivity, and transport electric field, the structure of complex resistance Z^F(ω) is considered as a force one. If there is a diffusion component in Ohm’s law then the structure of complex resistance Z^μ(ω) is considered as an electrochemical one. We describe a standard electrolytic capacitor in series RC with a step load in terms of force or complex electrochemical impedance. Comparison with experiment shows the electrochemical structure of the complex resistance.
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