Pulsed UV Laser Research Articles

Influence of defocusing of UV pulse laser radiation on LIG synthesis on Polyetheretherketone

Laser-induced graphene (LIG) technology, a technique for preparing three-dimensional porous graphene by laser direct writing on carbon precursors under ambient condition, has been widely used due to its low cost and high efficiency. However, there is still a lack of research on the influence of the defocusing on LIG synthesis. In this paper, LIG is prepared by UV laser on Polyetheretherketone (PEEK) film, and a finite element simulation of this process is established to infer the temperature field. The influence of the defocusing on the structure, morphology, specific surface area SSA, and electrical properties of PEEK-LIG is investigated while maintaining the same energy radiated per unit area. The results show that the defocusing changes the structure and morphology of PEEK-LIG by affecting the temperature field distribution in both the surface and thickness directions, which affects the properties of LIG, where the surface area ratio Sdr does not depend on the defocusing amount monotonically. As the UV laser nears the beam waist at the threshold of LIG formation, Sdr has its maximum value and improves its electrical conductivity.

Photopolymerization of Chlorpromazine-Loaded Gelatin Methacryloyl Hydrogels: Characterization and Antimicrobial Applications.

This study investigates the synthesis, characterization, and antimicrobial properties of hydrogels synthesized through the UV-pulsed laser photopolymerization of a polymer-photoinitiator-chlorpromazine mixture. Chlorpromazine was used for its known enhanced antimicrobial properties when exposed to UV laser radiation. The hydrogel was formed from a mixture containing 0.05% Irgacure 2959, 10% gelatin methacryloyl, and various concentrations of chlorpromazine (1, 2, and 4 mg/mL). Laser-induced fluorescence spectroscopy was employed to monitor the photoinduced changes of chlorpromazine and Irgacure 2959 during hydrogel formation, providing insight into the photodegradation dynamics. FTIR spectroscopy confirmed the incorporation of irradiated chlorpromazine within the hydrogel matrix, while the release profiles of chlorpromazine showed sustained release only in hydrogels containing 1 mg/mL of CPZ. The hydrogel showed significant antimicrobial activity against MRSA bacteria when compared to that of penicillin. These findings highlight the potential of CPZ loaded during the photopolymerization process into hydrogels as effective antimicrobial agents with sustained release properties, making them suitable for combating resistant bacterial strains.

Laser engineered architectures for magnetic flux manipulation on superconducting Nb thin films

Custom shaped magnetic flux guiding channels have been fabricated on superconducting Nb thin films by laser nanopatterning of their surface. Preferential pathways are defined by suitable combination of imprinted anisotropic pinning domains through laser-induced periodic surface structures (LIPSS). Generated by the selective energy deposition of femtosecond UV laser pulses, quasi-parallel ripple structures are formed under optimized irradiation conditions. On average, each domain is formed by grooves with a lateral period of 260–270 nm and a depth about 80 nm. By combination of scanning and transmission electron microscopy, magneto-optical imaging, and conductive atomic force microscopy techniques, we conclude that the boundaries of the LIPSS-covered domains play a prominent role in the magnetic flux diversion process within the film. This is confirmed by dedicated modeling of the flux dynamics, combined with the inversion of the magneto-optical signal. The created metasurfaces enable control of the flux penetration process at the microscale.

Demonstration of Capture, Cooling, Tagging, and Spectroscopic Characterization of UV Photoproduct Ions in a Cryogenic Ion Trap: Application to 266 nm Photofragment Ions from Rhodamine 6G.

We demonstrate a method to determine the structures of the primary photodissociation products from a cryogenically cooled parent ion. In this approach, a target ion is cooled by a pulse of buffer gas and tagged in a 20 K Paul trap. The cold ion is then photodissociated by pulsed (∼5 ns) UV laser excitation, and the ionic products are trapped, cooled, and tagged by introduction of a second buffer gas pulse in the same trap. The tagged fragments are then ejected into a triple focusing, UV/vis/IR time-of-flight photofragmentation mass spectrometer which yields vibrational and electronic spectra of the mass-selected photofragments. These methods are demonstrated by application to the 266 nm photodissociation of the Rhodamine 6G cation to yield the R575 fragment ion based on loss of ethene as well as to a weaker secondary fragment arising from loss of m/z 43.

22.56% total area efficiency of n-TOPCon solar cell with screen-printed Al paste

Screen-printing Ag paste on the rear side of the Tunnel Oxide Passivated Contact solar cells (TOPCon) is still the mainstream method to form electrodes. However, the high price of precious metals increases the cost of TOPCon cells. Al is a cheap and high-performance conductor, and its work function is compatible with the rear side of TOPCon cells. In this study, we used a UV pulse laser (355 nm, 10 ps) to ablate the rear side SiNx passivation layer of TOPCon cells and then printed Al paste with different weight percentages of silicon (Si-wt.%) on the phosphorus-doped polycrystalline silicon (n+-poly-Si) layer to reduce the cost. We investigated the damage mechanism of laser on SiOx/n+-poly-Si/SiNx passivation structure and the contact mechanism between Al paste and n+-poly-Si layer. The results show that the Voc of SiOx/n+-poly-Si/SiNx passivation structure reduced about 6–7 mV when the laser energy density was 0.431 J/cm2. We got the best electrical performance of TOPCon cells printed with Al paste (25 wt%-29 wt% silicon). The open-circuit voltage (Voc) and the conversion efficiency (Eff), have reached 663.60 mV and 22.56 % respectively. Although the efficiency was 9.40 % relative lower than that of TOPCon cells printed with Ag paste, but the cost of Al paste only accounted for 10 % of Ag paste. In the future, the highest Eff of TOPCon solar cells printed with Al paste on the rear side are expected to reach the commercial TOPCon based on Ag paste, which applies laser doping selective emitter technology (SE) and bifacial poly-Si passivation structure.

Solid-state laser (266 nm) as an alternative to ArF excimer laser (193 nm) for corneal reshaping: Comparative numerical study of the thermal effect.

Laser corneal reshaping is a safe and effective technique utilized to treat common vision disorders. An advanced laser delivery system equipped with a pulsed UV laser with specific parameters is used to ablate parts of the cornea surface to correct the existing refractive error. The argon fluoride (ArF) excimer pulsed gas laser at 193 nm is the most employed type in the commercial devices for such treatments. This laser is generated using a mixture of Argon, Fluorine, and a significant amount of Neon gases. However, due to the ongoing Russian-Ukraine war, the availability of Neon gas is currently very limited, as this region is considered the primary supplier of pure Neon gas. Consequently we suggest replacing the common ArF laser source in the commercial devices with a solid-state (forth harmonic neodymium-doped yttrium aluminum garnet laser at 266 nm). This replacement uses the same operation parameters, optics, and scanning algorithm. Parameters from five commercial devices (Zeiss MEL 90, Technolas TENEO 317, Alcon Wave Light EX 500, Schwind Amaris 750 s, OptoSystems MICROSCAN VISUM) were compared with those of the i-ablation device, a research device that uses a 266 nm laser source. Our goal is to reduce production costs through a simple modification that has a significant impact. Consequently, the present study aims to find an alternative laser source for the current ArF laser without exchanging the complete system's design. This recommendation is based on a numerical simulation study. The thermal effect on a human cornea model was numerically evaluated using finite-element solutions of Pennes' bioheat equation on the COMSOL platform by applying two laser wavelengths. The results demonstrated that changing the laser source significantly impacts the thermal effect, even with the same laser settings. All studied devices showed a reduction in the thermal effect to below 40°C, compared with nearly 100°C under ordinary conditions.

Characterization of the upgraded single-line-of-sight time-resolved x-ray imager using short-pulse visible and UV lasers.

The single-line-of-sight time-resolved x-ray imager (SLOS-TRXI), a fast-gated x-ray imager used for capturing x-ray self-emission in inertial confinement fusion experiments on OMEGA, has been upgraded and characterized. SLOS-TRXI combines an electron-dilation imager and a hybrid complementary metal-oxide-semiconductor (hCMOS) sensor to capture multiple gated frames on a single line of sight with a temporal resolution of ∼40ps and a spatial resolution of 10 µm. The original hCMOS sensor with four frames was replaced with a newer-generation hCMOS sensor having eight frames. Gate characterizations of both the sensor and the entire SLOS-TRXI diagnostic were performed using ∼10-ps FWHM visible (2ω) and UV (4ω) short-pulse lasers, respectively. A stepped echelon was used to generate a train of five UV laser pulses having an interpulse separation of 30 ± 3ps. Characterization results of the hCMOS gating (2.28 ± 0.02-ns FWHM on average) and a temporal resolution of the upgraded SLOS-TRXI (34 ± 4-ps FWHM on average) are presented. A temporal magnification for the electron-dilation imager between 40 and 60 was inferred from the characterization results. The spatial resolution of the upgraded SLOS-TRXI remains the same in light of this work.

Study of the Effect of UV Laser Pulse Duration and Wavelength on Fibroblasts

Study of the Effect of UV Laser Pulse Duration and Wavelength on Fibroblasts

Development Of An Endoscopic, Absorption Corrected And Calibrated OH Laser Induced Fluorescence Probe System for High Pressure Combustion Diagnostics

We present the design and preliminary results of an endoscopic OH laser-induced fluorescence (LIF) system that is capable of acquiring 1D-line measurements in high pressure combustion processes within large-scale test facilities. The system can be exploited to acquire line-of-sight OH-chemiluminescence images and absorption corrected absolute OH-species concentration from which additionally temperature distribution can be extracted in case of lean mixtures in chemical equilibrium. Different critical components, such as light guides for high power UV laser pulses and flexible UV image guides, were first tested and characterized in a laboratory setup. Optimization regarding pulse energy and beam quality led to the selection of an 1m long hollow core fiber for laser light delivery as a central element for the experimental setup despite high losses caused by bending the fiber. The image transfer is accomplished by a 7m long flexible UV image bundle, which is preferred to the use of a rigid borescope in harsh environments. We designed the endoscopic UV optics using readily available parts and achieved an approximated image resolution of 21.6 line pairs/mm. Additionally, post-processing methods, such as flat-field correction, can improve the image quality substantially and remove the pixilation effect of the fiber bundle structure nearly completely. To validate the complete system, probe-based qualitative OH-LIF measurements were performed in a well-known laminar flame of a matrix burner, which serves as a mock-up for anticipated applications in an industrial test environment with a technology readiness level (TRL) greater than 4. The final step consists of the integration of the miniaturized optics into a cooled probe system which protects the sensitive optics against the harsh environment of an aero-engine sector combustor. For this purpose, two probe systems were designed to include, on the one hand, the endoscope optics together with the fiber image bundle end tip and, on the other hand, the laser emitting and receiving system for performing an absorption measurement needed to quantify the recorded LIF signal.

Removing Metallic Lead Defects in the Surface Layer of Lead Halide Perovskite Films Using a Pulsed UV Laser for Enhancing the Performance of Perovskite Solar Cells

Removing Metallic Lead Defects in the Surface Layer of Lead Halide Perovskite Films Using a Pulsed UV Laser for Enhancing the Performance of Perovskite Solar Cells

Photochemical modification of a diamond surface using a pulsed UV laser as the energy source

The use of an excimer benchtop pulsed UV laser as the energy source for the photochemical modification of the surface of diamond films is reported. Boron-doped nanocrystalline diamond (NCD) films were deposited on Si wafers via plasma-enhanced chemical vapour deposition (PECVD). The as-deposited films were characterised by scanning electron microscopy (SEM), Raman spectroscopy, and X-ray diffraction (XRD). Following characterisation, the surfaces of the films were subjected to a photochemical reaction with 2,2,2-trifluoroethyl undec-10-enoate using two different sources of radiation: a benchtop UV lamp (254 nm) and a KrF excimer pulsed UV laser (248 nm). The photochemically treated films were characterised by contact angle measurements and X-ray photoelectric spectroscopy (XPS) using non-treated films as a control. The use of a pulsed UV laser source was shown to reduce the photochemical reaction time from several hours to a few minutes.

Application of deep UV resonance Raman spectroscopy to column liquid chromatography: Development of a low-flow method for the identification of active pharmaceutical ingredients

In this study, deep UV resonance Raman spectroscopy (DUV-RRS) was coupled with high performance liquid chromatography (HPLC) to be applied in the field of pharmaceutical analysis. Naproxen, Metformin and Epirubicin were employed as active pharmaceutical ingredients (APIs) covering different areas of the pharmacological spectrum. Raman signals were successfully generated and attributed to the test substances, even in the presence of the dominant solvent bands of the mobile phase. To increase sensitivity, a low-flow method was developed to extend the exposure time of the sample. This approach enabled the use of a deep UV pulse laser with a low average power of 0.5 mW. Compared to previous studies, where energy-intensive argon ion lasers were commonly used, we were able to achieve similar detection limits with our setup. Using affordable lasers with low operating costs may facilitate the transfer of the results of this study into practical applications.

Dynamics of phase transformations in Si and Ge upon strong excitation with UV femtosecond laser pulses

Femtosecond laser processing of semiconductors has evolved into a mature, high-precision fabrication technique, enabling a wide range of applications. While initially most studies have employed pulses at near infrared wavelengths, the interest in using UV laser pulses is constantly increasing due to the different excitation conditions as a consequence of the much shorter optical penetration depth, leading to an improved resolution. In this context, fundamental studies on the temporal dynamics of phase transformations triggered by such pulses are necessary in order to comprehend and eventually control the complex phase transformation pathways. Here, we report a detailed time-resolved study on the phase transformation dynamics of crystalline silicon and germanium upon irradiation with single 400 nm, 100 fs laser pulses in the moderate and high excitation regime. To this end, we have employed fs-resolved optical microscopy with a probe wavelength of 800 nm to study the reflectivity evolution of the irradiated surface over a temporal window ranging from 100 fs up to 20 ns. At moderate excitation fluence, the data reveals the entire sequence of laser-induced processes, starting from the generation of a free-electron plasma, non-thermal melting, ablation onset and expansion of a semi-transparent ablation layer with sharp interfaces. At excitation with peak fluences more than 30 times the ablation threshold, an anomalous transient high-reflectivity state is observed, which might be indicative of a recoil pressure-induced liquid–liquid phase transition. Moreover, 70 nm-thick amorphous surface layers are formed in both materials after irradiation at moderate fluences. Overall, our results provide relevant information on both, transformation dynamics and final state of both materials for fs-pulse excitation in the near-UV wavelength range.

TOFHIR2: the readout ASIC of the CMS barrel MIP Timing Detector

The CMS detector will be upgraded for the HL-LHC to include a MIP Timing Detector (MTD). The MTD will consist of barrel and endcap timing layers, BTL and ETL respectively, providing precision timing of charged particles. The BTL sensors are based on LYSO:Ce scintillation crystals coupled to SiPMs with TOFHIR2 ASICs for the front-end readout. A resolution of 30–60 ps for MIP signals at a rate of 2.5 Mhit/s per channel is expected along the HL-LHC lifetime. We present an overview of the TOFHIR2 requirements and design, simulation results and measurements with TOFHIR2 ASICs. The measurements of TOFHIR2 associated to sensor modules were performed in different test setups using internal test pulses or blue and UV laser pulses emulating the signals expected in the experiment. The measurements show a time resolution of 24 ps initially during Beginning of Operation (BoO) and 58 ps at End of Operation (EoO) conditions, matching well the BTL requirements. We also showed that the time resolution is stable up to the highest expected MIP rate. Extensive radiation tests were performed, both with x-rays and heavy ions, showing that TOFHIR2 is not affected by the radiation environment during the experiment lifetime.

Surface adhesion enhancement of A5052 aluminum alloy by surface texturing with a UV pulsed laser

Surface adhesion enhancement of A5052 aluminum alloy by surface texturing with a UV pulsed laser

Beam dynamics optimization for high gradient beam driven plasma wakefield acceleration at SPARC-LAB

The SPARC_LAB test facility at the LNF (Laboratori Nazionali di Frascati, Rome) holds a high brightness photo-injector used to investigate advanced beam manipulation techniques. High brightness electron bunch trains (so-called comb beams) can be generated striking on the photo-cathode of a Radio Frequency (RF) photo-injector with a ultra-short UV laser pulse train in tandem with the velocity bunching technique. Beam dynamics studies have been performed with the aim of optimizing the dynamics of the double beam (driver and witness) used to perform particle driven plasma wake field acceleration (PWFA). In this scenario different scans on beam parameters were carried on adopting the ASTRA simulation code, in order to optimize the witness beam quality and improve the plasma booster stage performances. A benchmark of the simulations has been then performed, reproducing the experimental data obtained from the optimization of machine performances, and a good agreement was found.

Highly Robust p-GaN Gate HEMT with Surge-Energy Ruggedness under Unclamped Inductive Switching and UV Pulse Laser Irradiation

Highly Robust p-GaN Gate HEMT with Surge-Energy Ruggedness under Unclamped Inductive Switching and UV Pulse Laser Irradiation

Dense plasma diagnostics with a Nomarski interferometer using a frequency-tripled Ti:sapphire laser

An overdense plasma is considered as a new tool for high-power laser pulse compression. For this purpose, a high density plasma was generated by illuminating an intense fs Ti:sapphire laser pulse onto a surface of an aluminum disk and its spatio-time-resolved dynamics was investigated by a Nomarski interferometer. To probe the laser-produced high density plasma, the original Ti:sapphire laser pulse with a wavelength of 800 nm was frequency-tripled and the UV laser pulse of 266 nm in wavelength was used in the interferometer. It turned out that the fs UV laser interferometer can provide a fairly high density information up to 8.5 × 1020 cm-3. Our experimental result shows that the initial high density plasma near the solid target surface expands rapidly and its density profile in space is gradually reduced to exponential in the ns time scale. This result will provide an important information towards the next step for experimental demonstration of the laser pulse compression using a plasma.

Pulsed-Laser-Triggered Piezoelectric Photocatalytic CO2 Reduction over Tetragonal BaTiO3 Nanocubes.

The recombination of photoinduced carriers in photocatalysts is considered one of the biggest barriers to the increase of photocatalytic efficiency. Piezoelectric photocatalysts open a new route to realize rapid carrier separation by mechanically distorting the lattice of piezoelectric nanocrystals to form a piezoelectric potential within the nanocrystals, generally requiring external force (e.g., ultrasonic radiation, mechanical stirring, and ball milling). In this study, a low-power UV pulsed laser (PL) (3W, 355nm) as a UV light source can trigger piezoelectric photocatalytic CO2 reduction of tetragonal BaTiO3 (BTO-T) in the absence of an applied force. The tremendous transient light pressure (5.7 × 107 Pa, 2.7W) of 355nm PL not only bends the energy band of BTO-T, thus allowing reactions that cannot theoretically occur to take place, but also induces a pulsed built-in electric field to determine an efficient photoinduced carrier separation. On that basis, the PL-triggered piezoelectric photocatalytic CO2 reduction realizes the highest reported performance, reaching a millimole level CO yield of 52.9mmol g-1 h-1 and achieving efficient photocatalytic CO2 reduction in the continuous catalytic system. The method in this study is promising to contribute to the design of efficient piezoelectric photocatalytic reactions.

Mass-selected ion-molecule cluster beam apparatus for ultrafast photofragmentation studies.

We describe an apparatus for investigating the excited-state dissociation dynamics of mass-selected ion-molecule clusters by mass-resolving and detecting photofragment-ions and neutrals, in coincidence, using an ultrafast laser operating at high repetition rates. The apparatus comprises a source that generates ion-molecule clusters, a time-of-flight spectrometer, and a mass filter that selects the desired anions, and a linear-plus-quadratic reflectron mass spectrometer that discriminates the fragment anions after the femtosecond laser excites the clusters. The fragment neutrals and anions are then captured by two channeltron detectors. The apparatus performance is tested by measuring the photofragments: I-, CF3I-, and neutrals from photoexcitation of the ion-molecule cluster CF3I·I- using femtosecond UV laser pulses with a wavelength of 266nm. The experimental results are compared with our ground state and excited state electronic structure calculations as well as the existing results and calculations, with particular attention to the generation mechanism of the anion fragments and dissociation channels of the ion-molecule cluster CF3I·I- in the charge-transfer excited state.