The possible presence of atomic chlorine in the upper atmosphere of Venus is examined. It is suggested that a Cl abundance as low as 2 ppm will be readily detectable in far ultraviolet via 1351.7 and 1335.7 Å emissions of neutral Cl atoms. These transitions can be resonantly excited by the bright solar emission line of C+, at 1335.7 Å. It is particularly interesting to investigate atomic chlorine since the bright 1356 Å emission feature which was reported by Rottman and Moos (1973) in the Venus spectra could not be explained without requiring high concentrations of atomic oxygen. From these data, a spectroscopic upper limit of 10−4 is deduced for the mixing ratio of Cl atoms at 125 km altitude. Although we cannot justify such a large mixing ratio, it may not be unreasonable considering the uncertainties in the present understanding of chlorine photochemistry on Venus.
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