A prerequisite for the development of quantitative ultrasonic-inspection techniques for surface flaws is a thorough understanding of the ways in which elastic waves interact with defects. Analytical and numerical approaches are presently inadequate. Experimental methods are needed for a better understanding of wave interactions with real geometries. This paper describes how dynamic photoelasticity was used to study the interaction between Rayleigh waves and slots. To fully interpret the interactions between an incident Rayleigh wave and a surface slot, the problem was subdivided as follows: first, the reflections and mode conversions of a Rayleigh wave at a corner were studied. This simulated the Rayleigh-wave interaction with a slot opening. Then, the interaction when a Rayleigh wave ran off the tip of a slot was observed, and, finally, the total interaction with slots perpendicular to the surface was studied. The results for these three cases are presented. It is suggested that the most important property of a Rayleigh wave that can be used to size surface and near-surface defects is the subsurface particle motions. These motions persist up to a depth of the order of a wavelength. The shape (that is, the frequency spectrum of the transmitted wave) should, therefore, be affected by the depth of the slot. Spectroscopic analysis is applied to the photoelastic data to develop a simple method for sizing slots. Results from ultrasonic tests on slots in steel confirm the validity of the suggested method. By applying contemporary concepts of signal processing to photoelastic data, a powerful new area of experimental investigation is introduced. It promises to overcome the current inability of scatter theories to predict the interactions between real-life defects and acoustic waves as used in ultrasonic testing. Applications of this approach will improve the quantitative ability of ultrasonic-inspection methods.