Transition Band Research Articles

Examination of structural and spectrophotometric optical characteristics of nano-like flower quinolinyl carbonyl pyrazole-1-carbodithioate films: a new trend for optoelectronic applications

The current investigation entailed the synthesis of benzyl 5-amino-4-[(1-ethyl-4-hydroxy-2-oxo-1,2-dihydroquinolin-3-yl)carbonyl]-1H-pyrazole-1-carbodithioate (referred as BAEHQP, compound 2) from 6-ethyl-4,5-dioxo-5,6-dihydro-4H-pyrano[3,2-c]quinoline-3-carbonitrile (compound 1), followed by its characterization in nanocrystalline thin films produced through thermal evaporation in a high vacuum. Computational and experimental methodologies were employed for this purpose. Density functional theory (DFT) calculations using the B3LYP/6-311++G(d,p) basis set were utilized to predict the HOMO-LUMO gap and evaluate the global reactivity descriptors, elucidating the chemical hardness, kinetic stability, and electron-donating capabilities. X-ray diffraction (XRD) analysis verified the presence of a polycrystalline structure in the BAEHQP powder and indicated an amorphous nature in the thin film. Utilizing the Williamson-Hall formula, the mean crystallite size and microstrain were determined to be 63.36 nm and 0.00667, respectively. Scanning electron microscopy corroborated the nanoflower-like structure, and particle size analysis was conducted to determine the size distribution. The optical properties, encompassing both linear and nonlinear aspects, of BAEHQP thin film were investigated using spectrophotometric methods, delineating band transitions and identifying a fundamental direct energy gap of 2.2 eV. The distinct attributes of thin-film absorption and dispersion were outlined, and the unanticipated findings hold potential implications for advancing the industrialization of photodiode device manufacturing.

Optoelectronic Response to the Fluor Ion Bond on 4-(4,4,5,5-Tetramethyl-1,3,2-dioxoborolan-2-yl)benzaldehyde.

Boronate esters are a class of compounds containing a boron atom bonded to two oxygen atoms in an ester group, often being used as precursors in the synthesis of other materials. The characterization of the structure and properties of esters is usually carried out by UV-visible, infrared, and nuclear magnetic resonance (NMR) spectroscopic techniques. With the aim to better understand our experimental data, in this article, the density functional theory (DFT) is used to analyze the UV-visible and infrared spectra, as well as the isotropic shielding and chemical shifts of the hydrogen atoms 1H, carbon 13C and boron 11B in the compound 4-(4,4,5,5-tetramethyl-1,3,2-dioxoborolan-2-yl)benzaldehyde. Furthermore, this study considers the change in its electronic and spectroscopic properties of this particular ester, when its boron atom is coordinated with a fluoride anion. The calculations were carried out using the LSDA and B3LYP functionals in Gaussian-16, and PBE in CASTEP. The results show that the B3LYP functional gives the best approximation to the experimental data. The formation of a coordinated covalent B-F bond highlights the remarkable sensitivity of the NMR chemical shifts of carbon, oxygen, and boron atoms and their surroundings. Furthermore, this bond also highlights the changes in the electron transitions bands n → π* and π → π* during the absorption and emission of a photon in the UV-vis, and in the stretching bands of the C=C bonds, and bending of BO2 in the infrared spectrum. This study not only contributes to the understanding of the properties of boronate esters but also provides important information on the interactions and responses optoelectronic of the compound when is bonded to a fluorine atom.

Photonics of Hydrothermally Treated β‐Lactoglobulin Amyloids

Increased temperature and high pressure are applied to β‐lactoglobulin fibrils in the autoclave, resulting in the acquisition of a composite material comprised of partially disassembled amyloid fibrils and carbon dots. Confirmation of the preservation of the β‐sheet motif attributed to amyloids in the hydrothermally treated fibrils is obtained through wide‐angle X‐ray scattering and ThT assay. Z‐scan analysis reveals a two‐photon absorption (2PA) enhancement in the low‐lying transition band (La) of tyrosine, while quantum chemical calculations demonstrate a correlation between the yield of 2PA and the interspace distance between aromatic residues. Overall, the intrinsic optical properties of amyloid fibrils treated in a subcritical water environment are found to be linked with the π‐conjugation of tyrosine units and their through‐space coupling. The resulting composite material is employed as a coating for a commercial ultraviolet light‐emitting diode lamp, showcasing the potential utility of sustainable biomaterials with improved optical properties for photonics applications.

Non-Invasive Hemodynamic Monitoring System Integrating Spectrometry, Photoplethysmography, and Arterial Pressure Measurement Capabilities.

Minimally invasive and non-invasive hemodynamic monitoring technologies have recently gained more attention, driven by technological advances and the inherent risk of complications in invasive techniques. In this article, an experimental non-invasive system is presented that effectively combines the capabilities of spectrometry, photoplethysmography (PPG), and arterial pressure measurement. Both time- and wavelength-resolved optical signals from the fingertip are measured under external pressure, which gradually increased above the level of systolic blood pressure. The optical channels measured at 434-731 nm divided into three groups separated by a group of channels with wavelengths approximately between 590 and 630 nm. This group of channels, labeled transition band, is characterized by abrupt changes resulting from a decrease in the absorption coefficient of whole blood. External pressure levels of maximum pulsation showed that shorter wavelengths (<590 nm) probe superficial low-pressure blood vessels, whereas longer wavelengths (>630 nm) probe high-pressure arteries. The results on perfusion indices and DC component level changes showed clear differences between the optical channels, further highlighting the importance of wavelength selection in optical hemodynamic monitoring systems. Altogether, the results demonstrated that the integrated system presented has the potential to extract new hemodynamic information simultaneously from macrocirculation tomicrocirculation.

Polarity-driven distribution of the non-aqueous tear components during microdesiccation on flat glass surfaces

Spontaneous desiccation of microvolumes of tear from a healthy subject on flat glass surfaces produces highly reproducible supramolecular structures called tear microdesiccate. In the process, non-aqueous tear components organize four main radially distributed morphological domains (zones I, II, III, and transition band or TB) through non-well understood mechanisms. Tear lipids have been located in the outermost domains (ZI, TB), thus suggesting that tear components in microdesiccate are partitioned according to electric polarities. Using a combination of dark-field and contrast phase transmitted-light microscopy, we have now studied the impact on preformed tear microdesiccate of a series of six small-sized monohydric alcohols (methanol, ethanol, n-propanol, n-butanol, n-pentanol, 2-propanol; C1 through I-C3) ranked according to polarity index (P.I. 0.762–0.546). Water (P.I. 1.000) served as control. The study aimed to assess the influence of the electric polarity of the alcohols on the organization of the microdesiccate domains.The study revealed self-assembly as a mechanism underlying formation of the entire microdesiccate as shown by the fully disruptive effect of water on preformed tear microdesiccate and their reorganization following a new desiccation cycle. Devastating effects of the most polar alcohol in the assay (methanol) were observed particularly on the centermost domain (zone III), and secondarily on zone II. Contrarily, the less polar alcohols (C2 to C5) showed both fixative effects on crystalloids of ZII and ZIII and differential unveiling of filamentous structures in ZI and TB probably due to selective extraction of lipid-like components from these latter two domains. Those effects on microdesiccate from different subjects were highly reproducible, thus supporting the view that these tear specimens bear a common design.Microdesiccates from normal tears produced on flat glass surfaces are self-assembled structures based on a design including a radial gradient of charge polarities spanning from the lipid-rich outermost hydrophobic domain (ZI) to the centermost hydrophilic fern-like crystalloid-rich domain (ZIII).

Induced ferromagnetism in Ni(II) doped ZnO monolayers via Al co-doping and their optical characteristics: ab initio study

For applications in magneto-electronic devices, diluted magnetic semiconductors (DMSs) usually exhibit spin-dependent coupling and induced ferromagnetism at high Curie temperatures. The processes behind the behavior of optical emission and ferromagnetism, which can be identified by complicated microstructural and chemical characteristics, are still not well understood. In this study, the impact of Al co-doping on the electronic, optical, and magnetic properties of Ni(II) doped ZnO monolayers has been investigated using first principles calculations. Ferromagnetism in the co-doped monolayer is mainly triggered by the exchange coupling between the electrons provided by Al co-doping and Ni(II)-d states; therefore, the estimated Curie temperature is greater than room temperature. The spin–spin couplings in mono-doped and co-doped monolayers were explained using the band-coupling mechanism. Based on the optical study, we observed that the Ni-related absorption peak occurred at 2.13–2.17 eV, showing a redshift as Ni concentrations increased. The FM coupling between Ni ions in the co-doped monolayer may be responsible for the reduction in the fundamental band gap seen with Al co-doping. We observed peaks in the near IR and visible regions of the co-doped monolayer, which improve the optoelectronic device’s photovoltaic performance. Additionally, the correlation between optical characteristics and spin–spin couplings has been studied. We found that the Ni(II)’s d–d transition bands or fundamental band gap in the near configuration undergoes a significant shift in response to AFM and FM coupling, whereas in the far configuration, they have a negligible shift due to the paramagnetic behavior of the Ni ions. These findings suggest that the magnetic coupling in DMS may be utilized for controlling the optical characteristics.

Photocatalytic Enhancement for CO2 Reduction Using Au Nanoparticles Supported on Fe‐Doped SrTiO3−δ Perovskite

This study focuses on the use of Au nanoparticles supported on the SrTiO3−δ perovskite doped with Fe ions as a photocatalyst for CO2 reduction and methanol production using water as the hydrogen supplier. The photocatalytic evaluation of the synthesized materials shows that Au nanoparticles supported on the SrTi(1−x)FexO3−δ perovskites can enhance photocatalytic CO2 reduction. The sample with the doping level x = 0.125 has the highest methanol production, 9.5 times more than the undoped sample and 3.5 times more than its counterpart without Au nanoparticles. The results of the DFT + U calculations show that the contributions from the iron atoms states reduce the energy gap in the perovskite composite, SrTi(1−x)FexO3−δ. Additionally, Fe incorporation endows the system with the capacity to create electron–hole pairs via direct band transitions at the high‐symmetry point R with the doping levels of x = 0.125 and x = 0.250.

Production and Characterization of Electrodeposited Cadmium Sulfide Semiconductor Films with Different Boron Content

AbstractIn this study, Cadmium Sulfide (CdS) semiconductor films are electrodeposited on Indium Tin Oxide (ITO) substrates at 80 °C base temperature for different boric acid (H3BO3) ratios. The effect of boric acid on these films is investigated. For this, first of all, the structural change of the films is examined. Among the films obtained with different boric acid ratios, the optimum film is achieved with 0.06 m boric acid doped. From the basic absorption spectra (αhʋ) of the obtained CdS:B films, the variation of hʋ is drawn and it is determined that the CdS:B semiconductor films has a direct band transition. From the basic absorption spectra of the obtained CdS:B films, it is observed that the CdS:B semiconductor films has a direct band transition. In addition, the optical energy bandgap values obtained are in agreement with the values in the available literatures. The results of the structural, optical, and morphological properties of the films produced in this study indicate that among the selected additive ratios, 1% boric acid gives the best and optimum deposition condition. The thin films obtained are also found to be useful as absorber layers in photovoltaic solar cells.

Improved accuracy and robustness of electron density profiles from JET's X-mode frequency-modulated continuous-wave reflectometers.

JET's frequency-modulated continuous wave (FMCW) reflectometers have been operating well with the current design since 2005, and density profiles have been automatically calculated intershot since then. However, the calculated profiles had long suffered from several shortcomings: poor agreement with other diagnostics, sometimes inappropriately moving radially by several centimeters, elevated levels of radial jitter, and persistent wriggles (strong unphysical oscillations). In this research, several techniques are applied to the reflectometry data analysis, and the shortcomings are significantly improved. Starting with improving the equilibrium reconstruction that estimates the background magnetic field, adding a ripple correction in the reconstructed magnetic field profile, and adding new inner-wall reflection positions estimated through ray-tracing, these changes not only improve the agreement of reconstructed profiles to other diagnostics but also solve density profile wriggles that were present during band transitions. Other smaller but also persistent wriggles were also suppressed by applying a localized correction to the measured beat frequency where persistent oscillations are present. Finally, the burst analysis method, as introduced by Varela etal. [Nucl. Fusion 46 S693 (2006)], has been implemented to extract the beat frequency from stacked spectrograms. Due to the strong suppression of spurious reflections, the radial jitter that sometimes would span several centimeters has been strongly reduced. The stacking of spectrograms has also been shown to be very useful for stacking recurring events, like small gas puff modulations, and extracting transport coefficients that would otherwise be below the noise level.

Sunlight driven photocatalytic degradation of organic pollutants by solvothermally synthesized rGO-BiVO4 nanohybrids

This study reports photocatalytic degradation of organic dyes by rGO-BiVO4 nanohybrids. rGO- BiVO4 nanohybrids were solvothermally prepared with different rGO loading (1.5, 3 and 6 %) and their structural, optical and photocatalytic properties were investigated. Effect of rGO loading on photocatalytic dye degradation was studied and the factors responsible were analyzed. Structural analysis was done using XRD and Raman analyses which clearly showed monoclinic phase of the BiVO4. FESEM images showed sub-micron spheres of BiVO4 along with sheet-like structures corresponding to rGO. A slight change in the band gap was observed from 2.2 eV for BiVO4 to around 2 eV for the rGO-BiVO4 nanohybrids. Band to band transitions as well as the transitions from the defect bands were observed from the PL spectra. Photocatalytic degradation studies of organic pollutant MB under natural sunlight showed 3 % rGO-BiVO4 to be the best photocatalyst which degraded 88.4 % of MB in 80 min with rate constant of 0.0244 min−1. It was observed that for obtaining a maximum catalytic efficiency an optimum loading of rGO proved to be best. In either case of higher or lower loading of rGO showed a lower degradation performance. Amongst the samples synthesized 3 % rGO loading was found to be the optimum rGO loading to have the lowest band gap (2 eV) as well as the reduced recombination that has resulted in highest photocatalytic efficiency under solar irradiation.

Transformation from MoO3 into MoS2: Experimental study on phase transition and energy band modulation

The transformation of MoO3 into MoS2 is investigated by sulfurizing MoO3 on sapphire at various temperatures. The amorphous MoO3 are crystallized at 500 ℃ and then sulfurized from 500 ℃ to 900 ℃. The phase transition occurs as the temperature increases, from MoO3 to S- doped MoO3 at 500 ℃, mixture of MoO3 and MoS2 at 600 ℃, O- doped MoS2 at 700 ℃, ideal stoichiometric ratio of MoS2 at 800 ℃, and S- deficient MoS2 at 900 ℃, respectively. Correspondingly, the work function is significantly modulated from 4.68 eV for MoO3 to 3.90 eV for MoS2, and the band gap energy decreases from 3.08 eV to 1.00 eV gradually, which are fairly consistent with the theoretical predictions. The contacts between titanium and S- doped MoO3, or the mixture of MoO3 and MoS2, are ohmic- like contacts with specific contact resistivities of 2.68 × 10-3 Ω•cm2 and 3.14 × 10-3 Ω•cm2. While the contacts between Ti and O- doped MoS2, ideal stoichiometric ratio of MoS2, or S- deficient MoS2 are Schottky contacts with barrier heights of 0.22 eV, 0.43 eV and 0.45 eV, respectively. Those results demonstrate that temperature plays pivotal role in determining the phase of sulfurized MoO3 and their properties.

The infrared absorption spectrum of phenylacetylene and its deuterated isotopologue in the mid- to far-IR.

Anharmonicity strongly influences the absorption and emission spectra of polycyclic aromatic hydrocarbon (PAH) molecules. Here, IR-UV ion-dip spectroscopy experiments together with detailed anharmonic computations reveal the presence of fundamental, overtone, as well as 2- and 3-quanta combination band transitions in the far- and mid-infrared absorption spectra of phenylacetylene and its singly deuterated isotopologue. Strong absorption features in the 400-900 cm-1 range originate from CH(D) in-plane and out-of-plane wags and bends, as well as bending motions including the C≡C and CH bonds of the acetylene substituent and the aromatic ring. For phenylacetylene, every absorption feature is assigned either directly or indirectly to a single or multiple vibrational mode(s). The measured spectrum is dense, broad, and structureless in many regions but well characterized by computations. Upon deuteration, large isotopic shifts are observed. At frequencies above 1500 cm-1 for d1-phenylacetylene, a one-to-one match is seen when comparing computations and experiments with all features assigned to combination bands and overtones. The C≡C stretch observed in phenylacetylene is not observed in d1-phenylacetylene due to a computed 40-fold drop in intensity. Overall, a careful treatment of anharmonicity that includes 2- and 3-quanta modes is found to be crucial to understand the rich details of the infrared spectrum of phenylacetylene. Based on these results, it can be expected that such an all-inclusive anharmonic treatment will also be key for unraveling the infrared spectra of PAHs in general.

Precision Measurement of Vibrational Quanta in Tritium Hydride.

Saturated absorption measurements of transitions in the (2-0) band of radioactive tritium hydride are performed with the ultrasensitive noise-immune cavity-enhanced optical-heterodyne molecular spectroscopy intracavity absorption technique in the range 1460-1510nm. The hyperfine structure of rovibrational transitions of tritium hydride, in contrast to that of hydrogen deuteride, exhibits a single isolated hyperfine component, allowing for the accurate determination of hyperfineless rovibrational transition frequencies, resulting in R(0)=203 396 426 692(22) kHz and R(1)=205 380 033 644(21) kHz. This corresponds to an accuracy 3 orders of magnitude better than previous measurements in tritiated hydrogen molecules. Observation of an isolated component in P(1) with reversed signal amplitude contradicts models for line shapes in hydrogen deuteride based on crossover resonances.

Synthesis and structural characterization of CaMg0.5CoxNi0.5-xSi2O6 (0 ≤ x ≤ 0.5) solid solutions as a colouring substance

In this study, CaMg0.5CoxNi0.5-xSi2O6 (0.0 ≤ x ≤ 0.5) solid solutions with a diopside structure were prepared to reduce the cobalt and nickel amounts compared to M2SiO4 or MgMSiO4 (M = Co, Ni) compounds or CaCoxNi1-xSi2O6 solid solutions. Colloidal gels were obtained by adding an ammonia aqueous solution to the suspensions of precursors in aqua until pH = 10. Diopside structure began to develop at 800 °C and at 1000–1200 °C crystallinity and pink colour of materials (x ≠ 0) are optimal. In both CaMg0.5CoxNi0.5-xSi2O6 (0.0 ≤ x ≤ 0.5) and MgCoxNi1-xSiO4 (0.0 ≤ x ≤ 1.0) solid solutions with diopside and olivine structures the position of the third transition of octahedral Co(II), 4T1 → 4T1(P), is centred into the green absorption range and the observed colour is pink. A higher red amount in diopside than in olivine structure can be explained by the minor width of band of this third transition (minor distortion of octahedral M1 site) and shorter mean M1-O distances (M = Ni, Co).

Theoretical study of valence excitations in fluoromethanes by high energy electron impact

We report a theoretical study of the electron-impact electronic excitation of fluoromethanes. Generalized oscillator strengths (GOSs) are calculated for the molecules at the equation-of-motion coupled-cluster singles and doubles level. To clarify the influence of nuclear dynamics on the electronic excitations, the effects of internal molecular vibrations are included in the calculation. Comparison with experimental data resolves some inconsistencies in the assignment of the transition bands. Furthermore, it is shown that the lengthening of the CH bond enhances the excitation from the highest occupied orbital to the 3s Rydberg orbital for CHF3, CH2F2, and CH3F, and that the CH stretching vibrations thus have a significant influence, especially at small momentum transfer where electric dipole transitions are dominant. Since the 2 1A1 state of CHF3 dissociates into CF3 + H, the result indicates that the CH stretching vibration causes an increase in the production of CF3 by electron collision and by photoabsorption.

First detection and absolute transition frequencies in the (3-0) band of D2.

Three electric quadrupole transitions in the second overtone band of D2 are newly measured by comb-referenced cavity ring down spectroscopy around 1.18 µm. These extremely weak transitions (line intensities smaller than 10-29 cm/molecule) are the first to be detected in the (3-0) band of D2. The spectra of the O(3), O(2), and Q(2) lines near 8321, 8446, and 8607cm-1, respectively, are recorded at room temperature for pressure values ranging between 100 and 600 Torr. Accurate transition frequencies and line intensities of the three D2 transitions are determined from a line fitting procedure using beyond-Voigt profiles, including strong Dicke narrowing. Considering statistical fit errors and possible biases due to the interference with water lines (which are six orders of magnitude stronger than the studied D2 lines), total uncertainties on the frequencies extrapolated at zero pressure are estimated below 14MHz (∼4.7 × 10-4cm-1). The derived experimental frequencies and intensities are compared to abinitio values. An overall agreement is achieved, confirming the positional accuracy of the most advanced theoretical calculations.

Adjusting UV-Vis Spectrum of Alizarin by Insertion of Auxochromes.

First synthesized in 1868, alizarin became one of the first synthetic dyes and was widely used as a red dye in the textile industry, making it more affordable and readily available than the traditional red dyes derived from natural sources. Despite extensive both experimental and computational analyses on the electronic effects of substituents on the shape of the visible spectrum of alizarin and alizarin Red S, no previous systematic work has been undertaken with the aim to fine tune the dominant absorption region defining its color by introducing other electron-withdrawing or electron-donor groups. For such, we have performed a comprehensive study of electronic effects of substituents in position C3 of alizarin by means of a time dependent DFT approach. These auxochromes attached to the chromophore are proven to alter both the wavelength and intensity of absorption. It is shown that the introduction of an electron-donor group in alizarin causes the transition bands to be significantly red-shifted whereas electron-withdrawing groups cause a minor blue-shifting.

Ho3+ -doped BaGd2 ZnO5 green-emitting phosphor for solid-state lighting: synthesis, characterization, and photoluminescence properties.

In this work, we present the synthesis of a green-emitting series of BaGd2 ZnO5 :xHo3+ (0.5-3mol%) phosphors using a high-temperature solid-state reaction method. Phase purity and crystal structure information were evaluated through X-ray powder diffraction patterns. Optical properties were examined through diffuse reflectance spectra, revealing that the prepared phosphor exhibited a band gap of 4.65 eV. The effect of Ho3+ doping on the morphology and ion distribution on the surface was assessed using scanning electron microscopy and time-of-flight secondary ion mass spectrometry techniques, respectively. The excitation spectra of the synthesized phosphor exhibited a charge transfer band and strong absorption transitions. The emission spectra displayed typical holmium emission characteristics, featuring a strong green emission band associated with f-f transitions from 5 F4 + 2 S2 → 5 I8 . Decay dynamics of the synthesized phosphor exhibited a single-exponential decay pattern, with lifetimes ranging from 0.103 to 0.053 ms. The intrinsic radiative lifetime, calculated through Auzel's fitting was determined to be 0.14 ms. Using the emission spectra, colorimetric behaviour was analyzed, revealing that the Commission Internationale de l'éclairage (CIE) coordinates exclusively lay within the green region at (0.285, 0.705), with an impressive colour purity of 99.6%. Given these marked properties, the synthesized phosphor exhibits great potential for a wide range of green-emitting applications, including displays, white light-emitting diodes, and security signage.

High-Order Wideband Band-Pass Miniaturized Frequency-Selective Surface with Enhanced Equivalent Inductance

To extend the wideband performance of high-order band-pass filtering applications, optimized designs with knitted structures based on traditional miniaturized frequency-selective surfaces (FSSs) are proposed in this paper. The presented miniaturized FSSs consist of multiple metallic capacitive layers, knitted inductive layers, and substrates. In contrast to the conventional high-order miniaturized FSSs composed of metallic frames, patches, and substrates, the optimized miniaturized FSSs replace the original metallic wire frames with knitted structures. Both proposed modified miniaturized FSSs achieve a flat pass-band from 5.5 GHz to 10.3 GHz with a 3 dB bandwidth of 71.6% under vertical incidence. The unit cells have dimensions of 0.16 λ0 × 0.16 λ0 × 0.284 λ0 and 0.16 λ0 × 0.16 λ0 × 0.279 λ0, respectively, where λ0 is the free space wavelength at 7.9 GHz, which is the center frequency of the operating band. Numerical simulations and measurements demonstrate that the proposed modified miniaturized FSSs exhibit excellent wideband performance with clean transition bands around the pass-band during oblique incidence and are suitable for applications such as radomes, where wideband filtering is essential for covering multi-band functions of radar or communication instruments.

Optical, electrical, and structural properties of polyethylene oxide/fullerene nanocomposite films

Polyethylene oxide (PEO)/fullerene (C60) nanocomposite films were synthesized through a solution mixing and casting method. The influence of increasing C60 concentration on thermal stability is evident in thermogravimetric analysis (TGA) profiles. TGA is employed to assess the thermal stability of polyethylene oxide (PEO) films, revealing a gradual weight loss below 200°C and pronounced degradation between 200°C and 500°C. PEO films doped with C60 improve their stability, with the 8 wt% C60 film retaining 40 wt% of its initial weight at 425°C—four times greater than the 1 wt% C60 film. XRD patterns exhibit a progressive reduction in crystallinity, decreasing from 52% to 38% with higher C60 content. Furthermore, C60 introduction leads to a reduced transmittance in the visible region, a redshift in the band edge, indicative of decreasing bandgap energy from 3.95 eV to 3.59 eV. Overlapping absorption bands in the extinction coefficient spectra (490 nm–620 nm) corresponded to π-π* and n-π* transition bands of C60. The electrical conductivity of PEO/C60 nanocomposite films demonstrate a substantial increase directly proportional to C60 concentration, reaching approximately 200-fold the conductivity of undoped PEO (2.28 × 10−6) at 8 wt% (1.11 × 10−4 S cm−1).