Changes In Topography Research Articles

Fabrication of novel glutathione-Fe3O4-loaded/activated carbon encapsulated sand bionanocomposites for enhanced removal of diethyl phthalate from aqueous environment in a vertical flow reactor

The extensive use of plasticizers in various industries has made Diethyl phthalate (DEP), a serious threat to the environment and ecological water security, owing to its complex-structure and low-biodegradability. Thus, the present study aimed to design a sustainable sand-coated nano glutathione (GSH) -Fe3O4-loaded/activated carbon (AC) bionanocomposite (AC-GSH-Fe3O4@sand bionanocomposite) for effective removal of DEP from water. Characterization results suggested bionanocomposites' rough and irregular texture due to the uneven distribution of AC and Fe3O4 nanoparticles over the sand. The XRD spectra indicated high crystallinity of bionanocomposites, while the FTIR spectra confirmed the presence of all individual components, i.e., GSH, AC, Fe3O4, and sand. EDX-mapping, AFM, and TGA further verified its elemental composition, topographical changes and thermal stability. The influence of pH (3, 7, 9), bed height (2, 4, 6) cm, and flow rate (2.5, 3.5, 4.5) mL min−1 were studied in a dynamic system with an initial DEP concentration of 50 mg L−1 to investigate the removal behavior of the bionanocomposites. The best DEP removal efficiency (90.18 %) was achieved over 28-h at pH 9, bed-height-4 cm, and flow-rate-3.5 mL min−1, with an optimum qmax-200.25 mg g−1 as determined through Thomas-model. Breakthrough curves were predicted using various column models, and the corresponding parameters essential for column-reactor process design were calculated. The high reusability up to the 10th cycle (≥83.32%) and the effective treatment in complex matrices (tap-water: 90.11 %, river-water: 89.72 %, wastewater: 83.83%) demonstrated bionanocomposites’ prominent sustainability. Additionally, the production cost at 6.64 USD per Kg, underscores its potentiality for industrial application. Phytotoxicity assessment on mung-bean revealed better root (5.02 ± 0.27 cm) and shoot (17.64 ± 0.35 cm) growth in the bionanocomposite-treated DEP samples over the untreated samples. Thus, AC-GSH-Fe3O4@sand bionanocomposites could be considered a highly-sustainable, low-cost technique for the effective removal of DEP and other phthalate-esters from contaminated matrices.

Analysis on the Response of Land Use/Land Cover and Ecological Service Value to Topographic Changes in the Mountainous Areas of Southwest China

Analysis on the Response of Land Use/Land Cover and Ecological Service Value to Topographic Changes in the Mountainous Areas of Southwest China

Assessing sandbar morphology in the Nakdong River Estuary using SPOT series satellite imagery

This study assessed sandbar-topography changes in Nakdong River Estuary. The island shorelines in the study area, including Jinwoo Island, Shinja Island, and Doyo Sandbar, were analyzed using SPOT satellite images from 2006 to 2022. Shoreline analysis via ArcGIS revealed that Jinwoo Island is expanding at 6.46 m/year towards Nulcha Island. Shinja Island’s western side is expanding at 4.76 m/year, while the eastern side is retreating at 24.41 m/year. Doyo Sandbar’s southern shoreline is retreating at 14.69 m/year, with a gradual decrease in speed. Significant topographical changes indicate that the interlinked barrier islands are undergoing deposition and erosion, altering the shoreline.

Patterns and controls of topographic change within the deflation basins of a trough and bowl coastal blowout

AbstractIn North‐West Europe and throughout the world, dune systems are increasingly stabilised by vegetation, due to both human intervention and changes in climate. Blowouts are erosional hollows produced by wind erosion in vegetated or semi‐vegetated dune systems. Where active blowouts are present in vegetated dunes, they provide a source of dynamism and sediment in an otherwise fixed environment. The transition from a fixed vegetated dune to an active blowout is poorly understood, however, and anthropogenic attempts to reactivate areas of bare sand in dunes are often unsuccessful. In this study, we measured topographic change at a monthly resolution in the deflation basins of one bowl and one trough blowout over a 23‐month period in Ainsdale Sand Dunes National Nature Reserve, North‐West England. Our results show that monthly surface change in the blowouts did not correlate strongly with the transport capacity of winds measured at a meteorological station 10 km south of the site. Precipitation was found to have a moderate negative correlation with all indices of surface change, that is, the more it rained the less the surface changed. Inter‐annual (23 months) patterns of topographic change in the bowl and trough blowouts were distinctly different. In the deflation basin of the bowl blowout erosion predominantly took place on the erosional walls facing into the prevailing winds, while minimal change occurred on the erosional walls facing away from the prevailing wind direction. This produced a moderate negative correlation between surface change and slope, that is, the steeper the slope, the more erosion occurred. In the trough blowout, erosion took place in the centre of the deflation basin and minimal change was measured on the easternmost erosional wall, which faced the prevailing winds. Patterns of monthly topographic change were highly variable and demonstrated that changes in the direction of above‐threshold winds can cause blowout walls and floors to ‘flip’ from erosional to depositional surfaces. These findings highlight the variability and complexity of surface change in blowouts and demonstrate that patterns vary because of landform morphology and climatic conditions.

Effect of conventional cigarette smoking and recent heated tobacco products on CAD/CAM restorative materials

ObjectiveTo determine the effects of conventional cigarette smoking (CS) and recent heated tobacco products (HTPs) on the surface roughness and color stability of different indirect restorative materials.Materials and methodsOne hundred disc-shaped samples were constructed of three different restorative CAD/CAM materials: lithium disilicate glass–ceramic (IPS e.max CAD; Ivoclar Vivadent, Liechtenstein), zirconia (BruxZir® Zirconia, Glidewell, USA) and polyetheretherketone (BioHPP® bredent GmbH, Germany). Of the IPS e.max CAD and the Bruxzir samples, 20 samples were glazed, and 20 samples were polished, while the BioHPP samples were all polished according to the manufacturer’s instructions.Fifty samples were subjected to conventional cigarette smoking (LM, Philip Morris International Inc., Egypt) (Groups: IPS e.max CAD_Glazed exposed to CS (LD_G_Cig), IPS e.max CAD_Polished exposed to CS (LD_P_Cig), Bruxzir_Glazed exposed to CS (Zr_G_Cig), Bruxzir _Polished exposed to CS (Zr_P_Cig) and BioHPP exposed to CS (PEEK_Cig) and fifty samples were exposed to heated tobacco product smoking (Heets, Russet selection, Philip Morris International Inc., Italy) (Groups: IPS e.max CAD_Glazed exposed to HTP (LD_G_HTP), IPS e.max CAD_Polished exposed to HTP (LD_P_HTP), Bruxzir_Glazed exposed to HTP (Zr_G_HTP), Bruxzir CAD_Polished exposed to HTP (Zr_P_HTP) and BioHPP exposed to HTP (PEEK_HTP).. Six hundred cigarettes/heets representing 30 days of medium smoking behavior (20 cigarettes/day) were used. Before and after exposure to smoke, the surface roughness of all the samples was measured using JITAI8101 surface roughness tester (Beijing Jitai Tech Detection Device Co., Ltd, China, and the color parameters were assessed using VITA Easyshade Advance 4.01 (VITA shade, VITA made, VITA). The data were analyzed using One-way ANOVA, paired sample t-test and independent sample t-test. The significance level was set at α < 0.05.The surface topography was evaluated by scanning electron microscopy (SEM) and analyzed using energy-dispersive X-ray (EDX) spectroscopy to determine changes in the surface chemical composition.ResultsBoth types of smoking caused significant increases in the surface roughness of all the samples. There was a significant difference in color change between CS and HTP for all materials with different surface finish (P < 0.01) and zirconia had the greatest effect on color change (P < 0.001). In contrast, polyetheretherketone (PEEK) “BioHPP” had the least effect (P < 0.001).ConclusionExposure to different types of smoking induce changes in the surface topography and color of different esthetic restorative materials. Compared with HTP, conventional cigarette smoke has a greater effect on the surface roughness and color stability of esthetic restorative materials. The glazed surfaces showed less change in surface topography than did the polished surfaces. Zirconia showed better color stability when compared to polyetheretherketone (PEEK).

Corneal topography findings among patients with thyroid dysfunction

Background Hormonal dysregulation impacts the metabolism of the cornea and could be linked to keratoconus. Previous research has suggested an association between keratoconus and autoimmune thyroid disorders. Aim The aim of this study was to compare the topographic corneal changes in patients with thyroid dysfunction. Patients and methods This is a cross-sectional study of 200 patients with thyroid dysfunction attending the Endocrinology Clinic at the Faculty of Medicine, Alexandria University. The corneal topography of patients was examined with TMS. Serum levels of thyroid-stimulating hormone, free thyroxine, and free triiodothyronine were measured. Results Two hundred patients with thyroid dysfunction were enrolled in the study. Of them, 129 were hypothyroid patients and 71 were hyperthyroid patients. The study included 137 females and 63 males with a mean age of 32.4 ± 8.2 years. Corneal keratometry readings, including K1, K2, and K max readings, were measured. The mean value of K1 was 45.86 ± 4.69 D, mean K2 was 47.89 ± 5.08 D and the mean corneal thickness was 475 ± 0.36 µm, no relation was found between any of these parameters and serum thyroid-stimulating hormone, free triiodothyronine, or free thyroxine levels. Conclusion In our study, more topographic changes in favor of a thin cornea and steep cornea rather than a true keratoconus were detected in patients with thyroid dysfunction, making cautious analysis of corneal topography important, especially before refractive surgery.

Internal Tides at the Coast: Energy Flux of Baroclinic Tides Propagating into the Deep Ocean in the Presence of Supercritical Shelf Topography

Abstract The generation of internal tides at coastal margins is an important mechanism for the loss of energy from the barotropic tide. Although some previous studies attempted to quantify energy loss from the barotropic tides into the deep ocean, global estimates are complicated by the coastal geometry and spatially and temporally variable stratification. Here, we explore the effects of supercritical, finite amplitude bottom topography, which is difficult to solve analytically. We conduct a suite of 2D linear numerical simulations of the barotropic tide interacting with a uniform alongshore coastal shelf, representing the tidal forcing by a body force derived from the vertical displacement of the isopycnals by the gravest coastal trapped wave (of which a Kelvin wave is a close approximation). We explore the effects of latitude, topographic parameters, and nonuniform stratification on the baroclinic tidal energy flux propagating into the deep ocean away from the shelf. By varying the pycnocline depth and thickness, we extend previous studies of shallow and infinitesimally thin pycnoclines to include deep permanent pycnoclines. We find that scaling laws previously derived in terms of continental shelf width and depth for shallow and thin pycnoclines generally hold for the deeper and thicker pycnoclines considered in this study. We also find that baroclinic tidal energy flux is more sensitive to topographic than stratification parameters. Interestingly, we find that the slope of the shelf itself is an important parameter but not the width of the continental slope in the case of these steep topographies. Significance Statement The objective of this study is to better understand how vertical density stratification, which can vary seasonally in the ocean, affects the interaction of tides with steep coastal topography and the generation of waves that travel away from the coast in the ocean interior. These waves in the interior can travel over long distances, carrying energy offshore into the deep ocean. Our results suggest that the amount of energy in these internal waves is more sensitive to changes in topography and latitude than to the vertical density profile. The scaling laws found in this study suggest which parameters are important for calculating global estimates of the energy lost from the tide to the ocean interior at the coastal margins.

Geodynamic and Climatic Forcing on Late‐Cenozoic Exhumation of the Southern Patagonian Andes (Fitz Roy and Torres del Paine massifs)

AbstractHigh‐relief glacial valleys shape the modern topography of the Southern Patagonian Andes, but their formation remains poorly understood. Two Miocene plutonic complexes in the Andean retroarc, the Fitz Roy (49°S) and Torres del Paine (51°S) massifs, were emplaced between 16.9–16.4 Ma and 12.6–12.4 Ma, respectively. Subduction of oceanic ridge segments initiated ca. 16 Ma at 54°S, leading to northward opening of a slab window with associated mantle upwelling. The onset of major glaciations caused drastic topographic changes since ca. 7 Ma. To constrain the respective contributions of tectonic‐mantle dynamics and fluvio‐glacial erosion to rock exhumation and landscape evolution, we perform inverse thermal modeling of a new data set of zircon and apatite (U‐Th)/He from the two massifs, complemented by apatite 4He/3He data for Torres del Paine. Our results show rapid rock exhumation recorded only in the Fitz Roy massif between 10 and 8 Ma, which we ascribe to local mantle upwelling forcing surface uplift and intensified erosion around 49°S. Both massifs record a pulse of rock exhumation between 7 and 4 Ma, which we interpret as enhanced erosion during the beginning of Patagonian glaciations. After a period of erosional and tectonic quiescence in the Pliocene, increased rock exhumation since 3–2 Ma is interpreted as the result of alpine glacial valley carving promoted by reinforced glacial‐interglacial cycles. This study highlights that glacial erosion was the main driver to rock exhumation in the Patagonian retroarc since 7 Ma, but that mantle upwelling might be a driving force to rock exhumation as well.

Extracting waterline and inverting tidal flats topography based on Sentinel-2 remote sensing images: A case study of the northern part of the North Jiangsu radial sand ridges

Muddy tidal flats with landforms vary widely over space and time. The evolution of tidal flats topography has had a significant impact on the region. Therefore, there is a need to develop methods for rapidly and accurately characterizing tidal flats topography. This study applied thresholding segmentation (TS), machine learning, and two image classification methods to Sentinel-2 remote sensing images to extract the instantaneous waterline of the northern part of the North Jiangsu Radial sand Ridges (NJRSR). Tidal level data at specific time intervals were obtained using the Delft3D and TPXO9 models, after which tidal flats topography inversion was conducted. As a result, varied among the different classification methods, with the K-Nearest Neighbors (KNN) algorithm producing the optimal waterline extraction. Furthermore, the accuracy of tidal level simulation was improved by employing Delft3D software and constructing a scaled-down model of the study area. Comparisons with Delft3D model simulations of tidal levels with observations at three tide gauge stations yielded accuracies of 17.5 cm, 18.5 cm and 17.9 cm, this result showed that the establishment of the tidal level model can enhance the accuracy of tidal flats Digital Elevation Model (DEM) inversion. In fact, the combined application of the KNN algorithm and Delft3D model within retrieval of tidal level provided the most accurate topographic inversion, with an average error of 0.297 m, which was reduced to 0.292 m after median filtering, and the results indicated a trend of southward erosion in the tidal flats in the study area, with a turning point roughly located in the southern part of Doulong Port. The results of this study can help improve the future monitoring of dynamic changes in intertidal wetland topography and the conservation and development of tidal flats areas.

Effects of combined anodal transcranial direct current stimulation and motor control exercise on cortical topography and muscle activation in individuals with chronic low back pain: A randomized controlled study.

Aberrant movement in chronic low back pain (CLBP) is associated with a deficit in the lumbar multifidus (LM) and changes in cortical topography. Anodal transcranial direct current stimulation (a-tDCS) can be used to enhance cortical excitability by priming the neuromuscular system for motor control exercise (MCE), thereby enhancing LM activation and movement control. This study aimed to determine the effects of a 6-week MCE program combined with a-tDCS on cortical topography, LM activation, movement patterns, and clinical outcomes in individuals with CLBP. Twenty-two individuals with CLBP were randomly allocated to the a-tDCS group (a-tDCS; n=12) or sham-tDCS group (s-tDCS; n=10). Both groups received 20min of tDCS followed by 30min of MCE. The LM and erector spinae (ES) cortical topography, LM activation, movement control battery tests, and clinical outcomes (disability and quality of life) were measured pre- and post-intervention. Significant interaction (group×time; p<0.01) was found in the distance between LM and ES cortical locations. The a-tDCS group demonstrated significantly fewer discrete peaks (p<0.05) in both ES and LM and significant improvements (p<0.05) in clinical outcomes post-intervention. The s-tDCS group demonstrated a significant increase (p<0.05) in the number of discrete peaks in the LM cortical topography. No significant changes (p>0.05) in LM activation were observed in either group; however, both groups demonstrated improved movement patterns. Our findings suggest that combined a-tDCS with MCE can separate LM and ES locations over time while s-tDCS (MCE alone) reduces the distance. Our study did not find superior benefits of adding a-tDCS before MCE for LM activation, movement patterns, or clinical outcomes.

Refractive and topographic corneal changes associated with increased inflammatory mediators in tears after COVID-19

This is a rare case report of a sudden shift to myopic astigmatism and topography alterations in a patient who experienced mild coronavirus disease 2019 (COVID-19) symptoms. A complete ophthalmologic evaluation, slit-lamp examination, corneal topography, and tear sampling for biochemical analysis were performed. Elevated corneal K-values were found, indicating abnormal anterior corneal curvature, based on the asymmetric corneal steepening index (cone location and magnitude index) in a Galilei G6 study. Tear analysis demonstrated elevated levels of interleukin (IL)-1β, IL-6, IP-10, IL-8, interferon-β, and prometalloproteinase-9. Ophthalmologists should maintain a high level of suspicion when symptoms suggestive of corneal involvement arise in patients recently infected with severe acute respiratory syndrome coronavirus 2.

Investigating the Intense Sediment Load by Dam‐Break Floods Using a Meshless Two‐Phase Mathematical Model

AbstractExtreme precipitation is increasing the risk of dam breaks and formation occurring debris dams. Accurate prediction of dam‐break wave propagation is critical to disaster emergency management. Intense bed‐load transport by dam‐break floods can result in a dramatic change of topography, which in turn may affect flood propagation. However, only a very few studies have investigated the thin intense bed‐load layer under dam‐break floods. In this paper, a meshless two‐phase mathematical model is utilized to examine the water velocity, sediment velocity and volumetric fraction, and bed‐load transport flux as well as energy dissipation in bed‐load layer. The model is applied to simulate two‐ and three‐dimensional laboratory experiments of dam‐break wave over erodible beds. For the two‐dimensional experiment, the relative root mean square errors in computed water surface are all below 3.60% and those in profiles of bed‐load layer and static bed are mostly below 13.40%. For the three‐dimensional case, the relative error in computed highest water level is lower than 5.9%. Sediment stream‐wise velocity in bed‐load layer follows a power‐law vertical distribution while sediment volumetric fraction decreases linearly upwards. Accordingly, a formulation of the vertical distribution of bed‐load transport flux, contradictory to the parabolic law in existing studies, is proposed. Most of the water mechanical energy transferred to the sediment is dissipated due to the shear stress in the intense bed‐load layer while only a limit part is kept by the sediment grains. Energy dissipation due to sediment shear stress dominates the consumption of total mechanical energy in the two‐phase system.

Source‐To‐Sink Analysis in the Mesozoic SW Junggar Basin, Central Asia: Evidence From Detrital Garnet and Tourmaline Geochemistry

AbstractSource‐to‐sink systems respond to and therefore potentially record topographic and tectonic changes. North of the Tian Shan Belt, the Sikeshu subbasin of the SW Junggar Basin transitioned from active extension in the Triassic to post‐extensional subsidence in the Jurassic‐Cretaceous. Sediment in the Sikeshu subbasin has been shown to be derived from the Tianshan. However, the details of the source‐to‐sink system remain unclear and discrepancies exist between proxy records. The heavy minerals in the Middle Triassic in the Sikeshu subbasin are dominated by garnets. To investigate the garnet sources and decipher the Mesozoic source‐to‐sink evolution, we conducted petrological and sedimentary analysis and detrital garnet and tourmaline geochemistry. We found that the geochemistry of garnets in the Middle Triassic sandstone is most consistent with that of the skarns in the Yili Block (YB) in Tianshan, while the geochemistry of 55%–84% of garnets in other Mesozoic sandstones is consistent with that of garnets in amphibolites in the YB. The geochemistry of the tourmalines since the Upper Triassic is consistent with that of the meta‐sedimentary rocks in the YB and Central Tianshan Block. The dominance of garnets sourced from skarns in the Middle Triassic probably indicates a near‐source point provenance and the broader range of garnet compositions from the Upper Triassic–Lower Cretaceous suggests multiple sources. We infer that the point source changed to multiple sources, which is consistent with the zircon spectra changing from unimodal to multimodal. This change reflects the expansion of the drainage that accompanies a change from active rifting to a post‐rift stage.

Numerical modeling and simulation of microbially induced calcite precipitation on a cement surface at the pore scale

Accurate estimation of contaminant transport in cementitious material using numerical tools plays a key role in the risk assessments of nuclear waste disposal. At the pore scale, the increase of microbial activity, such as microbially induced calcite precipitation on cementitious material, causes changes in solid surface topography, pore network geometry, and pore water chemistry, which affect contaminant transport at the core scale and beyond. Consequently, a meaningful estimation of contaminant migration in the subsurface requires a pore-scale investigation of the influence of microbial activity on transport processes. In this study, a pore-scale reactive transport model is presented to simulate the physicochemical processes resulting from microbially induced calcite precipitation on a cement surface. Numerical investigations focus on modeling the reactive transport in a two-dimensional flow-through cell. The model results are validated by experimental data showing an increase in pH and a decrease in calcium concentration due to microbially induced calcite precipitation. Our results show heterogeneous calcite precipitation under transport-limited conditions and homogeneous calcite precipitation under reaction-limited conditions, resulting in non-uniform and uniform changes in the material surface topography. Moreover, power spectral density analysis of the surface data demonstrates that microbially induced calcite precipitation affects the surface topography via both general changes over the entire frequency and local modifications in the high-frequency region. The sensitivity studies provide a comprehensive understanding of the evolution of surface topography due to the microbially induced calcite precipitation at the pore scale, thus contributing to an improved predictability of contaminant transport at the core scale and beyond.

Rebonding of orthodontic metallic brackets: Comparative analysis of shear bond strength using different sandblasting particles

IntroductionThis study aimed to evaluate the effect of two different sandblasting particles on the shear bond strength of rebonded metallic brackets to dental enamel. MethodsForty-eight metallic orthodontic brackets were divided into 4 experimental groups (n = 12) according to the surface treatment they received at their bases: positive control group (Metal), negative control group (MetalU), sandblasted with Rocatec Soft (MetalRoc) and sandblasted with Glass beads (MetalGlas). An elementary and topographic analysis of the base of the brackets was performed using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) after the surface treatment. The brackets rebonded to dental enamel were tested for their shear bond strength. The obtained data were subjected to statistical analysis one-way ANOVA and Tukey's test (α = 0.05). The fracture surfaces of the specimens after the mechanical test were analyzed using optical microscopy to classify the failure mode. ResultsSEM photomicrographs for the MetalRoc and MetalGlas groups showed efficient removal of the remaining resin composite. In both sandblasting treatments, the presence of silicon (Si) and oxygen (O) at the base of the brackets were verified by means of the EDS, suggesting the occurrence of silica coating. MetalGlas group showed greater bond strength (9.38 ± 2.78 MPa) compared to the MetalU group (5.31 ± 1.2Mpa). Metal (8.82 ± 4.14 MPa) and MetalRoc (8.29 ± 3.95 MPa) groups showed similar bond strengths. The failure mode predominantly found in the sandblasted groups was the totally adhesive failure between resin composite and tooth. SignificanceThe sandblasting treatment using the glass beads was efficient in removing the remaining resin composite of recycled brackets and generated fewer surface defects and topographic changes in the bracket bases.

Intervisit Reproducibility of Foveal Cone Density Metrics.

To assess longitudinal reproducibility of metrics of foveal density (peak cone density [PCD], cone density centroid [CDC], and 80th percentile centroid area) in participants with normal vision. Participants (n = 19; five male and 14 female) were imaged at two time points (average interval of 3.2years) using an adaptive optics scanning light ophthalmoscope (AOSLO). Foveally centered regions of interest (ROIs) were extracted from AOSLO montages. Cone coordinate matrices were semiautomatically derived for each ROI, and cone mosaic metrics were calculated. On average, there were no significant changes in cone mosaic metrics between visits. The average ± SD PCD was 187,000 ± 20,000 cones/mm2 and 189,000 ± 21,700 cones/mm2 for visits 1 and 2, respectively (P = 0.52). The average ± SD density at the CDC was 183,000 ± 19,000 cones/mm2 and 184,000 ± 20,800 cones/mm2 for visits 1 and 2, respectively (P = 0.78). The average ± SD 80th percentile isodensity contour area was 15,400 ± 1800µm2 and 15,600 ± 1910µm2 for visits 1 and 2, respectively (P = 0.57). Foveal cone mosaic density metrics were highly reproducible in the cohort examined here, although further study is required in more diverse populations. Determination of the normative longitudinal changes in foveal cone topography is key for evaluating longitudinal measures of foveal cone topography in patients with progressive retinal dystrophies.

Out-of-plane preferential growth of 2D molybdenum diselenide nanosheets on laser-induced periodic surface structures

In this study, we explore the morphology and orientation of molybdenum diselenide, a Van der Waals 2D material, through isothermal closed space vapor deposition on both pristine and laser-structured substrates. Laser structuring is conducted on dielectric (sapphire), semiconductor (silicon), and conductive (titanium nitride) substrates using ultrashort laser pulses, resulting in smooth topographic changes such as laser-induced periodic surface structures (LIPSS) or selective ablation. Scanning electron microscopy (SEM) reveals the pivotal role of surface structuring in the growth of out-of-plane MoSe2 nanosheets. This effect is particularly pronounced on monocrystalline substrates like sapphire and silicon, exhibiting in-plane growth on pristine substrates. Additionally, Raman spectroscopy confirms the vertical orientation of flakes on structured substrates and highlights the presence of active edge sites by demonstrating an increased abundance of deposited material. Overall, our findings emphasize the controllability of directing the growth of MoSe2 flakes through appropriate pre-treatment of the substrate, with potential applications in various fields, including Surface-Enhanced Raman Scattering (SERS). Furthermore, the scalability, reproducibility, and applicability to any substrate make ultrashort laser structuration a promising general strategy for orienting 2D materials.

Studying the Effect of Magnetron Copper Deposition on the Surface Topography of Biodegradable Antibacterial Coating.

The surface properties of the materials used significantly influence the success and longevity of medical implants. Increasing surface roughness promotes osteoblast activity and osseointegration, while biodegradable materials such as copper have shown potential for antimicrobial applications. However, the effect of coating parameters on surface topography is not well investigated. Sputtering of copper was performed using EPOS-PVD-440 system (Zeleno-grad, Russia). The samples were examined by Scanning Electron Microscopy (SEM) with subsequent image processing in Mountains software (Digital Surf). Antibacterial efficacy was evaluated against Staphylococcus aureus by measuring the zone of inhibition. Additionally, copper ion release was monitored over time to assess its correlation with changes in surface topography. Higher sputtering currents increased surface roughness and particle size, with a significant release of copper ions within the first 24 hr of immersion. Samples sputtered at higher currents exhibited coarser grain structures. The release of copper ions in the simulated biological environment led to further changes in surface topography, highlighting the critical influence of sputtering parameters on coating properties. Optimizing magnetron copper deposition parameters enhances the surface topography and antibacterial effectiveness of biodegradable coatings on implants.

Erosion, deposition and breach evolution of landslide dams composed of various dam material types based on flume tests

The accurate and rapid prediction of breach outflow rates of landslide dams is crucial for effective risk assessment and mitigation strategies. However, challenges arise due to the complexities associated with breaching mechanisms. In this study, 12 flume tests were conducted on landslide dams composed of various material types, including fine-grained, coarse-grained, well-graded, and gap-graded materials, each with two dry densities. This study comprehensively investigated erosion, deposition, and breach evolution, providing the foundation for the development of breach evolution models. A comprehensive logic diagram, focusing on shear stress and grain size distribution, was proposed to forecast the failure modes of landslide dams. The study also suggested a method to assess the longitudinal breach evolution based on the prediction of the Erosion Point (EP) and Deposition Point (DP), and to assess the lateral breach evolution by considering both steep and gentle breach side slopes. Our findings indicate that fine-grained materials undergo layer erosion, coarse-grained materials remain stable, well-graded materials develop erosion pits, and gap-graded materials are prone to piping. The existence of an interface can result in piping channels, even when the overall hydraulic gradient is insufficient to initiate piping. Incorporating the longitudinal slope angle and its influence on both driving and resisting forces into the traditional erosion rate equation can significantly enhance its accuracy, especially when coarse particles are present. Coarse particles play a pivotal role in erosion and deposition behavior and reshaping the breach evolution as the initiation of coarse particles is dominated by rolling instead of slipping in fine particles. Deposition on the downstream slope of a dam can significantly influence the longitudinal breach process, leading to changes in the downstream topography and grain size distribution. The proposed method for assessing longitudinal breach evolution unifies the previous methodologies by predicting the positions of EP and DP based on erosion and deposition.

Influence of grit friability and grit distribution pattern on dry grindability of WC-6Co by single layered brazed diamond wheels

Single-layered brazed diamond wheels, composed of uni-layered diamond grits, metal binder, and metal core, have potentially good thermal conductivity to dissipate heat from the grinding zone. Considering this characteristic feature, the current study aims to explore the performance and suitability of various indigenously developed single-layered brazed diamond tools in plunge-grinding of fine-grained cemented carbide in a challenging dry atmospheric condition. Single crystalline synthetic diamond particles with different strengths and friability were utilized to develop indigenous diamond wheels with random and patterned grit distribution. The current study explores the role of diamond-grit friability and grit distribution patterns to identify the most suitable wheel for dry grinding of WC-6Co composite. Detailed analysis of the wheel morphology, signifying the fracture behavior of the diamond grit used, justified the variation in the grinding forces, tool life, and ground surface roughness. Irrespective of the grit and distribution type, all wheels showed saturation of dynamic changes in work-surface topography with the number of passes and more sensitively to the degree of increase of uncut chip thickness. Grinding wheels containing friable diamond grits with irregular granular structures performed better than the high-strength, cubo-octahedral grains during the dry grinding experiments.