In this study, novel Fe3O4 nanoparticles coated with surfactant Igepal Co-520 (polyoxyethylene (5) nonylphenylether) as adsorbent were synthesized, and total vanadium recovery was performed by magnetic solid phase extraction (MSPE) method. Fe3O4 nanoparticles coated with Igepal Co-520 were employed in the investigation of vanadium enrichment. The synthesized nanoparticles were characterized by Field Emission Scanning Electron Microscope (FESEM), Energy Dispersive X-Ray Analysis (EDX), X-Ray Diffraction Analysis (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), and Thermogravimetric Analysis (TGA), and total vanadium concentration was determined by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES). The corresponding values for the pH, adsorbent amount, and contact time were 3, 5 mg, and 120 min. Total vanadium was recovered from an aqueous solution under the optimum conditions. Langmuir and Freundlich adsorption isotherms, pseudo-first and pseudo-second order adsorption kinetics, foreign ion studies, desorption, and analytical value studies were performed. In isotherm studies, the effect on adsorption was examined by varying the vanadium concentration between 1 mg/L and 100 mg/L. The Langmuir model (R2>0.99) seems to be more compatible with vanadium adsorption than the Freundlich model (R2<0.87). Pseudo−first-order and pseudo-second-order equations were used to evaluate adsorption kinetic models. It has been observed that the pseudo-quadratic equation (R2>0.89) was more suitable for modeling than the pseudo-first-order equation (R2<0.56). The analytical performance parameters of the method were calculated as enrichment factor (EF) 114, the limit of detection (LOD) 8.3 µg/L, the limit of quantification (LOQ) 28.3 µg/L, and relative standard deviation (RSD) 1.20 %. At various molarities, the effects of acidic (HCl) and basic (NaOH) agents on the desorption of total vanadium ions adsorbed on the magnetic Fe3O4 surface were examined and compared. It was observed that the maximum recovery (100 %) was obtained using HCl as the desorption agent. The total vanadium concentration in spice samples was measured in an actual sample analysis. All the results demonstrate that the Fe3O4@Igepal Co-520 was successfully synthesized and has the potential to be a useful tool for heavy metal recovery.
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