We study the electronic kinetics of singlet molecular nitrogen in Titan’s upper atmosphere during precipitations of high-energetic particles. Both radiative processes and processes of electron excitation energy transfer during inelastic collisions with N2 and CH4 molecules were considered in the calculation of vibrational populations of electronically excited singlet states a'1Σu–, a1Πg, w1Δu of molecular nitrogen in the upper atmosphere of Titan. It is shown that the calculated volume emission intensities of the Lyman-Birge-Hopfield bands correlate with the profiles of the ion production rate in the atmosphere of Titan during the considered cases of electron precipitation for considered interval of the energies 30-1000 eV of magnetospheric electrons. This fact is explained by the negligible contribution of collisional processes to the vibrational populations a1Πg(v'=0-6) in the considered range of heights above 900 km.