Three-dimensional Structure Research Articles

Hierarchical Polyimide Nonwoven Fabric with Ultralow-Reflectivity Electromagnetic Interference Shielding and High-Temperature Resistant Infrared Stealth Performance

Designing and fabricating a compatible low-reflectivity electromagnetic interference (EMI) shielding/high-temperature resistant infrared stealth material possesses a critical significance in the field of military. Hence, a hierarchical polyimide (PI) nonwoven fabric is fabricated by alkali treatment, in-situ growth of magnetic particles and "self-activated" electroless Ag plating process. Especially, the hierarchical impedance matching can be constructed by systematically assembling Fe3O4/Ag-loaded PI nonwoven fabric (PFA) and pure Ag-coated PI nonwoven fabric (PA), endowing it with an ultralow-reflectivity EMI shielding performance. In addition, thermal insulation of fluffy three-dimensional (3D) space structure in PFA and low infrared emissivity of PA originated from Ag plating bring an excellent infrared stealth performance. More importantly, the strong bonding interaction between Fe3O4, Ag, and PI fiber improves thermal stability in EMI shielding and high-temperature resistant infrared stealth performance. Such excellent comprehensive performance makes it promising for military tents to protect internal equipment from electromagnetic interference stemmed from adjacent equipment and/or enemy, and inhibit external infrared detection.

Near-Isotropic Sub-Ångstrom 3D Resolution Phase Contrast Imaging Achieved by End-to-End Ptychographic Electron Tomography

Abstract Imaging three-dimensional atomic structures with sub-Ångstrom resolution using Scanning Transmission Electron Microscopy (STEM) has always been a challenging task. Linear electron tomography methods are limited by the missing wedge effect. Multislice ptychography is capable of achieving atomic resolution in the transverse direction, but the depth resolution is limited to 2 to 3 nanometers. In this paper, we propose and demonstrate an end-to-end approach to reconstructing the electrostatic potential volume of the sample directly from the 4D-STEM datasets. End-to-end multi slice ptychographic tomography recovers several slices at each tomography tilt angle and compensates for the missing wedge effect. The algorithm is initially tested in simulation with a Pt@$\mathrm{Al_2O_3}$ core-shell nanoparticle, where both heavy and light atoms are recovered in 3D from an unaligned 4D-STEM tilt series with a restricted tilt range of 90 degrees. We also demonstrate the algorithm experimentally, recovering a Te nanoparticle with sub-Ångstrom resolution.

Insights into the functional mechanisms of three terpene synthases from Lavandula angustifolia (Lavender)

Lavender species are of significant economic value being cultivated extensively worldwide for their essential oils (EOs), which include terpenes that play crucial roles in the cosmetic, personal care, and pharmaceutical industries. The terpene synthases in lavender, such as Lavandula angustifolia linalool synthase (LaLINS), limonene synthase (LaLIMS), and bergamotene synthase (LaBERS), are key enzymes in terpene biosynthesis. However, the functional mechanisms underlying these enzymes remain poorly understood. Here, we used AlphaFold2 to predict the three-dimensional structures of LaLINS, LaLIMS, and LaBERS. The hydrodynamic radii of LaLINS, LaLIMS, and LaBERS were 5.7 ± 0.2, 6.2 ± 0.3, and 5.4 ± 0.2 nm, respectively. Mutations D320A or D324A led to a complete loss of activity in LaLINS compared to the wild-type (WT) enzyme; similarly, mutations D356A or D360A abolished activity in LaLIMS, and D291A or D295A eliminated activity in LaBERS. Furthermore, the genes LaLINS, LaLIMS, and LaBERS exhibited significantly higher expression levels in leaves compared to stems and flowers, with peak expression occurring at 8:00 a.m. Our findings contribute to a deeper understanding of terpene biosynthesis in lavender and offer insights for improving essential oil production through genetic engineering.

3D Nanofabrication via Directed Material Assembly: Mechanism, Method, and Future.

Fabrication of complex three-dimensional (3D) structures at nanoscale is the core of nanotechnology, as it enables the creation of various micro-/nano-devices such as micro-robots, metamaterials, sensors, photonic devices, etc. Among most 3D nanofabrication strategies, the guided material assembly, an efficient bottom-up approach capable of directly constructing designed structures from precise integration of material building blocks, possesses compelling advantages in diverse material compatibility, sufficient driving forces, facile processing steps, and nanoscale resolution. In this review, we focus on assembly-based fabrication methods capable of creating complex 3D nanostructures (instead of periodic or 2.5D-only structures). Recent advances are classified based on the different assembly mechanisms, i.e., assembly driven by chemical reactions, physical interactions, and the synergy of multiple microscopic interactions. The design principles of representative fabrication strategies with an emphasis on their respective advantages, e.g., structural design flexibility, material compatibility, resolution, or applications are analyzed. In the summary and outlook, existing challenges, as well as possible paths to solutions for future development are reviewed. We believe that with recent advances in assembly-based nanofabrication strategies, 3D nanofabrication has achieved tremendous progress in resolution, material generality, and manufacturing cost, for it to make a greater impact in the near future.

Carbon Nanofiber/Polyaniline Composite Aerogel with Excellent Electromagnetic Interference Shielding, Low Thermal Conductivity, and Extremely Low Heat Release

Abstract The rapid development of communication technology and high-frequency electronic devices has created a need for more advanced electromagnetic interference (EMI) shielding materials. In response to this demand, a study has been conducted to develop multifunctional carbon nanofibers (CNFs)/polyaniline (PANI) aerogels with excellent electromagnetic interference shielding, flame retardancy, and thermal insulation performance. The process involved freeze-drying of electrospun CNFs and PANI nanoparticles followed by in situ growth PANI to coat the CNFs, creating the core–shell structured CNFs/PANI composite fiber and its hybrid aerogels (CP-3@PANI). The interaction between PANI and aniline (ANI) provides attachment sites, allowing additional ANI adsorption into the aerogel for in situ polymerization. This results in PANI uniformly covering the surface of the CNFs, creating a core–shell composite fiber with a flexible CNF core and PANI shell. This process enhances the utilization rate of the ANI monomer and increases the PANI content loaded onto the aerogel. Additionally, effective connections are established between the CNFs, forming a stable, conductive three-dimensional network structure. The prepared CP-3@PANI aerogels exhibit excellent EMI shielding efficiency (SE) of 85.4 dB and specific EMI SE (SE d−1) of 791.2 dB cm3 g⁻1 in the X-band. Due to the synergistic flame-retardant effect of CNFs, PANI, and the dopant (phytic acid), the CP-3@PANI aerogels demonstrate outstanding flame-retardant and thermal insulation properties, with a peak heat release rate (PHRR) as low as 7.8 W g⁻1 and a total heat release of only 0.58 kJ g⁻1. This study provides an effective strategy for preparing multifunctional integrated EMI shielding materials.

Photopatterned Anchoring Stabilizing Monodomain Blue Phases.

Blue phase liquid crystals (BPLCs) are chiral self-assembled three-dimensional (3D) periodic structures which have attracted a lot of attention due to their electro-optical properties, relevant for tunable soft photonic crystals and fast-response displays. However, to realize this application potential, controlling the BPLC alignment at the surfaces is crucial, and one way to obtain the desired alignment is by photoalignment patterning. In this article, monodomain BPLC samples with controlled orientation are achieved by imposing different alignment patterns that have a periodicity that is compatible with the size of the BPLC unit cell, using two-step photoalignment with polarized ultraviolet (UV) light. Experiments are complemented by numerical simulations to design striped surface alignment patterns, which induce specific director orientations on the boundary layer of the confined BPLC. By designing the patterns and matching the periodicity to a specific BP material, we can control the orientation of the blue phase unit cell lattice in the sample, including the azimuthal angle. The orientation is measured by the Kossel patterns and matches the optimal configuration predicted by stability analysis using Landau-de Gennes free energy modeling. The detailed structure and reduced symmetry of the BP near the surface are investigated, and the corresponding (meta)stable structures are demonstrated. Overall, we demonstrate that two-step photoalignment patterning is a reliable, relatively simple, and reconfigurable method to achieve a high-quality monodomain BP with controlled and tunable crystalline orientation.

Localization and antigenicity reduction of immunodominant conformational IgE epitopes on αs1-casein

αs1-Casein (αs1-CN) is the major allergen in cow milk; however, the understanding of its conformational epitopes remains limited due to the absence of a well-defined three-dimensional structure, which has impeded efforts to effectively reduce its antigenicity. This study employed molecular dynamics simulations (MD), ELISA, cell assays and peptidomes analysis to investigate the critical conformational epitopes of αs1-Casein. MD and immunological analyses identified a dominant conformational epitope encompassing the regions S55-E75 & Y154-T174 & F179-W199, which exhibited strong binding affinity to IgE and triggered the releasing of β-hexosaminidase, histamine and IL-6 in KU812 cells, thereby inducing allergic responses. Notably, the segments Y154-T174 and F179-W199 were particularly impactful. Furthermore, the presence of helical structures within the epitopes enhanced their binding to IgE to a certain extent. Peptidomes analysis further revealed that papain efficiently disrupted the key epitope (Y154-T174) by selectively cleaving the hotspot amino acid residues (Y154 and Y165), thereby significantly reducing the antigenicity of αs1-CN, decreasing IgE and IgG binding to 7.28 % and 10.39 %, respectively. These findings enhance the understanding of αs1-CN's antigenic epitopes and provides a theoretical and technical foundation for the targeted reduction of its antigenicity.

RNA-Puzzles Round V: blind predictions of 23 RNA structures.

RNA-Puzzles is a collective endeavor dedicated to the advancement and improvement of RNA three-dimensional structure prediction. With agreement from structural biologists, RNA structures are predicted by modeling groups before publication of the experimental structures. We report a large-scale set of predictions by 18 groups for 23 RNA-Puzzles: 4 RNA elements, 2 Aptamers, 4 Viral elements, 5 Ribozymes and 8 Riboswitches. We describe automatic assessment protocols for comparisons between prediction and experiment. Our analyses reveal some critical steps to be overcome to achieve good accuracy in modeling RNA structures: identification of helix-forming pairs and of non-Watson-Crick modules, correct coaxial stacking between helices and avoidance of entanglements. Three of the top four modeling groups in this round also ranked among the top four in the CASP15 contest.

Total Synthesis of Euphorbialoid A.

Euphorbialoid A (1) belongs to the rare diterpenoid family of premyrsinanes and exhibits potent anti-inflammatory effects. The 5/7/6/3-membered carbocycle (ABCD-ring) of 1 contains 11 contiguous stereocenters and seven oxygen-containing functional groups. Moreover, four of the six hydroxy groups of 1 are concentrated in the southern sector and flanked by four structurally different acyl groups. The dense array of various functional groups with disparate reactivities on the tetracyclic ABCD-ring presents a daunting challenge for the chemical synthesis of 1. As a reflection of its formidable complexity, synthesis of 1 or any other premyrsinane diterpenoids has not yet been reported. Here, we devised a novel strategy comprising two stages and achieved the first total synthesis of 1 (35 steps as the longest linear sequence). In the first stage, the ABCD-ring was expeditiously assembled by integrating three powerful transformations: (1) Pt-doped TiO2-catalyzed radical coupling to attach a northern chain to a 6/3-membered CD-ring, (2) Pd-catalyzed decarboxylative asymmetric allylation to construct a quaternary carbon with a southern chain, and (3) a Co-mediated Pauson-Khand reaction to cyclize the two chains into the 5/7-membered AB-ring. In the second stage, three-dimensional structures of the ABCD-ring intermediates were utilized to stereoselectively fabricate the A-ring and site-selectively append the four different acyl groups. In the present total synthesis, we revealed the significance of orchestrating the multistep reaction sequence and incorporating cyclic protective groups. The overall strategy and tactics provide new insights into designing synthetic routes to premyrsinanes and densely oxygenated terpenoids decorated with diverse acyl groups.

Interfacial evaporation characteristics of three-dimensional Cu-Fe3O4 nanoparticle film

In an effort to further enhance the evaporation effect of interfacial evaporation, a super-hydrophilic nanoparticle film was prepared by ultrasonic impregnation in this paper. Then, by improving the structure and configuration design of nanoparticle film, the nanoparticle film was transformed from two-dimensional structure to three-dimensional structure. The effects of three-dimensional structure shape, radiation intensity and three-dimensional structure height on the evaporation capacity of nanoparticle films were studied. It was found that the evaporation rate of the three-dimensional rectangular Cu-Fe3O4 nanoparticle film with a rectangular height of 15 mm achieved 1.2 kg/m2/h under one sun radiation intensity. The evaporation efficiency can reach 75.44 %, and the thermal efficiency can reach 111.91 %. The design of the three-dimensional structure enables the nanoparticle film to perform double-sided evaporation. At the same time, under the action of natural air convection, the nanoparticle film evaporation efficiency is greatly improved, which provides a design strategy for the nanoparticle film in the field of solar-driven interface evaporation.

Reconstructed three-dimensional structure of gas-foamed polycaprolactone/cellulose nanofibrous scaffold for biomedical applications

One of the unavoidable issues with the bio-scaffolding process is the collapse of the visually appealing external three-dimensional (3D) sponge-like structure and the internal porous and multilayered morphology of a gas-foamed nanofibrous scaffold. Herein, a gas-foamed polycaprolactone/cellulose (g-PCL/CL) nanofibers scaffold is first prepared by electrospinning PCL/cellulose acetate, followed by deacetylation and then Sodium borohydride-assisted gas-foaming technique. The deformed 3D architecture of g-PCL/CL nanofiber is finally reconstructed by mixing it with chitosan (CS) solution and molding. This straightforward method leverages the mechanical strength of PCL, the hydrophilic properties of CL, and the curing characteristics of chitosan. The physical characterization validated the successful reformation of the 3D architecture of the CS + PCL/CL scaffold demonstrating the unique porous interior structure assembled with nanofiber-reinforced pore walls. This molding process with chitosan solution enables the formation of mechanically enhanced 3D scaffolds with improved structural integrity, as evidenced by the increased compressive strength of the CS + PCL/CL scaffold (~95 kPa). In vitro studies further demonstrate improved cell adhesion, differentiation, and proliferation for the CS + PCL/CL scaffold. These findings suggest that the structurally reconstructed CS + PCL/CL composite scaffold possesses suitable characteristics to act as a potential bioscaffold, paving the way for promising strategies to retain the structural integrity of collapse scaffolds.

A pseudo-density conjugate heat transfer method and its application to simulating the quasi-steady temperature field of a compressor cylinder

The substantial disparity in time scales between heat conduction and convection requires extremely tiny time steps in simulations, leading to significant computational demands when using current-tightly coupled methods to solve the temperature field of cylinders at the quasi-steady stage. A new pseudo-density method is proposed to accelerate the heat conduction rate. The influence of solid density on transient temperature under the periodic third-type boundary conditions is analyzed in a one-dimensional model by analytical methods and verified in a three-dimensional structure by numerical methods. It is found that reducing solid density can accelerate the heat conduction rate and increase the fluctuation amplitude of solid temperature. Therefore, a variable pseudo density is adopted for solids in the simulation of the transient heat transfer characteristics between the compressed gas and the cylinder. The results show that the pseudo-density method provides similar computational accuracy to the current tightly coupled methods, but at significantly lower computational cost. The fluctuation amplitude of the cylinder's temperature decreases rapidly in the wall thickness direction. The distribution of the convective heat transfer coefficient on the inner wall of the cylinder is extremely transient and highly non-uniform, which is consistent with the distribution of gas velocity near the cylinder wall.

Designing a multi-epitope subunit vaccine against Toxoplasma gondii through reverse vaccinology approach

The parasite Toxoplasma gondii, or T. gondii, is zoonotic that both individuals as well as animals can contract resulting in toxoplasmosis, a life-threatening illness. We used an immunoinformatic technique in our research to construct a vaccine with multi-epitopes so that it can decrease the devastating impact caused by this dangerous parasite. In order to construct the vaccine, GRA6 and MIC3 proteins were targeted, which are engaged in T. gondii identification, infection, and immune response. Novel epitopes for linear B lymphocytes (LBL), cytotoxic T lymphocytes (CTL), and helper T lymphocytes (HTL) were found by epitope mapping, every anticipated epitope was assessed through rigorous screening to determine the top choices for epitopes which were entirely preserved, very antigenic in nature, nonallergenic, and nontoxic. 4 CTLs, 3 HTLs and 4 LBL epitopes were chosen and combined along with proper linkers and adjuvants to design a vaccine with several epitopes. Linkers as well as adjuvants were provided to make the vaccine more immunogenic, antigenic, and stable. The proposed vaccination was identified to possess the necessary biophysical properties, be soluble, extremely antigenic, and non-allergic. Reliability of the vaccine design was demonstrated by secondary along with tertiary structure prediction. It was anticipated that the vaccine's three-dimensional structure would likely link up with TLR-2 and TLR-4 via the investigation of molecular docking. TLR-2 and TLR-4 are crucial for the parasite's invasion and the body's response. In our docking investigation, both TLRs demonstrated strong binding affinities utilizing the vaccine structure. After that, the vaccine construct's elevated expression rate, which was observed in Escherichia coli strain K12, was confirmed by an investigation using in silico cloning and codon adaptation. The results of the research are really encouraging and some properties of the vaccine were found to be significantly better than existing the T. gondii multi-epitope vaccination based on the same proteins. Nonetheless, in vivo trials are strongly suggested for potential future studies.

ACOUSTIC-MODELING OF RANDOM FIBROUS MATERIALS

We present a microstructure-based model for determining the sound absorption behavior and transport parameters of random fibrous materials and exploring the physical mechanisms underlying acoustic energy dissipation. In order to increase the generalizability of the model, a three-dimensional random fiber structure is employed for simulation. The propagation of sound waves is associated with four transport parameters, including viscous permeability, tortuosity, as well as viscous and thermal characteristic lengths. These parameters are determined by the porosity and diameter of the fibrous material. By using the method of multi-scale asymptotic simulation, the theoretical model for transport parameters includes unknown coefficients that are adjusted based on the simulated results. The sound absorption coefficients are then obtained by integrating the transport parameters into the widely-used Johnson-Champoux-Allard (JCA) model for porous materials. The theoretical predictions match well with existing experimental measurements on sintered fiber metals and fibrous copper wires. Our model systematically examines the impact of fiber diameter, porosity, and material thickness on sound absorption performance. Optimal results are achieved by carefully selecting fiber diameter and porosity to enhance the acoustic dissipation of sound waves, while thicker fibrous materials increase sound absorption in the low frequency range. The model provides a theoretical framework for designing and fabricating fibrous materials to reduce noise.

An injectable epoxidized soybean oil/gelatin-based photothermal biogel with remarkable rapid hemostasis capability for wound repair.

The development of wound dressings with rapid hemostasis, antibacterial activity without the addition of antibiotics and on-demand removability that effectively avoid secondary damage to the wound during replacement still faces significant challenges. Herein, injectable epoxidized soybean oil/gelatin-based photothermal biogel with outstanding tissue adhesion, on-demand removability, shape-adaptability, and antibacterial performance is prepared as a removable wound dressing for wound repair. The biogel is composed of two types of hydrophilic/hydrophobic three-dimensional network structures, which interweave together through dynamic imine bonds, coordination bonds and numerous hydrogen bonds to synergistically improve injectability, self-healing, tissue adhesion, and compressive performance of the biogel. Moreover, the prepared EG-02 biogel not only has excellent thermal stability, biodegradability, hemocompatibility, and RBCs and platelet adhesion properties, but also displays outstanding cytocompatibility and the ability to promote cell migration. Furthermore, the EG-02 biogel treated with a near-infrared (NIR) laser (808 nm, 0.2 W·cm-2) exhibits prominent photothermal cycling stability and antibacterial performance. Notably, the EG-02 biogel presents remarkable rapid hemostasis capability, with the hemostatic time greatly shortened to 40 s and the blood loss significantly reduced to 89.2 mg. Therefore, the injectable photothermal biogel, as a fascinating candidate for on-demand removable wound dressing, has shown promising application prospects in wound repair.

Deep learning assisting construction of heat transfer constitutive relationships for porous media

Predicting heat transfer in porous materials is challenging due to their complex microstructure, and traditional experimental and theoretical methods often fall short. To address this, we present a machine learning-based approach using a single Descriptor-to-Property Network (D2P-Net) to identify the relationships between the effective thermal conductivity (ETC) of porous media with the structural descriptors. The D2P-Net, an ensemble of decision trees, uses eleven structural descriptors, such as porosity, pore size, and connectivity, derived from four distinct types of three-dimensional porous structures. These structures are computationally generated, and their ETC is computed using the Lattice Boltzmann Method (LBM) to create a robust dataset for training. The model is trained using mean squared error (MSE) employed as the loss function, and achieves an R2 value of 0.994 and a root mean square error (RMSE) of 0.229, indicating high predictive accuracy. Additionally, SHapley Additive exPlanations (SHAP) values are employed to analyze the importance of each structural descriptor, offering valuable insights into their contributions to ETC predictions. This approach provides a reliable and interpretable method for understanding and optimizing the thermal properties of porous materials, with potential applications in areas requiring efficient thermal management, such as hypersonic vehicles.

Ag@MXene-cellulose nanofiber composite for electromagnetic interference shielding, sensing, and actuating

With the development of flexible electronic devices, the development of flexible and multi-functional materials becomes increasingly important. In this study, we prepared Ag@MXene-cellulose nanofiber (AMC) multi-functional composites with a three-dimensional (3D) conductive network structure, which can be used for electromagnetic interference (EMI) shielding, pressure sensing, and actuating. AMC has good electrical conductivity (18.04 S cm-1) and EMI shielding effectiveness (37.7dB). The microstructure of the AMC surface gives it the potential to be applied in the pressure sensor. AMC is humidity-sensitive and has excellent electrical/photo-thermal conversion properties. Thus, AMC can be used to fabricate humidity-driven actuators and electrical/light-driven actuators. Finally, three multi-functional devices/systems have been carefully designed to achieve the fabrication of multi-functional devices/systems that rely on only one raw material, which significantly simplifies the preparation of multi-functional devices. We hope this research will open up new ways for artificial muscles, soft robots, and EMI shielding devices.

Ultralight and robust polyimide aerogels with tunable porous structures based on cation-π interactions for superior thermal insulation

Polyimide (PI) aerogels, renowned for their ultra-low density and exceptional porosity, exhibit substantial potential for thermal insulation applications. However, conventional freeze-drying method often produces irregular and large pore structures, which compromise the mechanical properties of PI aerogels and limit their practical applications. In this work, the enhanced PI-Cu aerogels by cation-π interactions are fabricated through the introduction of Cu ions and benzimidazole. The findings reveal that cation-π interactions facilitate the transformation of PI aerogels from two-dimensional layered structure to three-dimensional honeycomb structure characterized by smaller and more uniform pores, significantly reducing shrinkage and leading to ultra-light properties. Remarkably, a significant improvement of mechanical performance is also achieved after introducing cation-π interactions, even at a decreased density (0.046 g/cm3). Specifically, for samples with 3.5 wt% solid content, the yield strength and modulus of PI-Cu aerogels increase to 0.71 MPa and 13.58 MPa, respectively, representing improvements of 344 % and 520 % over pristine PI aerogels, which are superior to those of many other previously reported PI aerogels/foams with similar or even higher densities. Additionally, the toughness is significantly elevated from 13.5 MPa to 48.8 MPa. More importantly, after introducing cation-π interactions, the thermal insulation of PI-Cu aerogels are also improved with thermal conductivity decreasing from 0.04214 to 0.03997 W/m·K in axial direction and from 0.0399 to 0.03688 W/m·K in radial direction at 25°C. Interestingly, the thermal conductivity show only a slight increase under 180°C less than 0.05741 W/m·K in axial direction and 0.04923 W/m·K in radial direction owning to their exceptional thermal stability (Tg = 404 °C, T5%=524 °C). These exceptional properties position PI-Cu aerogels as promising candidates for diverse functional applications in the field of energy conservation.

Graphene origami with enhanced impact resistance and energy absorption performance

The ancient art of origami has recently shown its potential in engineering intricate three-dimensional graphene structures with unique properties. This study employs molecular dynamics simulations to investigate the dynamic mechanical behavior of graphene origami structures (GOS) under hypervelocity ballistic impact. The analysis of residual velocity, kinetic energy loss, and specific penetration energy shows that GOS exhibit superior impact resistance and energy absorption performance compared with pristine graphene. One reason for the enhancements is that highly flexible GOS can unfold to produce a conical impact zone with larger out-of-plane deformation. Another reason is that three-dimensional folded regions possess more mass, enabling them to dissipate more kinetic energy from the projectile. The impact behavior of GOS is further analyzed concerning projectile size, impact position, and surface roughness. It is found that the impact resistance and energy absorption capacity of GOS can be adjusted by altering the surface roughness, specifically the folding degree and pattern geometry. This GOS holds promise for diverse applications in impact protection, such as combat armor and spacecraft shields.

Electrocatalytic study on the degradation of tigecycline wastewater using a three-dimensional porous agarose@MXene hydrogel carbon cloth electrode with high conductivity

In this study successfully prepared AG@MXene/CC composite electrodes by employing a thermosolvation-ultrasonication technique combined with an impregnation method. This approach uniformly dispersed MXene, known for its high electrochemical properties, onto the surface of carbon cloth (CC) through biomass-derived AG hydrogels featuring a three-dimensional network structure. The hydrogen bonding and van der Waals forces between AG and MXene were harnessed to enhance material interactions, thereby improving electron transfer efficiency and electrocatalytic activity. Experimental results demonstrated that the composite electrode could achieve up to 96.16 % degradation rate of tigecycline (TGC) within 30 min under optimal conditions. Furthermore, this study delved into the reaction mechanism of the electrocatalytic system, clarifying the key roles of H* and H2O2 generated at the cathode, as well as ·OH and active chlorine species on the anode's surface during the TGC degradation process. A synergistic catalytic mechanism for the cathode and anode was proposed. The intermediates that may be formed during TGC degradation were analyzed and their toxicity was evaluated, confirming the high biosafety of the treated wastewater. This work not only offers new insights for designing efficient and stable electrocatalysts but also broadens the application scope of the green material AG in the electrocatalytic degradation of antibiotics.